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- ItemHydrothermal carbonization (HTC): Near infrared spectroscopy and partial least-squares regression for determination of selective components in HTC solid and liquid products derived from maize silage(Amsterdam : Elsevier, 2014) Reza, M. Toufiq; Becker, Wolfgang; Sachsenheimer, Kerstin; Mumme, JanNear-infrared (NIR) spectroscopy was evaluated as a rapid method of predicting fiber components (hemicellulose, cellulose, lignin, and ash) and selective compounds of hydrochar and corresponding process liquor produced by hydrothermal carbonization (HTC) of maize silage. Several HTC reaction times and temperatures were applied and NIR spectra of both HTC solids and liquids were obtained and correlated with concentration determined from van-Soest fiber analysis, IC, and UHPLC. Partial least-squares regression was applied to calculate models for the prediction of selective substances. The model developed with the spectra had the best performance in 3–7 factors with a correlation coefficient, which varied between 0.9275–0.9880 and 0.9364–0.9957 for compounds in solid and liquid, respectively. Calculated root mean square errors of prediction (RMSEP) were 0.42–5.06 mg/kg. The preliminary results indicate that NIR, a widely applied technique, might be applied to determine chemical compounds in HTC solid and liquid.
- ItemThe MiLA tool: Modeling greenhouse gas emissions and cumulative energy demand of energy crop cultivation in rotation(Amsterdam : Elsevier, 2016) Peter, Christiane; Specka, Xenia; Aurbacher, Joachim; Peter Kornatz, Peter Kornatz; Herrmann, Christiane; Heiermann, Monika; Müller, Janine; Nendel, ClaasCrop rotations are part of current agricultural practice, since they and their effects can contribute to a sustainable agricultural cropping system. However, in current Life Cycle Assessment (LCA) studies, crop rotation effects are insufficiently considered, since these effects are difficult to measure. LCA studies from crop production typically take only one vegetation period into account. As a result, the consideration of how the assessed crop is influenced by the previous crop (crop rotation effects) including: (1) nutrient carryover, (2) reduction in operational requirements and (3) different intensity and timing of farming activities, is outside of the system boundary. However, ignoring these effects may lead to incorrect interpretation of LCA results and consequently to poor agricultural management as well as poor policy decisions. A new LCA tool called the “Model for integrative Life Cycle Assessment in Agriculture (MiLA)” is presented in this work. MiLA has been developed to assess GHG emissions and cumulative energy demands (CED) of cropping systems by taking the characteristics of crop cultivation in rotation into account. This tool enables the user to analyze cropping systems at farm level in order to identify GHG mitigation options and energy-efficient cropping systems. The tool was applied to a case study, including two crop rotations in two different regions in Germany with the goal of demonstrating the effectiveness of this tool on LCA results. Results show that including crop rotation effects can influence the GHG emission result of the individual crop by − 34% up to + 99% and the CED by − 16 up to + 89%. Expanding the system boundary by taking the whole crop rotation into account as well as providing the results based on different functional units improves LCA of energy crop production and helps those making the assessment to draw a more realistic picture of the interactions between crops while increasing the reliability of the LCA results.
- ItemRisk efficiency of irrigation to cereals in northeast Germany with respect to nitrogen fertilizer(Amsterdam : Elsevier, 2016) Meyer-Aurich, Andreas; Gandorfer, Markus; Trost, Benjamin; Ellmer, Frank; Baumecker, MichaelThe potential role of irrigation of cereals as a response to climate change is under debate. Especially under temperate continental conditions empirical evidence of crop yield response to irrigation in interaction with nitrogen fertilizer supply is rare. Besides mean yield effects, irrigation reduces yield variance, which may be an incentive for farmers to use irrigation. This paper investigates the risk-efficiency of irrigation in cereal production in a temperate continental climate, based on data from a long term field experiment on a sandy soil. Irrigation and no irrigation of winter rye (Secale cereale) and winter barley (Hordeum vulgare) were investigated in three different nitrogen (N) fertilizer levels. Crop yield response data (1995–2010) to irrigation and N fertilizer were used to calculate net returns, certainty equivalents (CE) for different levels of risk aversion and the conditional value at risk (CVaR) as a downside risk indicator in two price scenarios. The scenarios were calculated with a total cost and a partial budget approach. Irrigation was found to be profit-maximizing in all partial budget calculations, which sometimes required higher N input to be profit-maximizing. Irrigation and N fertilizer reduction were identified as risk mitigation strategies, even though their impact was limited. Irrigation reduced the downside risk only in the partial budget calculations. The analysis based on the CE did not show improved risk efficiency with irrigated management options. In contrast, reduced fertilizer input proved to be risk efficient at specific levels of risk aversion. The price expectations of winter rye and winter barley had a much higher impact on the ranking of the management options than risk aversion based on the crop yield variances. At low crop prices for all levels of risk aversion, irrigation of winter barley and winter rye was only economically justified if fixed costs for irrigation were not taken into account. At high crop prices, irrigation of winter barley was also justified based on the total cost calculation. However, this advantage was only given at a very low level of risk aversion. With increasing levels of risk aversion irrigation was not efficient based on the CE in the total cost accounting scenario. In conclusion, irrigation of cereals can contribute to downside risk mitigation and increased profits, if fixed costs for irrigation are covered. However, this conclusion holds only when irrigation is combined with an increased N intensity. If total costs need to be accounted for, irrigation in cereals is not an appropriate risk reduction strategy and a reduction of N input is more effective.
