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- ItemArtificial Intelligence for the Prediction of the Thermal Performance of Evaporative Cooling Systems(Basel : MDPI, 2021) Asfahan, Hafiz M.; Sajjad, Uzair; Sultan, Muhammad; Hussain, Imtiyaz; Hamid, Khalid; Ali, Mubasher; Wang, Chi-Chuan; Shamshiri, Redmond R.; Khan, Muhammad UsmanThe present study reports the development of a deep learning artificial intelligence (AI) model for predicting the thermal performance of evaporative cooling systems, which are widely used for thermal comfort in different applications. The existing, conventional methods for the analysis of evaporation-assisted cooling systems rely on experimental, mathematical, and empirical approaches in order to determine their thermal performance, which limits their applications in diverse and ambient spatiotemporal conditions. The objective of this research was to predict the thermal performance of three evaporation-assisted air-conditioning systems—direct, indirect, and Maisotsenko evaporative cooling systems—by using an AI approach. For this purpose, a deep learning algorithm was developed and lumped hyperparameters were initially chosen. A correlation analysis was performed prior to the development of the AI model in order to identify the input features that could be the most influential for the prediction efficiency. The deep learning algorithm was then optimized to increase the learning rate and predictive accuracy with respect to experimental data by tuning the hyperparameters, such as by manipulating the activation functions, the number of hidden layers, and the neurons in each layer by incorporating optimizers, including Adam and RMsprop. The results confirmed the applicability of the method with an overall value of R2 = 0.987 between the input data and ground-truth data, showing that the most competent model could predict the designated output features (Tdbout, wout, and Eairout). The suggested method is straightforward and was found to be practical in the evaluation of the thermal performance of deployed air conditioning systems under different conditions. The results supported the hypothesis that the proposed deep learning AI algorithm has the potential to explore the feasibility of the three evaporative cooling systems in dynamic ambient conditions for various agricultural and livestock applications.
- ItemComparative Studies on Water- and Vapor-Based Hydrothermal Carbonization: Process Analysis(Basel : MDPI, 2020) Ro, Kyoung S.; Libra, Judy A.; Alvarez-Murillo, AndrésHydrothermal carbonization (HTC) reactor systems used to convert wet organic wastes into value-added hydrochar are generally classified in the literature as liquid water-based (HTC) or vapor-based (VTC). However, the distinction between the two is often ambiguous. In this paper, we present a methodological approach to analyze process conditions for hydrothermal systems. First, we theoretically developed models for predicting reactor pressure, volume fraction of liquid water and water distribution between phases as a function of temperature. The reactor pressure model predicted the measured pressure reasonably well. We also demonstrated the importance of predicting the condition at which the reactor system enters the subcooled compression liquid region to avoid the danger of explosion. To help understand water–feedstock interactions, we defined a new solid content parameter %S(T) based on the liquid water in physical contact with feedstock, which changes with temperature due to changes in the water distribution. Using these models, we then compared the process conditions of seven different HTC/VTC cases reported in the literature. This study illustrates that a large range of conditions need to be considered before applying the label VTC or HTC. These tools can help in designing experiments to compare systems and understand results in future HTC research
