25 results
Search Results
Now showing 1 - 10 of 25
- ItemAtomic oxygen number densities in the mesosphere–lower thermosphere region measured by solid electrolyte sensors onWADIS-2(Katlenburg-Lindau : Copernicus, 2019) Eberhart, Martin; Löhle, Stefan; Strelnikov, Boris; Hedin, Jonas; Khaplanov, Mikhail; Fasoulas, Stefanos; Gumbel, Jörg; Lübken, Franz-Josef; Rapp, MarkusAbsolute profiles of atomic oxygen number densities with high vertical resolution have been determined in the mesosphere-lower thermosphere (MLT) region from in situ measurements by several rocket-borne solid electrolyte sensors. The amperometric sensors were operated in both controlled and uncontrolled modes and with various orientations on the foredeck and aft deck of the payload. Calibration was based on mass spectrometry in a molecular beam containing atomic oxygen produced in a microwave discharge. The sensor signal is proportional to the number flux onto the electrodes, and the mass flow rate in the molecular beam was additionally measured to derive this quantity from the spectrometer reading. Numerical simulations provided aerodynamic correction factors to derive the atmospheric number density of atomic oxygen from the sensor data. The flight results indicate a preferable orientation of the electrode surface perpendicular to the rocket axis. While unstable during the upleg, the density profiles measured by these sensors show an excellent agreement with the atmospheric models and photometer results during the downleg of the trajectory. The high spatial resolution of the measurements allows for the identification of small-scale variations in the atomic oxygen concentration. © Author(s) 2019. This work is distributed under the Creative Commons Attribution 4.0 License.
- ItemResults and recommendations from an intercomparison of six Hygroscopicity-TDMA systems(München : European Geopyhsical Union, 2011) Massling, A.; Niedermeier, N.; Hennig, T.; Fors, E.O.; Swietlicki, E.; Ehn, M.; Hämeri, K.; Villani, P.; Laj, P.; Good, N.; McFiggans, G.; Wiedensohler, A.The performance of six custom-built Hygrocopicity-Tandem Differential Mobility Analyser (H-TDMA) systems was investigated in the frame of an international calibration and intercomparison workshop held in Leipzig, February 2006. The goal of the workshop was to harmonise H-TDMA measurements and develop recommendations for atmospheric measurements and their data evaluation. The H-TDMA systems were compared in terms of the sizing of dry particles, relative humidity (RH) uncertainty, and consistency in determination of number fractions of different hygroscopic particle groups. The experiments were performed in an air-conditioned laboratory using ammonium sulphate particles or an external mixture of ammonium sulphate and soot particles. The sizing of dry particles of the six H-TDMA systems was within 0.2 to 4.2% of the selected particle diameter depending on investigated size and individual system. Measurements of ammonium sulphate aerosol found deviations equivalent to 4.5% RH from the set point of 90% RH compared to results from previous experiments in the literature. Evaluation of the number fraction of particles within the clearly separated growth factor modes of a laboratory generated externally mixed aerosol was done. The data from the H-TDMAs was analysed with a single fitting routine to investigate differences caused by the different data evaluation procedures used for each H-TDMA. The differences between the H-TDMAs were reduced from +12/−13% to +8/−6% when the same analysis routine was applied. We conclude that a common data evaluation procedure to determine number fractions of externally mixed aerosols will improve the comparability of H-TDMA measurements. It is recommended to ensure proper calibration of all flow, temperature and RH sensors in the systems. It is most important to thermally insulate the aerosol humidification unit and the second DMA and to monitor these temperatures to an accuracy of 0.2 °C. For the correct determination of external mixtures, it is necessary to take into account size-dependent losses due to diffusion in the plumbing between the DMAs and in the aerosol humidification unit.
