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- ItemThe bleaching limits of IRSL signals at various stimulation temperatures and their potential inference of the pre-burial light exposure duration(Lausanne : Frontiers Media, 2023) Zhang, Jingran; Guralnik, Benny; Tsukamoto, Sumiko; Ankjærgaard, Christina; Reimann, TonyInfrared Stimulated Luminescence (IRSL) techniques are being increasingly used for dating sedimentary feldspars in the middle to late Quaternary. By employing several subsequent stimulations at increasing temperatures, a series of post-IR IRSL (pIRIR) signals with different characteristics (stability and bleachability) can be obtained for an individual sample. It has been experimentally demonstrated that higher-temperature pIRIR signals are more stable, but they tend to exhibit larger residual doses up to few tens of Gy, potentially causing severe age overestimation in young samples. In this study we conducted comprehensive bleaching experiments of IRSL and pIRIR signals using a loess sample from China, and demonstrated that non-bleachable components in the IR (and possibly pIRIR) signals do exist. The level of such non-bleachable signal shows clearly positive correlation with preheat/stimulation temperature, which further supports the notion that lower temperature pIRIR are advantageous to date young samples and sediments especially from difficult-to-bleach environments. These results display a potential in constrain the pre-burial light exposure history of sediment utilizing multiple feldspar post-IR IRSL (pIRIR) signals. For the studied loess sample, we infer that prior to its last burial, the sample has received an equivalent of >264 h exposure to the SOL2 simulator (more than 2,000 h of natural daylight).
- ItemEditorial: Climatic and Associated Cryospheric and Hydrospheric Changes on the Third Pole(Lausanne : Frontiers Media, 2021) Wang, Lei; Song, Chunqiao; Conradt, Tobias; Rasmy, Mohamed; Li, Xiuping[No abstract available]
- ItemNew Perspectives on Nitrogen Fixation Measurements Using 15N2 Gas(Lausanne : Frontiers Media, 2018-04-06) Wannicke, Nicola; Benavides, Mar; Dalsgaard, Tage; Dippner, Joachim W.; Montoya, Joseph P.; Voss, MarenRecently, the method widely used to determine 15N2 fixation rates in marine and freshwater environments was found to underestimate rates because the dissolution of the added 15N2 gas bubble in seawater takes longer than theoretically calculated. As a solution to the potential underestimate of rate measurements, the usage of the enriched water method was proposed to provide constant 15N2 enrichment. Still, the superiority of enriched water method over the previously used bubble injection remains inconclusive. To clarify this issue, we performed laboratory based experiments and implemented the results into an error analysis of 15N2 fixation rates. Moreover, we conducted a literature search on the comparison of the two methods to calculate a mean effect size using a meta-analysis approach. Our results indicate that the error potentially introduced by an equilibrium phase of the 15N2 gas is −72% at maximum for experiments with very short incubation times of 1 h. In contrast, the underestimation was negligible for incubations lasting 12–24 h (error is −0.2%). Our meta-analysis indicates that 84% of the measurements in the two groups will overlap and there is a 61% chance that a sample picked at random from the enriched water group will have a higher value than one picked at random from the bubble group. Overall, the underestimation of N2 fixation rates when using the bubble method relative to the enriched water method is highly dependent on incubation time and other experimental conditions and cannot be generalized.