- ItemProcess Analysis of Main Organic Compounds Dissolved in Aqueous Phase by Hydrothermal Processing of Açaí (Euterpe oleraceae, Mart.) Seeds: Influence of Process Temperature, Biomass-to-Water Ratio, and Production Scales(Basel : MDPI, 2021) da Silva, Conceição de Maria Sales; de Castro, Douglas Alberto Rocha; Santos, Marcelo Costa; Almeida, Hélio da Silva; Schultze, Maja; Lüder, Ulf; Hoffmann, Thomas; Machado, Nélio TeixeiraThis work aims to systematically investigate the influence of process temperature, biomass-to-water ratio, and production scales (laboratory and pilot) on the chemical composition of aqueous and gaseous phases and mass production of chemicals by hydrothermal processing of Açaí (Euterpe oleraceae, Mart.) seeds. The hydrothermal carbonization was carried out at 175, 200, 225, and 250 °C at 2 °C/min and a biomass-to-water ratio of 1:10; at 250 °C at 2 °C/min and biomass-to-water ratios of 1:10, 1:15, and 1:20 in technical scale; and at 200, 225, and 250 °C at 2 °C/min and a biomass-to-water ratio of 1:10 in laboratory scale. The elemental composition (C, H, N, S) in the solid phase was determined to compute the HHV. The chemical composition of the aqueous phase was determined by GC and HPLC and the volumetric composition of the gaseous phase using an infrared gas analyzer. For the experiments in the pilot test scale with a constant biomass-to-water ratio of 1:10, the yields of solid, liquid, and gaseous phases varied between 53.39 and 37.01% (wt.), 46.61 and 59.19% (wt.), and 0.00 and 3.80% (wt.), respectively. The yield of solids shows a smooth exponential decay with temperature, while that of liquid and gaseous phases showed a smooth growth. By varying the biomass-to-water ratios, the yields of solid, liquid, and gaseous reaction products varied between 53.39 and 32.09% (wt.), 46.61 and 67.28% (wt.), and 0.00 and 0.634% (wt.), respectively. The yield of solids decreased exponentially with increasing water-to-biomass ratio, and that of the liquid phase increased in a sigmoid fashion. For a constant biomass-to-water ratio, the concentrations of furfural and HMF decreased drastically with increasing temperature, reaching a minimum at 250 °C, while that of phenols increased. In addition, the concentrations of CH3COOH and total carboxylic acids increased, reaching a maximum concentration at 250 °C. For constant process temperature, the concentrations of aromatics varied smoothly with temperature. The concentrations of furfural, HMF, and catechol decreased with temperature, while that of phenols increased. The concentrations of CH3COOH and total carboxylic acids decreased exponentially with temperature. Finally, for the experiments with varying water-to-biomass ratios, the productions of chemicals (furfural, HMF, phenols, cathecol, and acetic acid) in the aqueous phase is highly dependent on the biomass-to-water ratio. For the experiments at the laboratory scale with a constant biomass-to-water ratio of 1:10, the yields of solids ranged between 55.9 and 51.1% (wt.), showing not only a linear decay with temperature but also a lower degradation grade. The chemical composition of main organic compounds (furfural, HMF, phenols, catechol, and acetic acid) dissolved in the aqueous phase in laboratory-scale study showed the same behavior as those obtained in the pilot-scale study.
- ItemInvestigation of Energy Consumption and Associated CO2 Emissions for Wheat–Rice Crop Rotation Farming(Basel : MDPI, 2021) Ashraf, Muhammad N.; Mahmood, Muhammad H.; Sultan, Muhammad; Shamshiri, Redmond R.; Ibrahim, Sobhy M.This study investigates the input–output energy-flow patterns and CO2 emissions from the wheat–rice crop rotation system. In this regard, an arid region of Punjab, Pakistan was selected as the study area, comprising 4150 km2. Farmers were interviewed to collect data and information on input/output sources during the 2020 work season. The total energy from these sources was calculated using appropriate energy equivalents. Three energy indices, including energy use efficiency (ηe), energy productivity (ηp), and net energy (ρ), were defined and calculated to investigate overall energy efficiency. Moreover, the data envelopment analysis (DEA) technique was used to optimize the input energy in wheat and rice production. Finally, CO2 emissions was calculated using emissions equivalents from peer-reviewed published literature. Results showed that the average total energy consumption in rice production was twice the energy consumed in wheat production. However, the values of ηe, ηp, and ρ were higher in wheat production and calculated as 5.68, 202.3 kg/GJ, and 100.12 GJ/ha, respectively. The DEA showed the highest reduction potential in machinery energy for both crops, calculated as −42.97% in rice production and −17.48% in wheat production. The highest CO2 emissions were found in rice production and calculated as 1762.5 kg-CO2/ha. Our conclusion indicates that energy consumption and CO2 emissions from wheat–rice cropping systems can be minimized using optimized energy inputs.
