2013, Becker, M.M., Loffhagen, D.

Common fluid models used for the description of electron transport in nonthermal discharge plasmas are subject to substantial restrictions if the electron energy transport significantly influences the discharge behaviour. A drift-diffusion approach is presented which is based on a multiterm approximation of the electron velocity distribution function and overcomes some of these restrictions. It is validated using a benchmark model and applied for the analysis of argon discharge plasmas at low and atmospheric pressure. The results are compared to those of common drift-diffusion models as well as to experimental data. It is pointed out that fluid models are able to describe nonlocal phenomena caused by electron energy transport, if the energy transport is consistently described. Numerical difficulties that frequently occur when the conventional drift-diffusion model is consistently applied are avoided by the proposed method.

2010, Koban, I., Matthes, R., Hübner, N.-O., Welk, A., Meisel, P., Holtfreter, B., Sietmann, R., Kindel, E., Weltmann, K.-D., Kramer, A., Kocher, T.

Because of some disadvantages of chemical disinfection in dental practice (especially denture cleaning), we investigated the effects of physical methods on Candida albicans biofilms. For this purpose, the antifungal efficacy of three different low-temperature plasma devices (an atmospheric pressure plasma jet and two different dielectric barrier discharges (DBDs)) on Candida albicans biofilms grown on titanium discs in vitro was investigated. As positive treatment controls, we used 0.1% Chlorhexidine digluconate (CHX) and 0.6% sodium hypochlorite (NaOCl). The corresponding gas streams without plasma ignition served as negative treatment controls. The efficacy of the plasma treatment was determined evaluating the number of colony-forming units (CFU) recovered from titanium discs. The plasma treatment reduced the CFU significantly compared to chemical disinfectants. While 10 min CHX or NaOCl exposure led to a CFU log 10 reduction factor of 1.5, the log10 reduction factor of DBD plasma was up to 5. In conclusion, the use of low-temperature plasma is a promising physical alternative to chemical antiseptics for dental practice. © IOP Publishing Ltd and Deutsche Physikalische Gesellschaft.

2014, Iseni, S., Zhang, S., Van Gessel, A.F.H., Hofmann, S., Van Ham, B.T.J., Reuter, S., Weltmann, K.-D., Bruggeman, P.J.

The effluent of an RF argon atmospheric pressure plasma jet, the so-called kinpen, is investigated with focus on the nitric-oxide (NO) distribution for laminar and turbulent flow regimes. An additional dry air gas curtain is applied around the plasma effluent to prevent interaction with the ambient humid air. By means of laser-induced fluorescence (LIF) the absolute spatially resolved NO density is measured as well as the rotational temperature and the air concentration. While in the laminar case, the transport of NO is attributed to thermal diffusion; in the turbulent case, turbulent mixing is responsible for air diffusion. Additionally, measurements with a molecular beam mass-spectrometer (MBMS) absolutely calibrated for NO are performed and compared with the LIF measurements. Discrepancies are explained by the contribution of the NO2 and N2O to the MBMS NO signal. Finally, the effect of a conductive substrate in front of the plasma jet on the spatial distribution of NO and air diffusion is also investigated.

2020, Pérez Donoso, Patricio-Ignacio, Ortiz Rojas, Adrián-Enrique, Meneses Rioseco, Ernesto

This work studies intensively the flow in fractures with finite hydraulic conductivity intersected by a well injecting or producing at constant pressure, either during an injection or production well test or the operation of a production well. Previous investigations showed that for a certain time the reciprocal of flow rate is proportional to the fourth root of time, which is characteristic of the flow regime known as bilinear flow. Using a 2D numerical model, we demonstrated that during the bilinear flow regime the transient propagation of isobars along the fracture is proportional to the fourth root of time. Moreover, we present relations to calculate the termination time of bilinear flow under constant injection or production well pressure as well as an expression for the bilinear hydraulic diffusivity of fractures with finite hydraulic conductivity. To determine the termination of bilinear flow regime, two different methods were used: (a) numerically measuring the transient flow rate in the well and (b) analyzing the propagation of isobars along the fracture. Numerical results show that for low dimensionless fracture conductivities the transition from bilinear flow to another flow regime (e.g., pseudo-radial flow) occurs before the pressure front reaches the fracture tip, and for high dimensionless fracture conductivities it occurs when the pressure front arrives at the fracture tip. Hence, this work complements and advances previous research on the interpretation and evaluation of well test analysis under different reservoir conditions. Our results aim to improve the understanding of the hydraulic diffusion in fractured geologic media, and as a result they can be utilized for the interpretation of hydraulic tests, for example to estimate the fracture length.