- ItemNano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) for investigating hygroscopic properties of sub-10nm aerosol nanoparticles(Katlenburg-Lindau : Copernicus, 2020) Lei, Ting; Ma, Nan; Hong, Juan; Tuch, Thomas; Wang, Xin; Wang, Zhibin; Pöhlker, Mira; Ge, Maofa; Wang, Weigang; Mikhailov, Eugene; Hoffmann, Thorsten; Pöschl, Ulrich; Su, Hang; Wiedensohler, Alfred; Cheng, YafangInteractions between water and nanoparticles are relevant for atmospheric multiphase processes, physical chemistry, and materials science. Current knowledge of the hygroscopic and related physicochemical properties of nanoparticles, however, is restricted by the limitations of the available measurement techniques. Here, we present the design and performance of a nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) apparatus that enables high accuracy and precision in hygroscopic growth measurements of aerosol nanoparticles with diameters less than 10 nm. Detailed methods of calibration and validation are provided. Besides maintaining accurate and stable sheath and aerosol flow rates (1 %), high accuracy of the differential mobility analyzer (DMA) voltage (0:1 %) in the range of 0-50V is crucial for achieving accurate sizing and small sizing offsets between the two DMAs (1:4 %). To maintain a stable relative humidity (RH), the humidification system and the second DMA are placed in a well-insulated and air conditioner housing (0:1 K). We also tested and discussed different ways of preventing predeliquescence in the second DMA. Our measurement results for ammonium sulfate nanoparticles are in good agreement with Biskos et al. (2006b), with no significant size effect on the deliquescence and efflorescence relative humidity (DRH and ERH, respectively) at diameters down to 6 nm. For sodium sulfate nanoparticles, however, we find a pronounced size dependence of DRH and ERH between 20 and 6 nm nanoparticles. © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License.
- ItemEmulating atmosphere-ocean and carbon cycle models with a simpler model, MAGICC6 - Part 2: Applications(München : European Geopyhsical Union, 2011) Meinshausen, M.; Raper, S.C.B.; Wigley, T.M.L.Intercomparisons of coupled atmosphere-ocean general circulation models (AOGCMs) and carbon cycle models are important for galvanizing our current scientific knowledge to project future climate. Interpreting such intercomparisons faces major challenges, not least because different models have been forced with different sets of forcing agents. Here, we show how an emulation approach with MAGICC6 can address such problems. In a companion paper (Meinshausen et al., 2011a), we show how the lower complexity carbon cycle-climate model MAGICC6 can be calibrated to emulate, with considerable accuracy, globally aggregated characteristics of these more complex models. Building on that, we examine here the Coupled Model Intercomparison Project's Phase 3 results (CMIP3). If forcing agents missed by individual AOGCMs in CMIP3 are considered, this reduces ensemble average temperature change from pre-industrial times to 2100 under SRES A1B by 0.4 °C. Differences in the results from the 1980 to 1999 base period (as reported in IPCC AR4) to 2100 are negligible, however, although there are some differences in the trajectories over the 21st century. In a second part of this study, we consider the new RCP scenarios that are to be investigated under the forthcoming CMIP5 intercomparison for the IPCC Fifth Assessment Report. For the highest scenario, RCP8.5, relative to pre-industrial levels, we project a median warming of around 4.6 °C by 2100 and more than 7 °C by 2300. For the lowest RCP scenario, RCP3-PD, the corresponding warming is around 1.5 °C by 2100, decreasing to around 1.1 °C by 2300 based on our AOGCM and carbon cycle model emulations. Implied cumulative CO2 emissions over the 21st century for RCP8.5 and RCP3-PD are 1881 GtC (1697 to 2034 GtC, 80% uncertainty range) and 381 GtC (334 to 488 GtC), when prescribing CO2 concentrations and accounting for uncertainty in the carbon cycle. Lastly, we assess the reasons why a previous MAGICC version (4.2) used in IPCC AR4 gave roughly 10% larger warmings over the 21st century compared to the CMIP3 average. We find that forcing differences and the use of slightly too high climate sensitivities inferred from idealized high-forcing runs were the major reasons for this difference.
