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    A Detailed Paleoclimate Proxy Record for the Middle Danube Basin Over the Last 430 kyr: A Rock Magnetic and Colorimetric Study of the Zemun Loess-Paleosol Sequence
    (Lausanne : Frontiers Media, 2021) Laag, Christian; Hambach, Ulrich; Zeeden, Christian; Lagroix, France; Guyodo, Yohan; Veres, Daniel; Jovanović, Mladjen; Marković, Slobodan B.
    Herein we report on fabrication and properties of organic field-effect transistors (OFETs) based on the spray-coated films of N,N′-dioctyl naphthalene diimide (NDIC8) doped with 2.4 wt% of poly (3-hexylthiophene) (P3HT). OFETs with the untreated NDIC8:P3HT films revealed electron conductivity [μe* = 5 × 10–4 cm2×(Vs)−1]. After the annealing in chloroform vapor the NDIC8:P3HT films revealed the hole transport only [μh* = 0.9 × 10–4 cm2×(Vs)−1]. Due to the chemical nature and energy levels, the hole transport was not expected for NDIC8-based system. Polarized optical- and scanning electron microscopies indicated that the solvent vapor annealing of the NDIC8:P3HT films caused a transition of their fine-grained morphology to the network of branched, dendritic crystallites. Grazing incidence wide-angle X-ray scattering studies indicated that the above transition was accompanied by a change in the crystal structure of NDIC8. The isotropic crystal structure of NDIC8 in the untreated film was identical to the known crystal structure of the bulk NDIC8. After the solvent annealing the crystal structure of NDIC8 changed to a not-yet-reported polymorph, that, unlike in the untreated film, was partially oriented with respect to the OFET substrate.
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    The Early Upper Paleolithic Site Crvenka-At, Serbia–The First Aurignacian Lowland Occupation Site in the Southern Carpathian Basin
    (Lausanne : Frontiers Media, 2021) Nett, Janina J.; Chu, Wei; Fischer, Peter; Hambach, Ulrich; Klasen, Nicole; Zeeden, Christian; Obreht, Igor; Obrocki, Lea; Pötter, Stephan; Gavrilov, Milivoj B.; Vött, Andreas; Mihailović, Dušan; Marković, Slobodan B.; Lehmkuhl, Frank
    The Carpathian Basin is a key region for understanding modern human expansion into western Eurasia during the Late Pleistocene because of numerous early hominid fossil find spots. However, the corresponding archeological record remains less understood due to a paucity of well dated, contextualized sites. To help rectify this, we excavated and sampled Crvenka-At (Serbia), one of the largest Upper Paleolithic sites in the region to obtain radiometric ages for the archeological artifacts and evaluate their depositional context and subsequent site formation processes. Our results confirm that this locality represents a multiple-occupation Aurignacian site that dates to 36.4 ± 2.8 ka based on modeling of luminescence ages. Electrical resistivity tomography measurements indicate that the site formed on a sandy-gravelly fill terrace covered by overbank deposits. Complex grain size distributions further suggest site formation in contrasting depositional environments typically occurring alongside fluvial channels, at lakeshores, in alluvial fan or delta settings. The site is thus the closest (ca. 50 km) known Aurignacian site to the earliest undisputed modern human remains in Europe at the Peştera cu oase and some intervals of the occupation may therefore have been contemporaneous with them. This suggests that modern humans, during their initial settlement of Europe, exploited a wider range of topographic and ecological settings than previously posited. Our findings indicate that lowland areas of the Carpathian Basin are an important part of understanding the early settlement patterns of modern humans in Europe.