2020, Heino, Matias, Guillaume, Joseph H.A., Müller, Christoph, Iizumi, Toshichika, Kummu, Matti

Climate oscillations are periodically fluctuating oceanic and atmospheric phenomena, which are related to variations in weather patterns and crop yields worldwide. In terms of crop production, the most widespread impacts have been observed for the El Niño-Southern Oscillation (ENSO), which has been found to impact crop yields on all continents that produce crops, while two other climate oscillations - the Indian Ocean Dipole (IOD) and the North Atlantic Oscillation (NAO) - have been shown to especially impact crop production in Australia and Europe, respectively. In this study, we analyse the impacts of ENSO, IOD, and NAO on the growing conditions of maize, rice, soybean, and wheat at the global scale by utilising crop yield data from an ensemble of global gridded crop models simulated for a range of crop management scenarios. Our results show that, while accounting for their potential co-variation, climate oscillations are correlated with simulated crop yield variability to a wide extent (half of all maize and wheat harvested areas for ENSO) and in several important crop-producing areas, e.g. in North America (ENSO, wheat), Australia (IOD and ENSO, wheat), and northern South America (ENSO, soybean). Further, our analyses show that higher sensitivity to these oscillations can be observed for rainfed and fully fertilised scenarios, while the sensitivity tends to be lower if crops were to be fully irrigated. Since the development of ENSO, IOD, and NAO can potentially be forecasted well in advance, a better understanding about the relationship between crop production and these climate oscillations can improve the resilience of the global food system to climate-related shocks. © 2020 American Institute of Physics Inc.. All rights reserved.

2020, Schnabel, Uta, Yarova, Kateryna, Zessin, Björn, Stachowiak, Jörg, Ehlbeck, Jörg

Microwave-induced plasma was used for the generation of plasma-processed air (PPA) and plasma-treated water (PTW). By this way, the plasma was able to functionalize the compressed air and the used water to antimicrobial effective agents. Their fungicidal effects by single and combined application were investigated on Candida albicans strain SC5314. The monoculture of C. albicans was cultivated on specimens with polymeric surface structures (PE-stripes). The additive as well as the synergistic fungicidal potential of PPA and PTW was investigated by different process windows of plasma exposure time (5-50 s) and sample treatment time with PPA/PTW (1-5 min). For a single PTW or PPA treatment, an increase in the reduction factor with the indicated treatment time was observed (maximum reduction factor of 1.1 and 1.6, respectively). In comparison, the combined application of PTW and then PPA resulted in antagonistic, additive and synergistic effects, depending on the combination. An application of the synergistically acting processes of PTW for cleaning and PPA for drying can be an innovative alternative to the sanitary processes currently used in production plants. © 2020 by the authors.

2015, Ekimova, Maria, Quevedo, Wilson, Faubel, Manfred, Wernet, Philippe, Nibbering, Erik T. J.

We present a liquid flatjet system for solution phase soft-x-ray spectroscopy. The flatjet set-up utilises the phenomenon of formation of stable liquid sheets upon collision of two identical laminar jets. Colliding the two single water jets, coming out of the nozzles with 50 μm orifices, under an impact angle of 48° leads to double sheet formation, of which the first sheet is 4.6 mm long and 1.0 mm wide. The liquid flatjet operates fully functional under vacuum conditions (<10(-3) mbar), allowing soft-x-ray spectroscopy of aqueous solutions in transmission mode. We analyse the liquid water flatjet thickness under atmospheric pressure using interferomeric or mid-infrared transmission measurements and under vacuum conditions by measuring the absorbance of the O K-edge of water in transmission, and comparing our results with previously published data obtained with standing cells with Si3N4 membrane windows. The thickness of the first liquid sheet is found to vary between 1.4-3 μm, depending on the transverse and longitudinal position in the liquid sheet. We observe that the derived thickness is of similar magnitude under 1 bar and under vacuum conditions. A catcher unit facilitates the recycling of the solutions, allowing measurements on small sample volumes (∼10 ml). We demonstrate the applicability of this approach by presenting measurements on the N K-edge of aqueous NH4 (+). Our results suggest the high potential of using liquid flatjets in steady-state and time-resolved studies in the soft-x-ray regime.

2015, Jablonowski, H., Bussiahn, R., Hammer, M.U., Weltmann, K.-D., von Woedtke, T., Reuter, S.