- ItemA model-based constraint on CO2 fertilisation(München : European Geopyhsical Union, 2013) Holden, P.B.; Edwards, N.R.; Gerten, D.; Schaphoff, S.We derive a constraint on the strength of CO2 fertilisation of the terrestrial biosphere through a "top-down" approach, calibrating Earth system model parameters constrained by the post-industrial increase of atmospheric CO2 concentration. We derive a probabilistic prediction for the globally averaged strength of CO2 fertilisation in nature, for the period 1850 to 2000 AD, implicitly net of other limiting factors such as nutrient availability. The approach yields an estimate that is independent of CO2 enrichment experiments. To achieve this, an essential requirement was the incorporation of a land use change (LUC) scheme into the GENIE Earth system model. Using output from a 671-member ensemble of transient GENIE simulations, we build an emulator of the change in atmospheric CO2 concentration change since the preindustrial period. We use this emulator to sample the 28-dimensional input parameter space. A Bayesian calibration of the emulator output suggests that the increase in gross primary productivity (GPP) in response to a doubling of CO2 from preindustrial values is very likely (90% confidence) to exceed 20%, with a most likely value of 40–60%. It is important to note that we do not represent all of the possible contributing mechanisms to the terrestrial sink. The missing processes are subsumed into our calibration of CO2 fertilisation, which therefore represents the combined effect of CO2 fertilisation and additional missing processes. If the missing processes are a net sink then our estimate represents an upper bound. We derive calibrated estimates of carbon fluxes that are consistent with existing estimates. The present-day land–atmosphere flux (1990–2000) is estimated at −0.7 GTC yr−1 (likely, 66% confidence, in the range 0.4 to −1.7 GTC yr−1). The present-day ocean–atmosphere flux (1990–2000) is estimated to be −2.3 GTC yr−1 (likely in the range −1.8 to −2.7 GTC yr−1). We estimate cumulative net land emissions over the post-industrial period (land use change emissions net of the CO2 fertilisation and climate sinks) to be 66 GTC, likely to lie in the range 0 to 128 GTC.
- ItemACTRIS ACSM intercomparison - Part 1: Reproducibility of concentration and fragment results from 13 individual Quadrupole Aerosol Chemical Speciation Monitors (Q-ACSM) and consistency with co-located instruments(München : European Geopyhsical Union, 2015) Crenn, V.; Sciare, J.; Croteau, P.L.; Verlhac, S.; Fröhlich, R.; Belis, C.A.; Aas, W.; Äijälä, M.; Alastuey, A.; Artiñano, B.; Baisnée, D.; Bonnaire, N.; Bressi, M.; Canagaratna, M.; Canonaco, F.; Carbone, C.; Cavalli, F.; Coz, E.; Cubison, M.J.; Esser-Gietl, J.K.; Green, D.C.; Gros, V.; Heikkinen, L.; Herrmann, H.; Lunder, C.; Minguillón, M.C.; Močnik, G.; O'Dowd, C.D.; Ovadnevaite, J.; Petit, J.-E.; Petralia, E.; Poulain, L.; Priestman, M.; Riffault, V.; Ripoll, A.; Sarda-Estève, R.; Slowik, J.G.; Setyan, A.; Wiedensohler, A.; Baltensperger, U.; Prévôt, A.S.H.; Jayne, J.T.; Favez, O.As part of the European ACTRIS project, the first large Quadrupole Aerosol Chemical Speciation Monitor (Q-ACSM) intercomparison study was conducted in the region of Paris for 3 weeks during the late-fall – early-winter period (November–December 2013). The first week was dedicated to the tuning and calibration of each instrument, whereas the second and third were dedicated to side-by-side comparison in ambient conditions with co-located instruments providing independent information on submicron aerosol optical, physical, and chemical properties. Near real-time measurements of the major chemical species (organic matter, sulfate, nitrate, ammonium, and chloride) in the non-refractory submicron aerosols (NR-PM1) were obtained here from 13 Q-ACSM. The results show that these instruments can produce highly comparable and robust measurements of the NR-PM1 total mass and its major components. Taking the median of the 13 Q-ACSM as a reference for this study, strong correlations (r2 > 0.9) were observed systematically for each individual Q-ACSM across all chemical families except for chloride for which three Q-ACSMs showing weak correlations partly due to the very low concentrations during the study. Reproducibility expanded uncertainties of Q-ACSM concentration measurements were determined using appropriate methodologies defined by the International Standard Organization (ISO 17025, 1999) and were found to be 9, 15, 19, 28, and 36 % for NR-PM1, nitrate, organic matter, sulfate, and ammonium, respectively. However, discrepancies were observed in the relative concentrations of the constituent mass fragments for each chemical component. In particular, significant differences were observed for the organic fragment at mass-to-charge ratio 44, which is a key parameter describing the oxidation state of organic aerosol. Following this first major intercomparison exercise of a large number of Q-ACSMs, detailed intercomparison results are presented, along with a discussion of some recommendations about best calibration practices, standardized data processing, and data treatment.
