2008, Hapke, M., Spannenberg, A.

The title compound, [Co(C5H5)(C18H15P)2]·0.2C7H8·0.25C6H14, was synthesized by the reaction of cobaltocene, Cp2Co, with elemental lithium in tetra-hydro-furan in the presence of two equivalents of PPh3. The mol-ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol-ecules in the asymmetric unit besides the disordered solvent molecules.

2008, Polom, U., Arsyad, I., Kümpel, H.-J.

As part of the project "Management of Georisk" (MANGEONAD) of the Federal Institute for Geosciences and Natural Resources (BGR), Hanover, high resolution shallow shear-wave reflection seismics was applied in the Indonesian province Nanggroe Aceh Darussalam, North Sumatra in cooperation with the Government of Indonesia, local counterparts, and the Leibniz Institute for Applied Geosciences, Hanover. The investigations were expected to support classification of earthquake site effects for the reconstruction of buildings and infrastructure as well as for groundwater exploration. The study focus sed on the city of Banda Aceh and the surroundings of Aceh Besar. The shear-wave seismic surveys were done parallel to standard geoengineering investigations like cone penetrometer tests to support subsequent site specific statistical calibration. They were also partly supplemented by shallow p-wave seismics for the identification of (a) elastic subsurface parameters and (b) zones with abundance of groundwater. Evaluation of seismic site effects based on shallow reflection seismics has in fact been found to be a highly useful method in Aceh province. In particular, use of a vibratory seismic source was essential for successful application of shear-wave seismics in the city of Banda Aceh and in areas with compacted ground like on farm tracks in the surroundings, presenting mostly agricultural land use areas. We thus were able to explore the mechanical stiffness of the subsurface down to 100 m depth, occasionally even deeper, with remarkably high resolution. The results were transferred into geotechnical site classification in terms of the International Building Code (IBC, 2003). The seismic images give also insights into the history of the basin sedimentation processes of the Krueng Aceh River delta, which is relevant for the exploration of new areas for construction of safe foundations of buildings and for identification of fresh water aquifers in the tsunami flooded region.

2008, Archer, D., Brovkin, V.

The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere/ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial/interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere. © 2008 The Author(s).

2008, Barth, Andreas, Marx, Werner

This study has been carried out to analyze the research field of high-temperature superconductivity and to demonstrate the potential of modern databases and search systems for generating meta-information. The alkaline earth (A2) rare earth (RE) cuprate high-temperature superconductors as a typical inorganic compound family and the corresponding literature were analyzed by scientometric methods. The time dependent overall number of articles and patents and of the publications related to specific compound subsets and subject categories are given. The data reveal a significant decrease of basic research activity in this research field. The A2 RE cuprate species covered by the CAS compound file were analyzed with respect to the occurrence of specific elements in order to visualize known and unknown substances and to identify characteristic patterns. The quaternary and quinternary cuprates were selected and the number of compound species as a function of specific combinations of A2 and RE elements is given. The Cu/O and RE/A2 ratios of the quaternary cuprate species as a function of A2 and RE atoms are shown. In addition, the research landscape of the MgB2 related publications was established using STN AnaVist, an analysis tool recently developed by STN International.

2008, Veličkov, B., Kahlenberg, V., Bertram, R., Uecker, R.

The crystal structure of terbium(III) scandate(III), with ideal formula TbScO3, has been reported previously on the basis of powder diffraction data [Liferovich & Mitchell (2004). J. Solid State Chem. 177, 2188-2197]. The current data were obtained from single crystals grown by the Czochralski method and show an improvement in the precision of the geometric parameters. Moreover, inductively coupled plasma optical emission spectrometry studies resulted in a nonstoichiometric composition of the title compound. Site-occupancy refinements based on diffraction data support the idea of a Tb deficiency on the A site (inducing O defects on the O2 position). The crystallochemical formula of the investigated sample thus may be written as A(0.04Tb0.96) BScO2.94. In the title compound, Tb occupies the eightfold- coordinated sites (site symmetry m) and Sc the centres of corner-sharing [ScO6] octa-hedra (site symmetry ). The mean bond lengths and site distortions fit well into the data of the remaining lanthanoid scandates in the series from DyScO3 to NdScO3. A linear structural evolution with the size of the lanthanoid from DyScO3 to NdScO3 can be predicted.

2007, Luderer, G., Trentmann, J., Hungershöfer, K., Herzog, M., Fromm, M., Andreae, M.O.