- ItemMeasuring Global Signals in the Potential Gradient at High Latitude Sites(Lausanne : Frontiers Media, 2021) Tacza, José; Nicoll, Keri A.; Macotela, Edith L.; Kubicki, Marek; Odzimek, Anna; Manninen, JyrkiPrevious research has shown that the study of the global electrical circuit can be relevant to climate change studies, and this can be done through measurements of the potential gradient near the surface in fair weather conditions. However, potential gradient measurements can be highly variable due to different local effects (e.g., pollution, convective processes). In order to try to minimize these effects, potential gradient measurements can be performed at remote locations where anthropogenic influences are small. In this work we present potential gradient measurements from five stations at high latitudes in the Southern and Northern Hemisphere. This is the first description of new datasets from Halley, Antarctica; and Sodankyla, Finland. The effect of the polar cap ionospheric potential can be significant at some polar stations and detailed analysis performed here demonstrates a negligible effect on the surface potential gradient at Halley and Sodankyla. New criteria for determination of fair weather conditions at snow covered sites is also reported, demonstrating that wind speeds as low as 3 m/s can loft snow particles, and that the fetch of the measurement site is an important factor in determining this threshold wind speed. Daily and seasonal analysis of the potential gradient in fair weather conditions shows great agreement with the “universal” Carnegie curve of the global electric circuit, particularly at Halley. This demonstrates that high latitude sites, at which the magnetic and solar influences can be present, can also provide globally representative measurement sites for study of the global electric circuit.
- ItemThe ocean's vital skin: Toward an integrated understanding of the sea surface microlayer(Lausanne : Frontiers Media, 2017) Engel, Anja; Bange, Hermann W.; Cunliffe, Michael; Burrows, Susannah M.; Friedrichs, Gernot; Galgani, Luisa; Herrmann, Hartmut; Hertkorn, Norbert; Johnson, Martin; Liss, Peter S.; Quinn, Patricia K.; Schartau, Markus; Soloviev, Alexander; Stolle, Christian; Upstill-Goddard, Robert C.; van Pinxteren, Manuela; Zäncker, BirtheDespite the huge extent of the ocean's surface, until now relatively little attention has been paid to the sea surface microlayer (SML) as the ultimate interface where heat, momentum and mass exchange between the ocean and the atmosphere takes place. Via the SML, large-scale environmental changes in the ocean such as warming, acidification, deoxygenation, and eutrophication potentially influence cloud formation, precipitation, and the global radiation balance. Due to the deep connectivity between biological, chemical, and physical processes, studies of the SML may reveal multiple sensitivities to global and regional changes. Understanding the processes at the ocean's surface, in particular involving the SML as an important and determinant interface, could therefore provide an essential contribution to the reduction of uncertainties regarding ocean-climate feedbacks. This review identifies gaps in our current knowledge of the SML and highlights a need to develop a holistic and mechanistic understanding of the diverse biological, chemical, and physical processes occurring at the ocean-atmosphere interface. We advocate the development of strong interdisciplinary expertise and collaboration in order to bridge between ocean and atmospheric sciences. Although this will pose significant methodological challenges, such an initiative would represent a new role model for interdisciplinary research in Earth System sciences.
- ItemMultiband Wavelet Age Modeling for a ∼293 m (∼600 kyr) Sediment Core From Chew Bahir Basin, Southern Ethiopian Rift(Lausanne : Frontiers Media, 2021) Duesing, Walter; Berner, Nadine; Deino, Alan L.; Foerster, Verena; Kraemer, K. Hauke; Marwan, Norbert; Trauth, Martin H.The use of cyclostratigraphy to reconstruct the timing of deposition of lacustrine deposits requires sophisticated tuning techniques that can accommodate continuous long-term changes in sedimentation rates. However, most tuning methods use stationary filters that are unable to take into account such long-term variations in accumulation rates. To overcome this problem we present herein a new multiband wavelet age modeling (MUBAWA) technique that is particularly suitable for such situations and demonstrate its use on a 293 m composite core from the Chew Bahir basin, southern Ethiopian rift. In contrast to traditional tuning methods, which use a single, defined bandpass filter, the new method uses an adaptive bandpass filter that adapts to changes in continuous spatial frequency evolution paths in a wavelet power spectrum, within which the wavelength varies considerably along the length of the core due to continuous changes in long-term sedimentation rates. We first applied the MUBAWA technique to a synthetic data set before then using it to establish an age model for the approximately 293 m long composite core from the Chew Bahir basin. For this we used the 2nd principal component of color reflectance values from the sediment, which showed distinct cycles with wavelengths of 10–15 and of ∼40 m that were probably a result of the influence of orbital cycles. We used six independent 40Ar/39Ar ages from volcanic ash layers within the core to determine an approximate spatial frequency range for the orbital signal. Our results demonstrate that the new wavelet-based age modeling technique can significantly increase the accuracy of tuned age models.
