6 results
Search Results
Now showing 1 - 6 of 6
- ItemRole of SrCO3 on Photocatalytic Performance of SrTiO3-SrCO3 Composites(Basel : MDPI, 2022) Boga, Bíborka; Steinfeldt, Norbert; Moustakas, Nikolaos G.; Peppel, Tim; Lund, Henrik; Rabeah, Jabor; Pap, Zsolt; Cristea, Vasile-Mircea; Strunk, JenniferPerovskites such as SrTiO3 are interesting for photocatalytic applications due to their structure-related and electronic properties. These properties are influenced by the presence of SrCO3 which is often formed simultaneously during the hydrothermal synthesis of SrTiO3. In this study, SrTiO3-SrCO3 composites with different contents of SrCO3 (5–24 wt%) were synthesized. Their morphological, structural, and optical properties were investigated using complementary methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD), nitrogen sorption, and diffuse reflectance spectroscopy (DRS). Their photocatalytic activity was assessed during the degradation of diclofenac (DCFNa) in aqueous solution and CO2 photoreduction under Xe lamp irradiation. Improved photocatalytic efficiency in DCFNa degradation was observed for all the studied composites in comparison with SrTiO3, and the highest mineralization efficiency was obtained for the sample with 21 wt% SrCO3 content. The presence of SrCO3 led to an increased concentration of active species, such as •OH radicals. Otherwise, its presence inhibits CH4 and C2H6 production during CO2 photoreduction compared with pure SrTiO3.
- ItemA novel approach to fabricate load-bearing Ti6Al4V-Barium titanate piezoelectric bone scaffolds by coupling electron beam melting and field-assisted sintering(Amsterdam [u.a.] : Elsevier Science, 2022) Riaz, Abdullah; Polley, Christian; Lund, Henrik; Springer, Armin; Seitz, HermannA critical-size bone defect in load-bearing areas is a challenging clinical problem in orthopaedic surgery. Titanium alloy (Ti6Al4V) scaffolds have advantages because of their biomechanical stability but lack electrical activity, which hinders their further use. This work is focused on the fabrication of Ti6Al4V-Barium Titanate (BaTiO3) bulk composite scaffolds to combine the biomechanical stability of Ti6Al4V with electrical activity through BaTiO3. For the first time, a hollow cylindrical Ti6Al4V is additively manufactured by electron beam melting and combined with piezoelectric BaTiO3 powder for joint processing in field-assisted sintering. Scanning electron microscope images on the interface of the Ti6Al4V-BaTiO3 composite scaffold showed that after sintering, the Ti6Al4V lattice structure bounded with BaTiO3 matrix without its major deformation. The Ti6Al4V-BaTiO3 scaffold had average piezoelectric constants of (0.63 ± 0.12) pC/N directly after sintering due to partial dipole alignment of the BaTiO3 tetragonal phase, which increased to (4.92 ± 0.75) pC/N after a successful corona poling. Moreover, the nanoindentation values of Ti6Al4V exhibited an average hardness and Young's modulus of (5.9 ± 0.9) GPa and (130 ± 14) GPa, and BaTiO3 showed (4.0 ± 0.6) GPa and (106 ± 10) GPa, respectively. It reveals that the Ti6Al4V is the harder and stiffer part in the Ti6Al4V-BaTiO3 composite scaffold. Such a scaffold has the potential to treat critical-size bone defects in load-bearing areas and guide tissue regeneration by physical stimulation.
- ItemIn situ powder X-ray diffraction during hydrogen reduction of MoO3 to MoO2(Amsterdam [u.a.] : Elsevier Science, 2022) Burgstaller, M.; Lund, H.; O'Sullivan, M.; Huppertz, H.The hydrogen reduction of molybdenum trioxide to molybdenum dioxide is not yet fully understood as evident by continuous scientific interest. Especially the effect of the potassium content on the reduction process has not yet been considered. We prepared several samples of molybdenum trioxide containing varying amounts of potassium by addition of potassium molybdate (K2MoO4). In situ powder X-ray diffraction experiments were then conducted to study the hydrogen reduction of these samples. We especially focused on the influence of the alkali content and on gaining insight into the importance of the intermediary product γ-Mo4O11. During the reduction process, MoO2 is formed from the reduction of MoO3, which then reacts with the starting material to form γ-Mo4O11. With increasing potassium content, the reduction rate is decreased and the fractional content of γ-Mo4O11 built up during the reduction process is increased. As evident from bulk sample reduction, this results in a significant increase in the grain size visualized via scanning electron microscopy. Our investigations once again underline the importance of γ-Mo4O11 on the morphology of the resulting MoO2 powder.
- ItemEfficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations(Weinheim : Wiley-VCH, 2022) Hu, Yuya; Sang, Rui; Vroemans, Robby; Mollaert, Guillaume; Razzaq, Rauf; Neumann, Helfried; Junge, Henrik; Franke, Robert; Jackstell, Ralf; Maes, Bert U. W.; Beller, MatthiasDiesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the “built-in-base” ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (Tg) via differential scanning calorimetry (DSC).
- ItemKinetic investigation of para-nitrophenol reduction with photodeposited platinum nanoparticles onto tunicate cellulose(London : RSC Publishing, 2022) Thiel, T.A.; Zhang, X.; Radhakrishnan, B.; van de Krol, R.; Abdi, F.F.; Schroeter, M.; Schomäcker, R.; Schwarze, M.Photodeposition is a specific method for depositing metallic co-catalysts onto photocatalysts and was applied for immobilizing platinum nanoparticles onto cellulose, a photocatalytically inactive biopolymer. The obtained Pt@cellulose catalysts show narrow and well-dispersed nanoparticles with average sizes between 2 and 5 nm, whereby loading, size and distribution depend on the preparation conditions. The catalysts were investigated for the hydrogenation of para-nitrophenol via transfer hydrogenation using sodium borohydride as the hydrogen source, and the reaction rate constant was determined using the pseudo-first-order reaction rate law. The Pt@cellulose catalysts are catalytically active with rate constant values k from 0.09 × 10−3 to 0.43 × 10−3 min−1, which were higher than the rate constant of a commercial Pt@Al2O3 catalyst (k = 0.09 × 10−3 min−1). Additionally, the Pt@cellulose catalyst can be used for electrochemical hydrogenation of para-nitrophenol where the hydrogen is electrocatalytically formed. The electrochemical hydrogenation is faster compared to the transfer hydrogenation (k = 0.11 min−1).
- ItemDifluoroalkylative carbonylation of alkenes to access carbonyl difluoro-containing heterocycles: convenient synthesis of gemigliptin(Berlin ; Heidelberg : Springer, 2022) Bao, Zhi-Peng; Zhang, Youcan; Wang, Le-Cheng; Wu, Xiao-FengFluorinated heterocycles play a vital role in pharmaceutical and agrochemical industries. Hence, rapid and efficient construction of fluorinated heterocycles remains highly demanded. Herein, a difluoroalkylative carbonylative cyclization of unactivated alkenes and ethylene gas enabled by palladium catalysis has been developed for the first time toward the synthesis of α-carbonyl difluoro-modified glutarimides. This procedure can also be applied to the synthesis of GeMigliptin which is a medicine approved for the treatment of type 2 diabetes mellitus. [Figure not available: see fulltext.]