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- ItemOverview: The Baltic Earth Assessment Reports (BEAR)(Göttingen : Copernicus Publ., 2023) Meier, H. E. Markus; Reckermann, Marcus; Langner, Joakim; Smith, Ben; Didenkulova, IraBaltic Earth is an independent research network of scientists from all Baltic Sea countries that promotes regional Earth system research. Within the framework of this network, the Baltic Earth Assessment Reports (BEARs) were produced in the period 2019-2022. These are a collection of 10 review articles summarising current knowledge on the environmental and climatic state of the Earth system in the Baltic Sea region and its changes in the past (palaeoclimate), present (historical period with instrumental observations) and prospective future (until 2100) caused by natural variability, climate change and other human activities. The division of topics among articles follows the grand challenges and selected themes of the Baltic Earth Science Plan, such as the regional water, biogeochemical and carbon cycles; extremes and natural hazards; sea-level dynamics and coastal erosion; marine ecosystems; coupled Earth system models; scenario simulations for the regional atmosphere and the Baltic Sea; and climate change and impacts of human use. Each review article contains an introduction, the current state of knowledge, knowledge gaps, conclusions and key messages; the latter are the bases on which recommendations for future research are made. Based on the BEARs, Baltic Earth has published an information leaflet on climate change in the Baltic Sea as part of its outreach work, which has been published in two languages so far, and organised conferences and workshops for stakeholders, in collaboration with the Baltic Marine Environment Protection Commission (Helsinki Commission, HELCOM).
- ItemDynamic regimes of the Greenland Ice Sheet emerging from interacting melt–elevation and glacial isostatic adjustment feedbacks(Göttingen : Copernicus Publ., 2022) Zeitz, Maria; Haacker, Jan M.; Donges, Jonathan F.; Albrecht, Torsten; Winkelmann, RicardaThe stability of the Greenland Ice Sheet under global warming is governed by a number of dynamic processes and interacting feedback mechanisms in the ice sheet, atmosphere and solid Earth. Here we study the long-term effects due to the interplay of the competing melt-elevation and glacial isostatic adjustment (GIA) feedbacks for different temperature step forcing experiments with a coupled ice-sheet and solid-Earth model. Our model results show that for warming levels above 2 C, Greenland could become essentially ice-free within several millennia, mainly as a result of surface melting and acceleration of ice flow. These ice losses are mitigated, however, in some cases with strong GIA feedback even promoting an incomplete recovery of the Greenland ice volume. We further explore the full-factorial parameter space determining the relative strengths of the two feedbacks: our findings suggest distinct dynamic regimes of the Greenland Ice Sheets on the route to destabilization under global warming - from incomplete recovery, via quasi-periodic oscillations in ice volume to ice-sheet collapse. In the incomplete recovery regime, the initial ice loss due to warming is essentially reversed within 50000years, and the ice volume stabilizes at 61-93 of the present-day volume. For certain combinations of temperature increase, atmospheric lapse rate and mantle viscosity, the interaction of the GIA feedback and the melt-elevation feedback leads to self-sustained, long-term oscillations in ice-sheet volume with oscillation periods between 74000 and over 300000 years and oscillation amplitudes between 15-70 of present-day ice volume. This oscillatory regime reveals a possible mode of internal climatic variability in the Earth system on timescales on the order of 100000years that may be excited by or synchronized with orbital forcing or interact with glacial cycles and other slow modes of variability. Our findings are not meant as scenario-based near-term projections of ice losses but rather providing insight into of the feedback loops governing the "deep future"and, thus, long-term resilience of the Greenland Ice Sheet.
- ItemThe effect of overshooting 1.5 °C global warming on the mass loss of the Greenland ice sheet(Göttingen : Copernicus Publ., 2018) Rückamp, Martin; Falk, Ulrike; Frieler, Katja; Lange, Stefan; Humbert, AngelikaSea-level rise associated with changing climate is expected to pose a major challenge for societies. Based on the efforts of COP21 to limit global warming to 2.0 ∘C or even 1.5 ∘C by the end of the 21st century (Paris Agreement), we simulate the future contribution of the Greenland ice sheet (GrIS) to sea-level change under the low emission Representative Concentration Pathway (RCP) 2.6 scenario. The Ice Sheet System Model (ISSM) with higher-order approximation is used and initialized with a hybrid approach of spin-up and data assimilation. For three general circulation models (GCMs: HadGEM2-ES, IPSL-CM5A-LR, MIROC5) the projections are conducted up to 2300 with forcing fields for surface mass balance (SMB) and ice surface temperature (Ts) computed by the surface energy balance model of intermediate complexity (SEMIC). The projected sea-level rise ranges between 21–38 mm by 2100 and 36–85 mm by 2300. According to the three GCMs used, global warming will exceed 1.5 ∘C early in the 21st century. The RCP2.6 peak and decline scenario is therefore manually adjusted in another set of experiments to suppress the 1.5 ∘C overshooting effect. These scenarios show a sea-level contribution that is on average about 38 % and 31 % less by 2100 and 2300, respectively. For some experiments, the rate of mass loss in the 23rd century does not exclude a stable ice sheet in the future. This is due to a spatially integrated SMB that remains positive and reaches values similar to the present day in the latter half of the simulation period. Although the mean SMB is reduced in the warmer climate, a future steady-state ice sheet with lower surface elevation and hence volume might be possible. Our results indicate that uncertainties in the projections stem from the underlying GCM climate data used to calculate the surface mass balance. However, the RCP2.6 scenario will lead to significant changes in the GrIS, including elevation changes of up to 100 m. The sea-level contribution estimated in this study may serve as a lower bound for the RCP2.6 scenario, as the currently observed sea-level rise is not reached in any of the experiments; this is attributed to processes (e.g. ocean forcing) not yet represented by the model, but proven to play a major role in GrIS mass loss.