- ItemK-feldspar pIRIR150 dating of the Late Pleistocene sediments in the NW Khangai Mountains (Mongolia) using a standardized dose-response curve approach(Lausanne : Frontiers Media, 2023) Li, Yan; Tsukamoto, Sumiko; Klinge, Michael; Sauer, Daniela; Frechen, ManfredK-feldspar luminescence dating has been widely applied to constrain the timing of Quaternary sedimentation in different environments. However, the measurements are time-consuming. Meanwhile, anomalous fading and partial bleaching are the two potential problems inducing dating uncertainty. In this study, sand-size K-feldspar grains extracted from 32 luminescence samples from the northern slope of the Khangai Mountains, Mongolia, were dated using the post-infrared (IR) infrared stimulated luminescence protocol (pIRIR150. subscript shows the second stimulation temperature). The standardized dose-response curves (sDRCs) for luminescence dating, which could improve the measurement efficiency, were constructed. The K-feldspar luminescence chronology has been established after careful investigations of fading correction and bleaching degree of the signals. The sDRCs and individual DRC yield consistent ages, indicating that sDRCs are applicable for luminescence dating with an improvement in measurement efficiency. The fading corrected ages using the two fading correction models are generally in agreement. Based on age comparisons between the radiocarbon dates, the fading corrected pIRIR150 and IR50 ages, the pIRIR150 signal was not fully bleached for several samples. In contrast, some IR50 ages were overestimated due to fading over-correction. The investigated profiles have documented the sedimentary information since the last deglaciation.
- ItemLoess-Palaeosol Sequences in the Kashmir Valley, NW Himalayas: A Review(Lausanne : Frontiers Media, 2020) Dar, Reyaz A.; Zeeden, ChristianLoess deposits and intercalated palaeosols are widespread in the Quaternary record, and these have been extensively used to gain insights into continental paleoclimatic and paleo-environmental conditions and changes. Especially over Eurasia, loess geoarchives play an important role for our understanding of past changes. Loess covers almost 500 km2 of the Kashmir Valley in north-western India, it occurs dominantly in plateau positions, but also on terraces and sometimes forms slope deposits with thicknesses ranging from several to more than 20 m. For the time being, however, the timing of the initiation of the loess accumulation, the provenance, the grain size composition and also the paleo-environment have not been studied systematically and yet only little quantitative data is available. Yet it is clear that deposition rates are at least comparable to European loess, and that the presence of multiple palaeosols intercalated in the loess can provide valuable information on the history of the region. The limited available data hinders regional and continental correlation, and tapping its value as archive of past environmental changes in this sensitive region with influence from Westerlies and the Indian Monsoon. However, several characteristic palaeosol patterns can be traced throughout the Kashmir valley, which provide stratigraphic information. Several studies investigate physical and chemical properties of the loess-paleosol sequences and conclude to its aeolian origin and recording of past climates. The intensity of soil formation phases is traced through various proxies in low resolution and yet without conclusive age control. Here we review the exiting literature, available data, and interpretations from loess-palaeosol sequences in the Kashmir Valley. These are placed in the context of our own observations and loess from the Indian subcontinent. © Copyright © 2020 Dar and Zeeden.
