2021, Schmidt, Michael, Kettlitz, Manfred, Kolb, Juergen F.

The combination of non-thermal plasma (NTP), operated at room temperature and at atmospheric pressure in air and in combination with activated carbon filters offers a more efficient removal of VOCs from gas streams than each individual method alone. Efficiencies, synergies and mechanisms of this combination were investigated by means of comprehensive quantitative Fourier transform infrared spectroscopy analysis. Therefore, dry and wet synthetic air containing about 90 ppm of methyl ethyl ketone (MEK) were treated with non-thermal plasma (NTP) and an intentionally undersized activated carbon (AC) filter, separately and in combination. As a result, removal of about 50 % was achieved for NTP or AC alone but a removal close to 95 % was found for the combination. Ozone, generated by the NTP, was reduced by 55 % with the AC-filter. For the operation of the NTP with humid air, a decomposition of the pollutant on AC was observed even after the plasma was switched off.

2021, Bolch, Tobias, Duethmann, Doris, Wortmann, Michel, Liu, Shiyin, Disse, Markus

Tarim River basin is the largest endorheic river basin in China. Due to the extremely arid climate the water supply solely depends on water originating from the glacierised mountains with about 75% stemming from the transboundary Aksu River. The water demand is linked to anthropogenic (specifically agriculture) and natural ecosystems, both competing for water. Ongoing climate change significantly impacts the cryosphere. The mass balance of the glaciers in Aksu River basin was clearly negative since 1975. The discharge of the Aksu headwaters has been increasing over the last decades mainly due to the glacier contribution. The average glacier melt contribution to total runoff is 30–37% with an estimated glacier imbalance contribution of 8–16%. Modelling using future climate scenarios indicate a glacier area loss of at least 50% until 2100. River discharge will first increase concomitant with glacier shrinkage until about 2050, but likely decline thereafter. The irrigated area doubled in the Aksu region between the early 1990s and 2020, causing at least a doubling of water demand. The current water surplus is comparable to the glacial runoff. Hence, even if the water demand will not grow further in the future a significant water shortage can be expected with declining glacial runoff. However, with the further expansion of irrigated agriculture and related industries, the water demand is expected to even further increase. Both improved discharge projections and planning of efficient and sustainable water use are necessary for further socioeconomic development in the region along with the preservation of natural ecosystems.

2021, Hänsel, Martin C., Bergh, Jeroen C. J. M. van den

We model a stylized economy dependent on agriculture and fisheries to study optimal environmental policy in the face of interacting external effects of ocean acidification, global warming, and eutrophication. This allows us to capture some of the latest insights from research on ocean acidification. Using a static two-sector general equilibrium model we derive optimal rules for national taxes on (Formula presented.) emissions and agricultural run-off and show how they depend on both isolated and interacting damage effects. In addition, we derive a second-best rule for a tax on agricultural run-off of fertilizers for the realistic case that effective internalization of (Formula presented.) externalities is lacking. The results contribute to a better understanding of the social costs of ocean acidification in coastal economies when there is interaction with other environmental stressors. Recommendations for Resource Managers: Marginal environmental damages from (Formula presented.) emissions should be internalized by a tax on (Formula presented.) emissions that is high enough to not only reflect marginal damages from temperature increases, but also marginal damages from ocean acidification and the interaction of both with regional sources of acidification like nutrient run-off from agriculture. In the absence of serious national policies that fully internalize externalities, a sufficiently high tax on regional nutrient run-off of fertilizers used in agricultural production can limit not only marginal environmental damages from nutrient run-off but also account for unregulated carbon emissions. Putting such regional policies in place that consider multiple important drivers of environmental change will be of particular importance for developing coastal economies that are likely to suffer the most from ocean acidification. © 2021 The Authors. Natural Resource Modeling published by Wiley Periodicals LLC.

2021, Eisenack, Klaus, Oberlack, Christoph, Sietz, Diana

Recent years have seen a proliferation of studies that use archetype analysis to better understand and to foster transitions toward sustainability. This growing literature reveals a common methodological ground, as well as a variety of perspectives and practices. In this paper, we provide an historical overview of the roots of archetype analysis from ancient philosophy to recent sustainability science. We thereby derive core features of the archetype approach, which we frame by eight propositions. We then introduce the Special Feature, “Archetype Analysis in Sustainability Research,” which offers a consolidated understanding of the approach, a portfolio of methods, and quality criteria, as well as cutting-edge applications. By reflecting on the Special Feature’s empirical and methodological contributions, we hope that the showcased advances, exemplary applications, and conceptual clarifications will help to design future research that contributes to collaborative learning on archetypical patterns leading toward sustainability. The paper concludes with an outlook highlighting central directions for the next wave of archetype analyses.