- ItemThe Impacts of Water Pricing and Non-Pricing Policies on Sustainable Water Resources Management: A Case of Ghorveh Plain at Kurdistan Province, Iran(Basel : MDPI, 2019) Asaadi, Mohammad Ali; Mortazavi, Seyed Abolghasem; Zamani, Omid; Najafi, Gholam Hassan; Yusaf, Talal; Hoseini, Seyed SalarAs with other regions of Iran, due to excessive extraction of groundwater for intense agricultural activity, Ghorveh plain, a water-scarce irrigation district in the west of Iran, has faced a serious water crisis during the last decade. The present study investigates the impacts of two scenario policies, namely, non-price policy (as a supply-oriented policy) and water pricing policies (as a demand-oriented policy) on agricultural sector of Ghorveh Plain, using positive mathematical programming (PMP). The model was calibrated by using farm-level data for the crop years in 2016–2017. Our findings indicate that applying water supply constraint policy will change the land use and cropping pattern to the crops with higher water productivity. The increase of water resource constraints can lead to the increase of water economic return which indicates a rising value of water resources shortage, warning the producers of the agriculture sector to allocate water to the crops with higher economic value under the water resources shortage conditions. In addition, the findings underline that in a situation where the price of irrigation water is low due to the low elasticity of water demand in the agriculture sector, formulating the economic instruments such as rising water prices does not solely suffice to achieve sustainable water resource management. However, mixed scenarios emphasized that the water distribution policies should be aligned with the increases in water cost. © 2019 by the authors.
- ItemComprehensive Assessment of the Dynamics of Banana Chilling Injury by Advanced Optical Techniques(Basel : MDPI, 2021) Herppich, Werner B.; Zsom, TamásGreen‐ripe banana fruit are sensitive to chilling injury (CI) and, thus, prone to postharvest quality losses. Early detection of CI facilitates quality maintenance and extends shelf life. CI affects all metabolic levels, with membranes and, consequently, photosynthesis being primary targets. Optical techniques such as chlorophyll a fluorescence analysis (CFA) and spectroscopy are promising tools to evaluate CI effects in photosynthetically active produce. Results obtained on bananas are, however, largely equivocal. This results from the lack of a rigorous evaluation of chilling impacts on the various aspects of photosynthesis. Continuous and modulated CFA and imaging (CFI), and VIS remission spectroscopy (VRS) were concomitantly applied to noninvasively and comprehensively monitor photosynthetically relevant effects of low temperatures (5 °C, 10 °C, 11.5 °C and 13 °C). Detailed analyses of chilling‐related variations in photosynthetic activity and photoprotection, and in contents of relevant pigments in green‐ripe bananas, helped to better understand the physiological changes occurring during CI, highlighting that distinct CFA and VRS parameters comprehensively reflect various effects of chilling on fruit photosynthesis. They revealed why not all CFA parameters can be applied meaningfully for early detection of chilling effects. This study provides relevant requisites for improving CI monitoring and prediction.
- ItemEffect of Liquid Hot Water Pretreatment on Hydrolysates Composition and Methane Yield of Rice Processing Residue(Basel : MDPI, 2021) López González, Lisbet Mailin; Heiermann, MonikaLignocellulosic rice processing residue was pretreated in liquid hot water (LHW) at three different temperatures (140, 160, and 180 °C) and two pretreatment times (10 and 20 min) in order to assess its effects on hydrolysates composition, matrix structural changes and methane yield. The concentrations of acetic acid, 5-hydroxymethylfurfural and furfural increased with pretreatment severity (log Ro). The maximum methane yield (276 L kg−1 VS) was achieved under pretreatment conditions of 180 °C for 20 min, with a 63% increase compared to untreated biomass. Structural changes resulted in a slight removal of silica on the upper portion of rice husks, visible predominantly at maximum severity. However, the outer epidermis was kept well organized. The results indicate, at severities 2.48 ≤ log Ro ≤ 3.66, a significant potential for the use of LHW to improve methane production from rice processing residue.
- ItemHydrothermal Carbonization: Modeling, Final Properties Design and Applications: A Review(Basel : MDPI, 2018-1-16) Román, Silvia; Libra, Judy; Berge, Nicole; Sabio, Eduardo; Ro, Kyoung; Li, Liang; Ledesma, Beatriz; Álvarez, Andrés; Bae, SunyoungActive research on biomass hydrothermal carbonization (HTC) continues to demonstrate its advantages over other thermochemical processes, in particular the interesting benefits that are associated with carbonaceous solid products, called hydrochar (HC). The areas of applications of HC range from biofuel to doped porous material for adsorption, energy storage, and catalysis. At the same time, intensive research has been aimed at better elucidating the process mechanisms and kinetics, and how the experimental variables (temperature, time, biomass load, feedstock composition, as well as their interactions) affect the distribution between phases and their composition. This review provides an analysis of the state of the art on HTC, mainly with regard to the effect of variables on the process, the associated kinetics, and the characteristics of the solid phase (HC), as well as some of the more studied applications so far. The focus is on research made over the last five years on these topics. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.
