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    Hybrid materials - past, present and future
    (Berlin : de Gruyter, 2014) Kickelbick, Guido
    Hybrid materials represent one of the most growing new material classes at the edge of technological innovations. Unique possibilities to create novel material properties by synergetic combination of inorganic and organic components on the molecular scale makes this materials class interesting for application-oriented research of chemists, physicists, and materials scientists. The modular approach for combination of properties by the selection of the best suited components opens new options for the generation of materials that are able to solve many technological problems. This review will show in selected examples how science and technological driven approaches can help to design better materials for future applications.
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    Crystallization behavior of poly(lactic acid)/titanium dioxide nanocomposites
    (Bangkok : King Mongkut’s University of Technology, 2015) Nomai, Jiraporn; Suksut, Buncha; Schlarb, Alois K
    In this study, a poly(lactic acid) (PLA) with various titanium dioxide (TiO2) nanoparticles loading were prepared by a manual laboratory mixing method. The effect of TiO2 nanoparticles on the non-isothermal and the isothermal crystallization behavior of PLA was investigated by polarized optical microscopy (POM) and differential scanning calorimetry (DSC). The presence of TiO2 nanoparticles decreased the spherulite growth rate of PLA, whereas it initiated faster crystallization through the heterogeneous nucleation process as observed by optical microscopy. The results of DSC analyzes confirmed that the TiO2 nanoparticles act as an efficient nucleating agent for PLA crystallization. The cold crystallization temperature and crystallization half-time of PLA decreased, while the degree of crystallinity of PLA increased in relation to increases of TiO2 nanoparticles.