- ItemImproving the electrical and structural stability of highly piezoresistive nickel–carbon sensor thin films(Göttingen : Copernicus Publ., 2022) Schultes, Günter; Cerino, Mario; Lellig, Angela; Koch, MarcusThe family of sputter deposited granular metal-based carbon-containing sensor films is known for their high sensitivity transforming force-dependent strain into electrical resistance change. Among them nickel–carbon thin films possess a gauge factor of up to 30, compared to only 2 for traditional sensor films of metal alloys. This high sensitivity is based on disordered interparticle tunneling through barriers of graphite-like carbon walls between metal–carbon particles of columnar shape. Force and pressure sensors would benefit a lot from the elevated piezoresistivity. A disadvantage, however, is a disturbing temporal creep and drift of the resistance under load and temperature. This contribution shows how to stabilize such sensor films. A significant stabilization is achieved by partially replacing nickel with chromium, albeit at the expense of sensitivity. The more chromium used in these NixCr1−x-C layers, the higher the optimum annealing temperature can be selected and the better the electrical stabilization. A good compromise while maintaining sensitivities well above the standard of 2 is identified for films with x=0.5 to 0.9, stabilized by optimized temperature treatments. The stabilizing effect of chromium is revealed by transmission electron microscopy with elemental analysis. The post-annealing drives segregation processes in the layer material. While the interior of the layer is depleted of chromium and carbon, boundary layers are formed. Chromium is enriched near the surface boundary, oxidized in air and forms chromium-rich oxide sub-layers, which are chemically very stable and protect against further reactions and corrosion. As a result, creep and drift errors are greatly reduced, so that the optimized sensor coatings are now suitable for widespread use.
- ItemFibre optic sensing system for monitoring of current collectors and overhead contact lines of railways(Göttingen : Copernicus Publ., 2017) Schröder, Kerstin; Rothhardt, Manfred; Ecke, Wolfgang; Richter, Uwe; Sonntag, André; Bartelt, HartmutFibre optic sensors are excellent tools to use for monitoring high-voltage current collectors. Because of their small cross section and electrical neutrality, they are easily integrated into the current collector strip and are well specialized for detection of high-speed load events. The conventional contact force measurement with four force sensors below the collector strips can also be simplified by using fibre optic force and acceleration sensors.
- ItemGranular metal-carbon nanocomposites as piezoresistive sensor films - Part 1: Experimental results and morphology(Göttingen : Copernicus Publ., 2018) Schultes, Günter; Schmid-Engel, Hanna; Schwebke, Silvan; Werner, UlfWe have produced granular films based on carbon and different transition metals by means of plasma deposition processes. Some of the films possess an increased strain sensitivity compared to metallic films. They respond to strain almost linearly with gauge factors of up to 30 if strained longitudinally, while in the transverse direction about half of the effect is still measured. In addition, the film's thermal coefficient of resistance is adjustable by the metal concentration. The influence of metal concentration was investigated for the elements Ni, Pd, Fe, Pt, W, and Cr, while the elements Co, Au, Ag, Al, Ti, and Cu were studied briefly. Only Ni and Pd have a pronounced strain sensitivity at 55- €±- €5- €at.- €% (atomic percent) of metal, among which Ni–C is far more stable. Two phases are identified by transmission electron microscopy and X-ray diffraction: metal-containing nanocolumns densely packed in a surrounding carbon phase. We differentiate three groups of metals, due to their respective affinity to carbon. It turns out that only nickel has the capability to bond and form a stable and closed encapsulation of GLC around each nanoparticle. In this structure, the electron transport is in part accomplished by tunneling processes across the basal planes of the graphitic encapsulation. Hence, we hold these tunneling processes responsible for the increased gauge factors of Ni–C composites. The other elements are unable to form graphitic encapsulations and thus do not exhibit elevated gauge factors.
