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search.filters.applied.f.access: openAccess × End date: 2012 × Start date: 2012 × Type: Text × Subject: Dispersion ×

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    Methods to characterize the dispersability of carbon nanotubes and their length distribution
    (Weinheim : Wiley-VCH Verl., 2012) Krause, Beate; Mende, Mandy; Petzold, Gudrun; Boldt, Regine; Pötschke, Petra
    Two main properties of carbon nanotube (CNT) materials are discussed in this contribution. First, a method to characterize the dispersability of CNT materials in aqueous surfactant solutions in presented, which also allows conclusions towards the dispersability in other media, like polymer melts. On the other hand it is shown, how the length of CNTs before and after processing, e.g., after melt mixing with thermoplastics, can be quantified. Both methods are illustrated with examples and the practical relevance is shown. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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    A successful approach to disperse MWCNTs in polyethylene by melt mixing using polyethylene glycol as additive
    (Oxford : Elsevier Science, 2012) Müller, Michael Thomas; Krause, Beate; Pötschke, Petra
    An additive-assisted one-step melt mixing approach was developed to produce nanocomposites based on linear low density polyethylene (LLDPE) with multiwalled carbon nanotube (MWCNT). The polymer granules, nanotube powder (2 wt% Nanocyl™ NC7000) and 1-10 wt% of the non-ionic additives poly(ethylene glycol) (PEG) or poly(ethylene oxide) (PEO) with molar masses between 100 g/mol and 100,000 g/mol were simply fed together in the hopper of a small-scale DSM Xplore 15 twin-screw microcompounder. The produced MWCNT/LLDPE composites showed excellent MWCNT dispersion and highly improved electrical properties as compared to samples without the additive, whereas the effects depend on the amount and molar mass of the additive. When 7 wt% PEG (2000 g/mol) were used, a reduction of the electrical percolation threshold from 2.5 wt% to 1.5 wt% was achieved. © 2012 Elsevier Ltd. All rights reserved.
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    Few-cycle optical solitons in dispersive media beyond the envelope approximation
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2012) Amiranashvili, Shalva; Bandelow, Uwe; Akhmediev, Nail
    We study the propagation of few-cycle optical solitons in nonlinear media with an anomalous, but otherwise arbitrary, dispersion and a cubic nonlinearity. Our theory extends beyond the slowly varying envelope approximation. The optical field is derived directly from the Maxwell equations under the assumption that generation of the third harmonic is a non-resonant process or at least cannot destroy the pulse prior to inevitable linear damping. The solitary wave solutions are obtained numerically up to nearly single-cycle duration using a modification of the spectral renormalisation method originally developed for the envelope solitons.