2021, Lu, Q., Jie, Y., Meng, X., Omar, A., Mikhailova, D., Cao, R., Jiao, S., Lu, Y., Xu, Y.

Lithium (Li) metal is regarded as the ultimate anode for next-generation Li-ion batteries due to its highest specific capacity and lowest electrochemical potential. However, the Li metal anode has limitations, including virtually infinite volume change, nonuniform Li deposition, and an unstable electrode–electrolyte interface, which lead to rapid capacity degradation and poor cycling stability, significantly hindering its practical application. To address these issues, intensive efforts have been devoted toward accommodating and guiding Li deposition as well as stabilizing the interface using various carbon materials, which have demonstrated excellent effectiveness, benefiting from their vast variety and excellent tunability of the structure–property relationship. This review is intended as a guide through the fundamental challenges of Li metal anodes to the corresponding solutions utilizing carbon materials. The specific functionalities and mechanisms of carbon materials for stabilizing Li metal anodes in these solutions are discussed in detail. Apart from the stabilization of the Li metal anode in liquid electrolytes, attention has also been paid to the review of anode-free Li metal batteries and solid-state batteries enabled by strategies based on carbon materials. Furthermore, we have reviewed the unresolved challenges and presented our outlook on the implementation of carbon materials for stabilizing Li metal anodes in practical applications.

2021, Wawerzinek, Britta, Buness, Hermann, von Hartmann, Hartwig, Tanner, David C.

There are many successful geothermal projects that exploit the Upper Jurassic aquifer at 2–3 km depth in the German Molasse Basin. However, up to now, only P-wave seismic exploration has been carried out. In an experiment in the Greater Munich area, we recorded S-waves that were generated by the conventional P-wave seismic survey, using 3C receivers. From this, we built a 3D volume of P- to S-converted (PS) waves using the asymptotic conversion point approach. By combining the P-volume and the resulting PS-seismic volume, we were able to derive the spatial distribution of the vp/vs ratio of both the Molasse overburden and the Upper Jurassic reservoir. We found that the vp/vs ratios for the Molasse units range from 2.0 to 2.3 with a median of 2.15, which is much higher than previously assumed. This raises the depth of hypocenters of induced earthquakes in surrounding geothermal wells. The vp/vs ratios found in the Upper Jurassic vary laterally between 1.5 and 2.2. Since no boreholes are available for verification, we test our results against an independently derived facies classification of the conventional 3D seismic volume and found it correlates well. Furthermore, we see that low vp/vs ratios correlate with high vp and vs velocities. We interpret the latter as dolomitized rocks, which are connected with enhanced permeability in the reservoir. We conclude that 3C registration of conventional P-wave surveys is worthwhile.

2021, van der Weerden, Tony J., Noble, Alasdair, de Klein, Cecile A. M., Hutchings, Nicholas, Thorman, Rachel E., Alfaro, Marta A., Amon, Barbara, Beltran, Ignacio, Grace, Peter, Hassouna, Mélynda, Krol, Dominika J., Leytem, April B., Salazar, Francisco, Velthof, Gerard L.

Manure application to land and deposition of urine and dung by grazing animals are major sources of ammonia (NH3 ) and nitrous oxide (N2 O) emissions. Using data on NH3 and N2 O emissions following land-applied manures and excreta deposited during grazing, emission factors (EFs) disaggregated by climate zone were developed, and the effects of mitigation strategies were evaluated. The NH3 data represent emissions from cattle and swine manures in temperate wet climates, and the N2 O data include cattle, sheep, and swine manure emissions in temperate wet/dry and tropical wet/dry climates. The NH3 EFs for broadcast cattle solid manure and slurry were 0.03 and 0.24 kg NH3 -N kg-1 total N (TN), respectively, whereas the NH3 EF of broadcast swine slurry was 0.29. Emissions from both cattle and swine slurry were reduced between 46 and 62% with low-emissions application methods. Land application of cattle and swine manure in wet climates had EFs of 0.005 and 0.011 kg N2 O-N kg-1 TN, respectively, whereas in dry climates the EF for cattle manure was 0.0031. The N2 O EFs for cattle urine and dung in wet climates were 0.0095 and 0.002 kg N2 O-N kg-1 TN, respectively, which were three times greater than for dry climates. The N2 O EFs for sheep urine and dung in wet climates were 0.0043 and 0.0005, respectively. The use of nitrification inhibitors reduced emissions in swine manure, cattle urine/dung, and sheep urine by 45-63%. These enhanced EFs can improve national inventories; however, more data from poorly represented regions (e.g., Asia, Africa, South America) are needed.

