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- ItemOn the evolutionary Gamma-convergence of gradient systems modeling slow and fast chemical reactions(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2016) Disser, Karoline; Liero, Matthias; Zinsl, JonathanWe investigate the limit passage for a system of ordinary differential equations modeling slow and fast chemical reaction of mass-action type, where the rates of fast reactions tend to infinity. We give an elementary proof of convergence to a reduced dynamical system acting in the slow reaction directions on the manifold of fast reaction equilibria. Then we study the entropic gradient structure of these systems and prove an E-convergence result via Gamma-convergence of the primary and dual dissipation potentials, which shows that this structure carries over to the fast reaction limit. We recover the limit dynamics as a gradient flow of the entropy with respect to a pseudo-metric.
- ItemOn gradient structures for Markov chains and the passage to Wasserstein gradient flows(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2013) Disser, Karoline; Liero, MatthiasWe study the approximation of Wasserstein gradient structures by their finite-dimensional analog. We show that simple finite-volume discretizations of the linear Fokker-Planck equation exhibit the recently established entropic gradient-flow structure for reversible Markov chains. Then we reprove the convergence of the discrete scheme in the limit of vanishing mesh size using only the involved gradient-flow structures. In particular, we make no use of the linearity of the equations nor of the fact that the Fokker-Planck equation is of second order.