- ItemUltrafast imaging Raman spectroscopy of large-area samples without stepwise scanning(Göttingen : Copernicus Publ., 2016) Schmälzlin, Elmar; Moralejo, Benito; Bodenmüller, Daniel; Darvin, Maxim E.; Thiede, Gisela; Roth, Martin M.Step-by-step, time-consuming scanning of the sample is still the state-of-the-art in imaging Raman spectroscopy. Even for a few 100 image points the measurement time may add up to minutes or hours. A radical decrease in measurement time can be achieved by applying multiplex spectrographs coupled to imaging fiber bundles that are successfully used in astronomy. For optimal use of the scarce and expensive observation time at astronomical observatories, special high-performance spectrograph systems were developed. They are designed for recording thousands of spatially resolved spectra of a two-dimensional image field within one single exposure. Transferring this technology to imaging Raman spectroscopy allows a considerably faster acquisition of chemical maps. Currently, an imaging field of up to 1 cm2 can be investigated. For porcine skin the required measurement time is less than 1 min. For this reason, this technique is of particular interest for medical diagnostics, e.g., the identification of potentially cancerous abnormalities of skin tissue.
- ItemGranular metal-carbon nanocomposites as piezoresistive sensor films-Part 2: Modeling longitudinal and transverse strain sensitivity(Göttingen : Copernicus Publ., 2018) Schwebke, Silvan; Werner, Ulf; Schultes, GünterGranular and columnar nickel-carbon composites may exhibit large strain sensitivity, which makes them an interesting sensor material. Based on experimental results and morphological characterization of the material, we develop a model of the electron transport in the film and use it to explain its piezoresistive effect. First we describe a model for the electron transport from particle to particle. The model is then applied in Monte Carlo simulations of the resistance and strain properties of the disordered films that give a first explanation of film properties. The simulations give insights into the origin of the transverse sensitivity and show the influence of various parameters such as particle separation and geometric disorder. An important influence towards larger strain sensitivity is local strain enhancement due to different elastic moduli of metal particles and carbon matrix.
- ItemParadigm change in hydrogel sensor manufacturing: From recipe-driven to specification-driven process optimization(Göttingen : Copernicus Publ., 2016) Windisch, M.; Eichhorn, K.-J.; Lienig, J.; Gerlach, G.; Schulze, L.The volume production of industrial hydrogel sensors lacks a quality-assuring manufacturing technique for thin polymer films with reproducible properties. Overcoming this problem requires a paradigm change from the current recipe-driven manufacturing process to a specification-driven one. This requires techniques to measure quality-determining hydrogel film properties as well as tools and methods for the control and optimization of the manufacturing process. In this paper we present an approach that comprehensively addresses these issues. The influence of process parameters on the hydrogel film properties and the resulting sensor characteristics have been assessed by means of batch manufacturing tests and the application of several measurement techniques. Based on these investigations, we present novel methods and a tool for the optimization of the cross-linking process step, with the latter being crucial for the sensor sensitivity. Our approach is applicable to various sensor designs with different hydrogels. It has been successfully tested with a sensor solution for surface technology based on PVA/PAA hydrogel as sensing layer and a piezoelectric thickness shear resonator as transducer. Finally, unresolved issues regarding the measurement of hydrogel film parameters are outlined for future research.
- ItemRearrangement of stresses in fault zones - detecting major issues of coupled hydraulic–mechanical processes with relevance to geothermal applications(Göttingen : Copernicus Publ., 2014) Ziefle, G.The South German Molasse Basin provides favourable conditions for geothermal plants. Nevertheless, micro-seismic events occur in the vicinity of the geothermal Unterhaching Gt2 well and seem to be caused by the geothermal plant. The injection and production are located in an existing fault system. The majority of seismic events takes place at a horizontal distance of 500 m or less of the borehole. However, none of the seismic events are located in the injection reservoir but in fact at a significantly greater depth. A deeper process understanding of the interacting thermal–hydraulic–mechanical effects in the vicinity of the well is desired. This article presents a significantly simplified 2-D model, investigating interactions of the stress field in the vicinity of the geothermal well and movements in the fault system. This might be of special interest, as the operation of the geothermal plant might lead to changes in the material and fracture properties on the one hand and in the equilibrium state on the other. A detailed description of the model, as well as various parameter studies, is presented. It can be seen that boundary conditions such as direction of the stress field in relation to the fault system, geometry of the fault system and parameters of the fractures have a significant influence on stresses in the proximity of the geothermal well. A variation in the spatial stress field in some parts of the fault system is to be expected. For the chosen assumptions the dimension of this variation is about 25% of the assumed stresses. Future work on this model might focus on the characteristics of the fault system, as well as on the influence of the coupled thermal–hydraulic–mechanical effects.