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- ItemMeasuring the morphology and density of internally mixed black carbon with SP2 and VTDMA: New insight into the absorption enhancement of black carbon in the atmosphere(München : European Geopyhsical Union, 2016) Zhang, Yuxuan; Zhang, Qiang; Cheng, Yafang; Su, Hang; Kecorius, Simonas; Wang, Zhibin; Wu, Zhijun; Hu, Min; Zhu, Tong; Wiedensohler, Alfred; He, KebinThe morphology and density of black carbon (BC) cores in internally mixed BC (In-BC) particles affect their mixing state and absorption enhancement. In this work, we developed a new method to measure the morphology and effective density of the BC cores of ambient In-BC particles using a single-particle soot photometer (SP2) and a volatility tandem differential mobility analyzer (VTDMA) during the CAREBeijing-2013 campaign from 8 to 27 July 2013 at Xianghe Observatory. This new measurement system can select size-resolved ambient In-BC particles and measure the mobility diameter and mass of the In-BC cores. The morphology and effective density of the ambient In-BC cores are then calculated. For the In-BC cores in the atmosphere, changes in their dynamic shape factor (χ) and effective density (ρeff) can be characterized as a function of the aging process (Dp∕Dc) measured by SP2 and VTDMA. During an intensive field study, the ambient In-BC cores had an average shape factor χ of ∼ 1.2 and an average density of ∼ 1.2 g cm−3, indicating that ambient In-BC cores have a near-spherical shape with an internal void of ∼ 30 %. From the measured morphology and density, the average shell ∕ core ratio and absorption enhancement (Eab) of ambient BC were estimated to be 2.1–2.7 and 1.6–1.9, respectively, for In-BC particles with sizes of 200–350 nm. When the In-BC cores were assumed to have a void-free BC sphere with a density of 1.8 g cm−3, the shell ∕ core ratio and Eab were overestimated by ∼ 13 and ∼ 17 %, respectively. The new approach developed in this work improves the calculations of the mixing state and optical properties of ambient In-BC particles by quantifying the changes in the morphology and density of ambient In-BC cores during aging.
- ItemOn the efficiency of rocket-borne particle detection in the mesosphere(München : European Geopyhsical Union, 2007) Hedin, J.; Gumbel, J.; Rapp, M.Meteoric smoke particles have been proposed as a key player in the formation and evolution of mesospheric phenomena. Despite their apparent importance still very little is known about these particles. Important questions concern the smoke number density and size distribution as a function of altitude as well as the fraction of charged particles. Sounding rockets are used to measure smoke in situ, but aerodynamics has remained a major challenge. Basically, the small smoke particles tend to follow the gas flow around the payload rather than reaching the detector if aerodynamics is not considered carefully in the detector design. So far only indirect evidence for the existence of meteoric smoke has been available from measurements of heavy charge carriers. Quantitative ways are needed that relate these measured particle population to the atmospheric particle population. This requires in particular knowledge about the size-dependent, altitude-dependent and charge-dependent detection efficiency for a given instrument. In this paper, we investigate the aerodynamics for a typical electrostatic detector design. We first quantify the flow field of the background gas, then introduce particles in the flow field and determine their trajectories around the payload structure. We use two different models to trace particles in the flow field, a Continuous motion model and a Brownian motion model. Brownian motion is shown to be of basic importance for the smallest particles. Detection efficiencies are determined for three detector designs, including two with ventilation holes to allow airflow through the detector. Results from this investigation show that rocket-borne smoke detection with conventional detectors is largely limited to altitudes above 75 km. The flow through a ventilated detector has to be relatively large in order to significantly improve the detection efficiency.