- ItemA brief dataset on the model-based evaluation of the growth performance of Bacillus coagulans and l-lactic acid production in a lignin-supplemented medium(Amsterdam : Elsevier, 2017) Glaser, Robert; Venus, JoachimThe data presented in this article are related to the research article entitled “Model-based characterization of growth performance and l-lactic acid production with high optical purity by thermophilic Bacillus coagulans in a lignin-supplemented mixed substrate medium (R. Glaser and J. Venus, 2016) [1]”. This data survey provides the information on characterization of three Bacillus coagulans strains. Information on cofermentation of lignocellulose-related sugars in lignin-containing media is given. Basic characterization data are supported by optical-density high-throughput screening and parameter adjustment to logistic growth models. Lab scale fermentation procedures are examined by model adjustment of a Monod kinetics-based growth model. Lignin consumption is analyzed using the data on decolorization of a lignin-supplemented minimal medium.
- ItemEnzyme-based lignocellulose hydrolyzation – Brief data survey for cellulase performance characterization on behalf of the Sauter mean diameter of raw material particles(Amsterdam : Elsevier, 2015) Glaser, RobertThe data presented here supports the informational background of enzyme-based lignocellulose hydrolyzation, cellulase characterization, and sugar yield prediction for the work “Enzyme-based lignocellulose hydrolyzation – Sauter mean diameter of raw materials as a basis for cellulase performance characterization and yield prediction” by Glaser [1]. Glucose yields from the enzymatic hydrolysis of the raw materials were shown as a function of cellulase enzyme loading as well as of particle size with different solid loading. The data for the proposed methods of the determination of enzyme activity in inhomogeneous samples of lignocellulosic raw materials are presented. The data of the empirical model that was developed for the prediction of hydrolysis yields for different enzyme concentrations, substrate specific particle size, and solid loadings, are given. Data are also given in relation of terms of scale-up opportunities.
- ItemAwassi sheep keeping in the Arabic steppe in relation to nitrous oxide emission from soil(Amsterdam : Elsevier, 2013) Hijazi, Omar; Berg, Werner; Moussa, Samouil; Ammon, Christian; von Bobrutzki, Kristina; Brunsch, ReinerSheep husbandry is the main source of income for farmers in arid zones. Increasing sheep production on steppes may increase the greenhouse gas production. The objective of this study was to investigate the nitrous oxide (N2O) emissions from the steppes for Awassi sheep keeping and feed cropping in arid zones such as Syria. The methodology developed by the Intergovernmental Panel on Climate Change (IPCC) was used to estimate N2O emissions. A survey was conducted on 64 farms in Syria to gather data for analysis. Precipitation and crop yield data from 2001 to 2009 were also used for calculation and modelling. Sheep-keeping systems, precipitation, year and the region have significant effects on N2O emissions (p<0.05). Emissions of N2O from lands with extensive, semi-intensive and intensive systems were 0.30 ± 0.093, 0.598± 0.113 and 2.243± 0.187 kg sheep1year1, respectively. Crop production was higher in regions with high precipitation levels, which helped to reduce N2O emissions. Using more residuals of wheat, cotton and soya as feed for sheep in the keeping systems evaluated may decrease the overuse of steppe regions and N2O emissions. Nitrous oxide emissions of N2O from sheep-keeping areas can be reduced by changing sheep-keeping systems and increasing the crop production in arid zones through artificial irrigation.