- ItemConcentrations and Uptake of Dissolved Organic Phosphorus Compounds in the Baltic Sea(Lausanne : Frontiers Media, 2018-12-10) Nausch, Monika; Achterberg, Eric P.; Bach, Lennart T.; Brussaard, Corinna P. D.; Crawfurd, Katharine J.; Fabian, Jenny; Riebesell, Ulf; Stuhr, Annegret; Unger, Juliane; Wannicke, NicolaThe dissolved organic phosphorus (DOP) pool in marine waters contains a variety of different compounds. Knowledge of the distribution and utilization of DOP by phyto- and bacterioplankton is limited, but critical to our understanding of the marine phosphorus cycle. In the Baltic Sea, detailed information about the composition of DOP and its turnover is lacking. This study reports the concentrations and uptake rates of DOP compounds, namely, adenosine triphosphate (dATP), deoxyribonucleic acid (dDNA), and phospholipids (dPL), in the Baltic Proper and in Finnish coastal waters in the summers of 2011 and 2012. Both areas differed in their dissolved inorganic phosphorus (DIP) concentrations (0.16 and 0.02–0.04 μM), in the C:P (123–178) and N:P (18–27) ratios, and in abundances of filamentous cyanobacteria and of autotrophic and heterotrophic picoplankton. The mean concentrations of dATP-P, dDNA-P, and dPL-P were 4.3–6.4, 0.05–0.12, and 1.9–6.8 nM, respectively, together contributing between 2.4 and 5.2% of the total DOP concentration. The concentrations of the compounds varied between and within the investigated regions and the distribution patterns of the individual components are not linked to each other. DIP was taken up at rates of 10.1–380.8 nM d-1. dATP-P and dDNA-P were consumed simultaneously with DIP at rates of 6.9–24.1 and 0.09–0.19 nM d-1, respectively, with the main proportion taken up by the size fraction <3 μm and with DIP to be the dominant source. Groups of hydrographical and biological parameters were identified in the multiple regression analysis to impact the concentrations and uptake rates. It points to the complexity of the regulation. Our results indicate that the investigated DOP compounds, particularly dATP-P, can make significant contributions to the P nutrition of microorganisms and their use seems to be not intertwined. Therefore, more detailed knowledge of all DOP components including variation of concentrations and the utilization is required to understand the roles of DOP in marine ecosystems.
- ItemRock Magnetic Cyclostratigraphy of Permian Loess in Eastern Equatorial Pangea (Salagou Formation, South-Central France)(Lausanne : Frontiers Media, 2020) Pfeifer, Lily S.; Hinnov, Linda; Zeeden, Christian; Rolf, Christian; Laag, Christian; Soreghan, Gerilyn S.We present the findings from analysis and modeling of a stratigraphic series of magnetic susceptibility (MS) data measured with a portable MS meter from the Permian Salagou Formation loessite (south-central France). The results reveal discernible Milankovitch-scale paleoclimatic variability throughout the Salagou Formation, recording astronomically forced climate change in deep-time loessite of eastern equatorial Pangea. Optimal sedimentation rates are estimated to have ranged between 9.4 cm/kyr (lower Salagou Formation) and 13 cm/kyr (mid-upper Salagou Formation). A persistent 10-m-thick cyclicity is present that likely represents orbital eccentricity-scale (∼100 kyr) variability through the middle to late Cisuralian (ca. 285—275 Ma). Subordinate, higher frequency cycles with thicknesses of ∼3.3–3.5 and ∼1.8 m appear to represent obliquity and precession-scale variability. If the driver of magnetic enhancement is pedogenic, then the ∼10 m thick cyclicity that is consistent over ∼1000 m of section may represent the thickness of loessite–paleosol couplets in the Salagou Formation. Laboratory rock magnetic data show generally low magnetic enhancement compared to analogous Eurasian Quaternary loess deposits. This is related to the predominance of hematite (substantially weaker signal than magnetite or maghemite) in the Salagou Formation which may be explained by different conditions of formation (e.g., syn depositional processes, more arid, and/or oxidizing climate conditions) than in present Eurasia and/or post depositional oxidation of magnetite and maghemite. © Copyright © 2020 Pfeifer, Hinnov, Zeeden, Rolf, Laag and Soreghan.