- ItemCalibration of Raman lidar water vapor profiles by means of AERONET photometer observations and GDAS meteorological data(München : European Geopyhsical Union, 2018) Dai, Guangyao; Althausen, Dietrich; Hofer, Julian; Engelmann, Ronny; Seifert, Patric; Bühl, Johannes; Mamouri, Rodanthi-Elisavet; Wu, Songhua; Ansmann, AlbertWe present a practical method to continuously calibrate Raman lidar observations of water vapor mixing ratio profiles. The water vapor profile measured with the multiwavelength polarization Raman lidar PollyXT is calibrated by means of co-located AErosol RObotic NETwork (AERONET) sun photometer observations and Global Data Assimilation System (GDAS) temperature and pressure profiles. This method is applied to lidar observations conducted during the Cyprus Cloud Aerosol and Rain Experiment (CyCARE) in Limassol, Cyprus. We use the GDAS temperature and pressure profiles to retrieve the water vapor density. In the next step, the precipitable water vapor from the lidar observations is used for the calibration of the lidar measurements with the sun photometer measurements. The retrieved calibrated water vapor mixing ratio from the lidar measurements has a relative uncertainty of 11 % in which the error is mainly caused by the error of the sun photometer measurements. During CyCARE, nine measurement cases with cloud-free and stable meteorological conditions are selected to calculate the precipitable water vapor from the lidar and the sun photometer observations. The ratio of these two precipitable water vapor values yields the water vapor calibration constant. The calibration constant for the PollyXT Raman lidar is 6.56 g kg−1 ± 0.72 g kg−1 (with a statistical uncertainty of 0.08 g kg−1 and an instrumental uncertainty of 0.72 g kg−1). To check the quality of the water vapor calibration, the water vapor mixing ratio profiles from the simultaneous nighttime observations with Raman lidar and Vaisala radiosonde sounding are compared. The correlation of the water vapor mixing ratios from these two instruments is determined by using all of the 19 simultaneous nighttime measurements during CyCARE. Excellent agreement with the slope of 1.01 and the R2 of 0.99 is found. One example is presented to demonstrate the full potential of a well-calibrated Raman lidar. The relative humidity profiles from lidar, GDAS (simulation) and radiosonde are compared, too. It is found that the combination of water vapor mixing ratio and GDAS temperature profiles allow us to derive relative humidity profiles with the relative uncertainty of 10–20 %.
- ItemMaritime aerosol network as a component of AERONET - First results and comparison with global aerosol models and satellite retrievals(München : European Geopyhsical Union, 2011) Smirnov, A.; Holben, B.N.; Giles, D.M.; Slutsker, I.; O'Neill, N.T.; Eck, T.F.; Macke, A.; Croot, P.; Courcoux, Y.; Sakerin, S.M.; Smyth, T.J.; Zielinski, T.; Zibordi, G.; Goes, J.I.; Harvey, M.J.; Quinn, P.K.; Nelson, N.B.; Radionov, V.F.; Duarte, C.M.; Losno, R.; Sciare, J.; Voss, K.J.; Kinne, S.; Nalli, N.R.; Joseph, E.; Krishna Moorthy, K.; Covert, D.S.; Gulev, S.K.; Milinevsky, G.; Larouche, P.; Belanger, S.; Horne, E.; Chin, M.; Remer, L.A.; Kahn, R.A.; Reid, J.S.; Schulz, M.; Heald, C.L.; Zhang, J.; Lapina, K.; Kleidman, R.G.; Griesfeller, J.; Gaitley, B.J.; Tan, Q.; Diehl, T.L.The Maritime Aerosol Network (MAN) has been collecting data over the oceans since November 2006. Over 80 cruises were completed through early 2010 with deployments continuing. Measurement areas included various parts of the Atlantic Ocean, the Northern and Southern Pacific Ocean, the South Indian Ocean, the Southern Ocean, the Arctic Ocean and inland seas. MAN deploys Microtops hand-held sunphotometers and utilizes a calibration procedure and data processing traceable to AERONET. Data collection included areas that previously had no aerosol optical depth (AOD) coverage at all, particularly vast areas of the Southern Ocean. The MAN data archive provides a valuable resource for aerosol studies in maritime environments. In the current paper we present results of AOD measurements over the oceans, and make a comparison with satellite AOD retrievals and model simulations.