2021, Sauer, Inga J., Roca, Elisabet, Villares, Míriam

Coastal cities are exposed to high risks due to climate change, as they are potentially affected by both rising sea levels and increasingly intense and frequent coastal storms. Socio-economic drivers also increase exposure to natural hazards, accelerate environmental degradation, and require adaptive governance structures to moderate negative impacts. Here, we use a social network analysis (SNA) combined with further qualitative information to identify barriers and enablers of adaptive governance in the Barcelona metropolitan area. By analyzing how climate change adaptation is mainstreamed between different administrative scales as well as different societal actors, we can determine the governance structures and external conditions that hamper or foster strategical adaptation plans from being used as operational adaptation tools. We identify a diverse set of stakeholders acting at different administrative levels (local to national), in public administration, science, civil society, and the tourism economy. The metropolitan administration acts as an important bridging organization by promoting climate change adaptation to different interest groups and by passing knowledge between actors. Nonetheless, national adaptation planning fails to take into account local experiences in coastal protection, which leads to an ineffective science policy interaction and limits adaptive management and learning opportunities. Overcoming this is difficult, however, as the effectiveness of local adaptation strategies in the Barcelona metropolitan area is very limited due to a strong centralization of power at the national level and a lack of polycentricity. Due to the high touristic pressure, the legal framework is currently oriented to primarily meet the demands of recreational use and tourism, prioritizing these aspects in daily management practice. Therefore, touristic and economic activities need to be aligned to adaptation efforts, to convert them from barriers into drivers for adaptation action. Our work strongly suggests that more effectively embedding adaptation planning and action into existing legal structures of coastal management would allow strategic adaptation plans to be an effective operational tool for local coastal governance.

2021, Beltran, Ignacio, van der Weerden, Tony J., Alfaro, Marta A., Amon, Barbara, de Klein, Cecile A. M., Grace, Peter, Hafner, Sasha, Hassouna, Mélynda, Hutchings, Nicholas, Krol, Dominika J., Leytem, April B., Noble, Alasdair, Salazar, Francisco, Thorman, Rachel E., Velthof, Gerard L.

Nitrous oxide (N2 O), ammonia (NH3 ), and methane (CH4 ) emissions from the manure management chain of livestock production systems are important contributors to greenhouse gases (GHGs) and NH3 emitted by human activities. Several studies have evaluated manure-related emissions and associated key variables at regional, national, or continental scales. However, there have been few studies focusing on the drivers of these emissions using a global dataset. An international project was created (DATAMAN) to develop a global database on GHG and NH3 emissions from the manure management chain (housing, storage, and field) to identify key variables influencing emissions and ultimately to refine emission factors (EFs) for future national GHG inventories and NH3 emission reporting. This paper describes the "field" database that focuses on N2 O and NH3 EFs from land-applied manure and excreta deposited by grazing livestock. We collated relevant information (EFs, manure characteristics, soil properties, and climatic conditions) from published peer-reviewed research, conference papers, and existing databases. The database, containing 5,632 observations compiled from 184 studies, was relatively evenly split between N2 O and NH3 (56 and 44% of the EF values, respectively). The N2 O data were derived from studies conducted in 21 countries on five continents, with New Zealand, the United Kingdom, Kenya, and Brazil representing 86% of the data. The NH3 data originated from studies conducted in 17 countries on four continents, with the United Kingdom, Denmark, Canada, and The Netherlands representing 79% of the data. Wet temperate climates represented 90% of the total database. The DATAMAN field database is available at http://www.dataman.co.nz.

2021, Kornek, Ulrike, Klenert, David, Edenhofer, Ottmar, Fleurbaey, Marc

The social cost of carbon is a central metric for optimal carbon prices. Previous literature shows that inequality significantly influences the social cost of carbon, but mostly omits heterogeneity below the national level. We present an optimal taxation model of the social cost of carbon that accounts for inequality between and within countries. We find that climate and distributional policy can generally not be separated. If only one country does not compensate low-income households for disproportionate damages, the social cost of carbon tends to increase globally. Optimal carbon prices remain roughly unchanged if national redistribution leaves inequality between households unaffected by climate change and if the utility of households is approximately logarithmic in consumption.