- ItemDirect production of lactic acid based on simultaneous saccharification and fermentation of mixed restaurant food waste(Amsterdam : Elsevier, 2016) Pleissner, Daniel; Demichelis, Francesca; Mariano, Silvia; Fiore, Silvia; Gutiérrez, Ivette Michelle Navarro; Schneider, Roland; Venus, JoachimThis study introduces to a one-step process for the fermentative production of L(+)-lactic acid from mixed restaurant food waste. Food waste was used as carbon and nitrogen source in simultaneous saccharification and fermentation (SSF) using Lactobacillus sp. or Streptococcus sp. strains for L(+)-lactic acid production. Waste consisted of (w/w) 33.5% starch, 14.8% proteins, 12.9% fat and 8.5% free sugars. Lactobacillus sp. strains showed a productivity of 0.27–0.53 g L−1 h−1 and a yield of 0.07–0.14 g g−1 of theoretically available sugars, while Streptococcus sp. more efficiently degraded the food waste material and produced lactic acid at a maximum rate of 2.16 g L−1 h−1 and a yield of 0.81 g g−1. For SSF, no enzymes were added or other hydrolytic treatments were carried out. Outcomes revealed a linear relationship between lactic acid concentration and solid-to-liquid ratio when Streptococcus sp. was applied. Statistically, from a 20% (w/w) dry food waste blend 52.4 g L−1 lactic acid can be produced. Experimentally, 58 g L−1 was achieved in presence of 20% (w/w), which was the highest solid-to-liquid ratio that could be treated using the equipment applied. Irrespective if SSF was performed at laboratory or technical scale, or under non-sterile conditions, Streptococcus sp. efficiently liquefied food waste and converted the released nutrients directly into lactic acid without considerable production of other organic acids, such as acetic acid. Downstream processing including micro- and nanofiltration, electrodialysis, chromatography and distillation gave a pure 702 g L−1 L(+)-lactic acid formulation.
- ItemRecovery and techno-functionality of flours and proteins from two edible insect species: Meal worm (Tenebrio molitor) and black soldier fly (Hermetia illucens) larvae(Amsterdam : Elsevier, 2016) Bußler, Sara; Rumpold, Birgit A.; Jander, Elisabeth; Rawel, Harshadrai M.; Schlüter, Oliver K.Depending on the species, edible insects are highly nutritious and thus represent a noteworthy alternative food and feed source. The current work investigates the protein extractability and techno-functionality of insect flour fractions recovered from Tenebrio molitor and Hermetia illucens. T. molitor and H. illucens flours contained about 20% crude fat and 60% and 36 % crude protein, respectively. Defatting reduced the crude fat content to 2.8% (T. molitor) and 8.8% (H. illucens) and increased the crude protein content to 68% and 47%, respectively. To isolate proteins from the flours, protein solubility was optimized by varying the pH, the ionic strength, and the extraction temperature of the solvent. All products and by-products accumulated in the protein production process were characterized by composition, selected techno-functional properties, protein solubility, composition and structure as well as their microbial load.
- ItemCo-fermentation of the main sugar types from a beechwood organosolv hydrolysate by several strains of Bacillus coagulans results in effective lactic acid production(Amsterdam : Elsevier, 2018) Glaser, Robert; Venus, JoachimBacillus coagulans is an interesting facultative anaerobic microorganism for biotechnological production of lactic acid that arouses interest. To determine the efficiency of biotechnological production of lactic acid from lignocellulosic feedstock hydrolysates, five Bacillus coagulans strains were grown in lignocellulose organosolv hydrolysate from ethanol/water-pulped beechwood. Parameter estimation based on a Monod-type model was used to derive the basic key parameters for a performance evaluation of the batch process. Three of the Bacillus coagulans strains, including DSM No. 2314, were able to produce lactate, primarily via uptake of glucose and xylose. Two other strains were identified as having the ability of utilizing cellobiose to a high degree, but they also had a lower affinity to xylose. The lactate yield concentration varied from 79.4 ± 2.1 g/L to 93.7 ± 1.4 g/L (85.4 ± 4.7 % of consumed carbohydrates) from the diluted organosolv hydrolysate.
- ItemImproving aerobic stability and biogas production of maize silage using silage additives(Amsterdam : Elsevier, 2015) Herrmann, Christiane; Idler, Christine; Heiermann, MonikaThe effects of air stress during storage, exposure to air at feed-out, and treatment with silage additives to enhance aerobic stability on methane production from maize silage were investigated at laboratory scale. Up to 17% of the methane potential of maize without additive was lost during seven days exposure to air on feed-out. Air stress during storage reduced aerobic stability and further increased methane losses. A chemical additive containing salts of benzoate and propionate, and inoculants containing heterofermentative lactic acid bacteria were effective to increase aerobic stability and resulted in up to 29% higher methane yields after exposure to air. Exclusion of air to the best possible extent and high aerobic stabilities should be primary objectives when ensiling biogas feedstocks.