- ItemDynamic Evaluation of Desiccant Dehumidification Evaporative Cooling Options for Greenhouse Air-Conditioning Application in Multan (Pakistan)(Basel : MDPI, 2021) Ashraf, Hadeed; Sultan, Muhammad; Shamshiri, Redmond R.; Abbas, Farrukh; Farooq, Muhammad; Sajjad, Uzair; Md-Tahir, Hafiz; Mahmood, Muhammad H.; Ahmad, Fiaz; Taseer, Yousaf R.; Shahzad, Aamir; Niazi, Badar M.K.This study provides insights into the feasibility of a desiccant dehumidification-based Maisotsenko cycle evaporative cooling (M-DAC) system for greenhouse air-conditioning application. Conventional cooling techniques include direct evaporative cooling, refrigeration systems, and passive/active ventilation. which are commonly used in Pakistan; however, they are either not feasible due to their energy cost, or they cannot efficiently provide an optimum microclimate depending on the regions, the growing seasons, and the crop being cultivated. The M-DAC system was therefore proposed and evaluated as an alternative solution for air conditioning to achieve optimum levels of vapor pressure deficit (VPD) for greenhouse crop production. The objective of this study was to investigate the thermodynamic performance of the proposed system from the viewpoints of the temperature gradient, relative humidity level, VPD, and dehumidification gradient. Results showed that the standalone desiccant air-conditioning (DAC) system created maximum dehumidification gradient (i.e., 16.8 g/kg) and maximum temperature gradient (i.e., 8.4 °C) at 24.3 g/kg and 38.6 °C ambient air conditions, respectively. The DAC coupled with a heat exchanger (DAC+HX) created a temperature gradient nearly equal to ambient air conditions, which is not in the optimal range for greenhouse growing conditions. Analysis of the M-DAC system showed that a maximum air temperature gradient, i.e., 21.9 °C at 39.2 °C ambient air condition, can be achieved, and is considered optimal for most greenhouse crops. Results were validated with two microclimate models (OptDeg and Cft) by taking into account the optimality of VPD at different growth stages of tomato plants. This study suggests that the M-DAC system is a feasible method to be considered as an efficient solution for greenhouse air-conditioning under the climate conditions of Multan (Pakistan).
- ItemAgricultural Monitoring Using Polarimetric Decomposition Parameters of Sentinel-1 Data(Basel : MDPI, 2021) Harfenmeister, Katharina; Itzerott, Sibylle; Weltzien, Cornelia; Spengler, DanielThe time series of synthetic aperture radar (SAR) data are commonly and successfully used to monitor the biophysical parameters of agricultural fields. Because, until now, mainly backscatter coefficients have been analysed, this study examines the potentials of entropy, anisotropy, and alpha angle derived from a dual-polarimetric decomposition of Sentinel-1 data to monitor crop development. The temporal profiles of these parameters are analysed for wheat and barley in the vegetation periods 2017 and 2018 for 13 fields in two test sites in Northeast Germany. The relation between polarimetric parameters and biophysical parameters observed in the field is investigated using linear and exponential regression models that are evaluated using the coefficient of determination (R2) and the root mean square error (RMSE). The performance of single regression models is furthermore compared to those of multiple regression models, including backscatter coefficients in VV and VH polarisation as well as polarimetric decomposition parameters entropy and alpha. Characteristic temporal profiles of entropy, anisotropy, and alpha reflecting the main phenological changes in plants as well as the meteorological differences between the two years are observed for both crop types. The regression models perform best for data from the phenological growth stages tillering to booting. The highest R2 values of the single regression models are reached for the plant height of wheat related to entropy and anisotropy with R2 values of 0.64 and 0.61, respectively. The multiple regression models of VH, VV, entropy, and alpha outperform single regression models in most cases. R2 values of multiple regression models of plant height (0.76), wet biomass (0.7), dry biomass (0.7), and vegetation water content (0.69) improve those of single regression models slightly by up to 0.05. Additionally, the RMSE values of the multiple regression models are around 10% lower compared to those of single regression models. The results indicate the capability of dual-polarimetric decomposition parameters in serving as meaningful input parameters for multiple regression models to improve the prediction of biophysical parameters. Additionally, their temporal profiles indicate phenological development dependent on meteorological conditions. Knowledge about biophysical parameter development and phenology is important for farmers to monitor crop growth variability during the vegetation period to adapt and to optimize field management.
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