- ItemSoot reference materials for instrument calibration and intercomparisons: A workshop summary with recommendations(München : European Geopyhsical Union, 2012) Baumgardner, D.; Popovicheva, O.; Allan, J.; Bernardoni, V.; Cao, J.; Cavalli, F.; Cozic, J.; Courcoux, Y.; Diapouli, E.; Eleftheriadis, K.; Genberg, P.J.; Gonzalez, C.; Gysel, M.; John, A.; Kirchstetter, T.W.; Kuhlbusch, T.A.J.; Laborde, M.; Lack, D.; Müller, T.; Niessner, R.; Petzold, A.; Piazzalunga, A.; Putaud, J.P.; Schwarz, J.; Sheridan, P.; Subramanian, R.; Swietlicki, E.; Valli, G.; Vecchi, R.; Viana, M.Soot, which is produced from biomass burning and the incomplete combustion of fossil and biomass fuels, has been linked to regional and global climate change and to negative health problems. Scientists measure the properties of soot using a variety of methods in order to quantify source emissions and understand its atmospheric chemistry, reactivity under emission conditions, interaction with solar radiation, influence on clouds, and health impacts. A major obstacle currently limiting progress is the absence of established standards or reference materials for calibrating the many instruments used to measure the various properties of soot. The current state of availability and practicability of soot standard reference materials (SRMs) was reviewed by a group of 50 international experts during a workshop in June of 2011. The workshop was convened to summarize the current knowledge on soot measurement techniques, identify the measurement uncertainties and limitations related to the lack of soot SRMs, and identify attributes of SRMs that, if developed, would reduce measurement uncertainties. The workshop established that suitable SRMs are available for calibrating some, but not all, measurement methods. The community of users of the single-particle soot-photometer (SP2), an instrument using laser-induced incandescence, identified a suitable SRM, fullerene soot, but users of instruments that measure light absorption by soot collected on filters did not. Similarly, those who use thermal optical analysis (TOA) to analyze the organic and elemental carbon components of soot were not satisfied with current SRMs. The workshop, and subsequent, interactive discussions, produced a number of recommendations for the development of new SRMs, and their implementation, that would be suitable for the different soot measurement methods.
- ItemCombined wind measurements by two different lidar instruments in the Arctic middle atmosphere(Göttingen : Copernicus, 2012) Hildebrand, J.; Baumgarten, G.; Fiedler, J.; Hoppe, U.-P.; Kaifler, B.; Lübken, F.-J.; Williams, B.P.During a joint campaign in January 2009, the Rayleigh/Mie/Raman (RMR) lidar and the sodium lidar at the ALOMAR Observatory (69 N, 16 E) in Northern Norway were operated simultaneously for more than 40 h, collecting data for wind measurements in the middle atmosphere from 30 up to 110 km altitude. As both lidars share the same receiving telescopes, the upper altitude range of the RMR lidar and the lower altitude range of the sodium lidar overlap in the altitude region of ≈80-85 km. For this overlap region we are thus able to present the first simultaneous wind measurements derived from two different lidar instruments. The comparison of winds derived by RMR and sodium lidar is excellent for long integration times of 10 h as well as shorter ones of 1 h. Combination of data from both lidars allows identifying wavy structures between 30 and 110 km altitude, whose amplitudes increase with height. We have also performed vertical wind measurements and measurements of the same horizontal wind component using two independent lasers and telescopes of the RMR lidar and show how to use this data to calibrate and validate the wind retrieval. For the latter configuration we found a good agreement of the results but also identified inhomogeneities in the horizontal wind at about 55 km altitude of up to 20 ms-1 for an integration time of nearly 4 h. Such small-scale inhomogeneities in the horizontal wind field are an essential challenge when comparing data from different instruments.
- «
- 1 (current)
- 2
- 3
- »