Deep convection induced by large forest fires is an efficient mechanism for transport of aerosol particles and trace gases into the upper troposphere and lower stratosphere (UT/LS). For many pyro-cumulonimbus clouds (pyroCbs) as well as other cases of severe convection without fire forcing, radiometric observations of cloud tops in the thermal infrared (IR) reveal characteristic structures, featuring a region of relatively high brightness temperatures (warm center) surrounded by a U-shaped region of low brightness temperatures. We performed a numerical simulation of a specific case study of pyroCb using a non-hydrostatic cloud resolving model with a two-moment cloud microphysics parameterization and a prognostic turbulence scheme. The model is able to reproduce the thermal IR structure as observed from satellite radiometry. Our findings establish a close link between the observed temperature pattern and small-scale mixing processes atop and downwind of the overshooting dome of the pyroCb. Such small-scale mixing processes are strongly enhanced by the formation and breaking of a stationary gravity wave induced by the overshoot. They are found to increase the stratospheric penetration of the smoke by up to almost 30 K and thus are of major significance for irreversible transport of forest fire smoke into the lower stratosphere.

2008, Jaeger, C., Schellnhuber, H.J., Brovkin, V.

The Stern Review has played an enormous role in making the world of business aware of the challenge of long-term climate change. In order to make real progress on the basis of this awareness, it is important to pay attention to the difference between human suffering and losses of gross domestic product (GDP). The Review has compared climate change to experiences of suffering like World War I. That war, however, hardly affected global GDP. The long-term damages to be expected from business-as-usual greenhouse gas emissions include loss of the coastal cities of the world over the next millennia. This would be an act of unprecedented barbarism, regardless of whether it would slow down economic growth or perhaps even accelerate it. Business leaders worried about climate change need to pay attention to the tensions between ethical and economic concerns. Otherwise, a credibility crisis threatens global climate policy. An important step to establish the credibility needed for effective climate policy will be to gradually move towards a regime where emission permits are auctioned, not handed out as hidden subsidies. The revenues generated by permit auctions should be used to establish a global system of regional climate funds. © 2008 The Author(s).

2008, Rost, S., Gerten, D., Heyder, U.

This study quantifies current and potential future changes in transpiration, evaporation, interception loss and river discharge in response to land use change, irrigation and climate change, by performing several distinct simulations within the consistent hydrology and biosphere modeling framework LPJmL (Lund-Potsdam-Jena managed Land). We distinguished two irrigation simulations: a water limited one in which irrigation was restricted by local renewable water resources (ILIM), and a potential one in which no such limitation was assumed but withdrawals from deep groundwater or remote rivers allowed (IPOT). We found that the effect of historical land use change as compared to potential natural vegetation was pronounced, including a reduction in interception loss and transpiration by 25.9% and 10.6%, respectively, whereas river discharge increased by 6.6% (climate conditions of 1991-2000). Furthermore, we estimated that about 1170km3yr-1 of irrigation water could be withdrawn from local renewable water resources (in ILIM), which resulted in a reduction of river discharge by 1.5%. However, up to 1660km3yr-1 of water withdrawals were required in addition under the assumption that optimal growth of irrigated crops was sustained (IPOT), which resulted in a slight net increase in global river discharge by 2.0% due to return flows. Under the HadCM3 A2 climate and emission scenario, climate change alone will decrease total evapotranspiration by 1.5% and river discharge by 0.9% in 2046-2055 compared to 1991-2000 average due to changes in precipitation patterns, a decrease in global precipitation amount, and the net effect of CO2 fertilization. A doubling of agricultural land in 2046-2055 compared to 1991-2000 average as proposed by the IMAGE land use change scenario will result in a decrease in total evapotranspiration by 2.5% and in an increase in river discharge by 3.9%. That is, the effects of land use change in the future will be comparable in magnitude to the effects of climate change in this particular scenario. On present irrigated areas future water withdrawal will increase especially in regions where climate changes towards warmer and dryer conditions will be pronounced.

2007, Osmany, S.A., Herzel, F., Schmalz, K., Winkler, W.

We present an analytical phase noise model for fractional-N phase-locked loops (PLL) with emphasis on integrated RF synthesizers in the GHz range. The noise of the crystal reference, the voltage-controlled oscillator (VCO), the loop filter, the charge pump, and the sigma-delta modulator (SDM) is filtered by the PLL operation. We express the rms phase error (jitter) in terms of phase noise of the reference, the VCO phase noise and the third-order loop filter parameters. In addition, we consider OFDM systems, where the PLL phase noise is reduced by digital signal processing after down-conversion of the RF signal to baseband. The rms phase error is discussed as a function of the loop parameters. Our model drastically simplifies the noise optimization of the PLL loop dynamics.

2007, Polzehl, J., Tabelow, K.

Digital imaging has become omnipresent in the past years with a bulk of applications ranging from medical imaging to photography. When pushing the limits of resolution and sensitivity noise has ever been a major issue. However, commonly used non-adaptive filters can do noise reduction at the cost of a reduced effective spatial resolution only. Here we present a new package adimpro for R, which implements the propagationseparation approach by (Polzehl arid Spokoiriy 2006) for smoothing digital images. This method naturally adapts to different structures of different size in the image and thus avoids oversmoothing edges and fine structures. We extend the method for imaging data with spatial correlation. Furthermore we show how the estimation of the dependence between variance and mean value can be included. We illustrate the use of the package through some examples.