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    Greenhouse gas effects on the solar cycle response of water vapour and noctilucent clouds
    (Katlenburg, Lindau : Copernicus, 2023) Vellalassery, Ashique; Baumgarten, Gerd; Grygalashvyly, Mykhaylo; Lübken, Franz-Josef
    The responses of water vapour (H2O) and noctilucent clouds (NLCs) to the solar cycle are studied using the Leibniz Institute for Middle Atmosphere (LIMA) model and the Mesospheric Ice Microphysics And tranSport (MIMAS) model. NLCs are sensitive to the solar cycle because their formation depends on background temperature and the H2O concentration. The solar cycle affects the H2O concentration in the upper mesosphere mainly in two ways: directly through the photolysis and, at the time and place of NLC formation, indirectly through temperature changes. We found that H2O concentration correlates positively with the temperature changes due to the solar cycle at altitudes above about 82 km, where NLCs form. The photolysis effect leads to an anti-correlation of H2O concentration and solar Lyman-α radiation, which gets even more pronounced at altitudes below ∼83 km when NLCs are present. We studied the H2O response to Lyman-α variability for the period 1992 to 2018, including the two most recent solar cycles. The amplitude of Lyman-α variation decreased by about 40 % in the period 2005 to 2018 compared to the preceding solar cycle, resulting in a lower H2O response in the late period. We investigated the effect of increasing greenhouse gases (GHGs) on the H2O response throughout the solar cycle by performing model runs with and without increases in carbon dioxide (CO2) and methane (CH4). The increase of methane and carbon dioxide amplifies the response of water vapour to the solar variability. Applying the geometry of satellite observations, we find a missing response when averaging over altitudes of 80 to 85 km, where H2O has a positive response and a negative response (depending on altitude), which largely cancel each other out. One main finding is that, during NLCs, the solar cycle response of H2O strongly depends on altitude.
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    Semi-annual variation of excited hydroxyl emission at mid-latitudes
    (Katlenburg, Lindau : Copernicus, 2021) Grygalashvyly, Mykhaylo; Pogoreltsev, Alexander I.; Andreyev, Alexey B.; Smyshlyaev, Sergei P.; Sonnemann, Gerd R.
    Ground-based observations show a phase shift in semi-annual variation of excited hydroxyl (OH∗) emissions at mid-latitudes (43∘ N) compared to those at low latitudes. This differs from the annual cycle at high latitudes. We examine this behaviour by utilising an OH∗ airglow model which was incorporated into a 3D chemistry–transport model (CTM). Through this modelling, we study the morphology of the excited hydroxyl emission layer at mid-latitudes (30–50∘ N), and we assess the impact of the main drivers of its semi-annual variation: temperature, atomic oxygen, and air density. We found that this shift in the semi-annual cycle is determined mainly by the superposition of annual variations of temperature and atomic oxygen concentration. Hence, the winter peak for emission is determined exclusively by atomic oxygen concentration, whereas the summer peak is the superposition of all impacts, with temperature taking a leading role.
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    The revised method for retrieving daytime distributions of atomic oxygen and odd-hydrogens in the mesopause region from satellite observations
    (Heidelberg : Springer, 2022) Kulikov, Mikhail Y.; Belikovich, Mikhail V.; Grygalashvyly, Mykhaylo; Sonnemann, Gerd R.; Feigin, Alexander M.
    Atomic oxygen (O) and atomic hydrogen (H) in the mesopause region are critical species, governing chemistry, airglow, and energy budget. However, they cannot be directly measured by satellite remote sensing techniques and so inference techniques, by airglow observations, are used. In this work, we retrieved daytime O and H distributions at ~ 77 km–100 km from the data of observations by the SABER (Sounding of the Atmosphere using Broadband Emission Radiometry) instrument at the TIMED (Thermosphere Ionosphere Mesosphere Energetics and Dynamics) satellite in 2003–2015. The retrieval approach considered the reaction H + O3 → O2 + OH in the ozone balance equation. Moreover, we revised all quenching and spontaneous emission coefficients according to latest published data. We then calculated daytime distributions of OH and HO2 at these altitudes with the use of their conditions of photochemical equilibrium.
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    Note on consistency between Kalogerakis–Sharma Mechanism (KSM) and two-step mechanism of atmospheric band emission (762 nm)
    (Heidelberg : Springer, 2020) Grygalashvyly, Mykhaylo; Sonnemann, Gerd Reinhold
    For more than 30 years, a two-step mechanism was used to explain observed Atmospheric band emission (762 nm) in mesopause region. A new mechanism, which leads to the formation of electronically excited molecular oxygen that gives this emission, was proposed recently. We show, based on an analytical solution, that the fit-functions for Atmospheric band volume emission in the case of the two-step mechanism and the new Kalogerakis–Sharma Mechanism (KSM) have analogous expression. This derivation solves the problem of consistency between the well-known two-step mechanism and the newly proposed KSM.