Plasma medicine utilizes the combined interaction of plasma produced reactive components. These are reactive atoms, molecules, ions, metastable species, and radiation. Here, ultraviolet (UV, 100–400 nm) and, in particular, vacuum ultraviolet (VUV, 10–200 nm) radiation generated by an atmospheric pressure argon plasma jet were investigated regarding plasma emission, absorption in a humidified atmosphere and in solutions relevant for plasma medicine. The energy absorption was obtained for simple solutions like distilled water (dH2O) or ultrapure water and sodium chloride (NaCl) solution as well as for more complex ones, for example, Rosewell Park Memorial Institute (RPMI 1640) cell culture media. As moderate stable reactive oxygen species, hydrogen peroxide (H2O2) was studied. Highly reactive oxygen radicals, namely, superoxide anion (O2•−) and hydroxyl radicals (•OH), were investigated by the use of electron paramagnetic resonance spectroscopy. All species amounts were detected for three different treatment cases: Plasma jet generated VUV and UV radiation, plasma jet generated UV radiation without VUV part, and complete plasma jet including all reactive components additionally to VUV and UV radiation. It was found that a considerable amount of radicals are generated by the plasma generated photoemission. From the experiments, estimation on the low hazard potential of plasma generated VUV radiation is discussed.

2019, Schnabel, Uta, Handorf, Oliver, Yarova, Kateryna, Zessin, Björn, Zechlin, Susann, Sydow, Diana, Zellmer, Elke, Stachowiak, Jörg, Andrasch, Mathias, Below, Harald, Ehlbeck, Jörg

The synergistic antimicrobial effects of plasma-processed air (PPA) and plasma-treated water (PTW), which are indirectly generated by a microwave-induced non-atmospheric pressure plasma, were investigated with the aid of proliferation assays. For this purpose, microorganisms (Listeria monocytogenes, Escherichia coli, Pectobacterium carotovorum, sporulated Bacillus atrophaeus) were cultivated as monocultures on specimens with polymeric surface structures. Both the distinct and synergistic antimicrobial potential of PPA and PTW were governed by the plasma-on time (5–50 s) and the treatment time of the specimens with PPA/PTW (1–5 min). In single PTW treatment of the bacteria, an elevation of the reduction factor with increasing treatment time could be observed (e.g., reduction factor of 2.4 to 3.0 for P. carotovorum). In comparison, the combination of PTW and subsequent PPA treatment leads to synergistic effects that are clearly not induced by longer treatment times. These findings have been valid for all bacteria (L. monocytogenes > P. carotovorum = E. coli). Controversially, the effect is reversed for endospores of B. atrophaeus. With pure PPA treatment, a strong inactivation at 50 s plasma-on time is detectable, whereas single PTW treatment shows no effect even with increasing treatment parameters. The use of synergistic effects of PTW for cleaning and PPA for drying shows a clear alternative for currently used sanitation methods in production plants. Highlights: Non-thermal atmospheric pressure microwave plasma source used indirect in two different modes—gaseous and liquid; Measurement of short and long-living nitrite and nitrate in corrosive gas PPA (plasma-processed air) and complex liquid PTW (plasma-treated water); Application of PTW and PPA in single and combined use for biological decontamination of different microorganisms.

2013, Ortiz R., A.E., Jung, R., Renner, J.

Bilinear flow occurs when fluid is drained from a permeable matrix by producing it through an enclosed fracture of finite conductivity intersecting a well along its axis. The terminology reflects the combination of two approximately linear flow regimes: one in the matrix with flow essentially perpendicular to the fracture, and one along the fracture itself associated with the non-negligible pressure drop in it. We investigated the characteristics, in particular the termination, of bilinear flow by numerical modeling allowing for an examination of the entire flow field without prescribing the flow geometry in the matrix. Fracture storage capacity was neglected relying on previous findings that bilinear flow is associated with a quasi-steady flow in the fracture. Numerical results were generalized by dimensionless presentation. Definition of a dimensionless time that, other than in previous approaches, does not use geometrical parameters of the fracture permitted identifying the dimensionless well pressure for the infinitely long fracture as the master curve for type curves of all fractures with finite length from the beginning of bilinear flow up to fully developed radial flow. In log–log scale the master curve's logarithmic derivative initially follows a 1/4-slope straight line (characteristic for bilinear flow) and gradually bends into a horizontal line (characteristic for radial flow) for long times. During the bilinear flow period, isobars normalized to well pressure propagate with the fourth and second root of time in fracture and matrix, respectively. The width-to-length ratio of the pressure field increases proportional to the fourth root of time during the bilinear period, and starts to deviate from this relation close to the deviation of well pressure and its derivative from their fourth-root-of-time relations. At this time, isobars are already significantly inclined with respect to the fracture. The type curves of finite fractures all deviate counterclockwise from the master curve instead of clockwise or counterclockwise from the 1/4-slope straight line as previously proposed. The counterclockwise deviation from the master curve was identified as the arrival of a normalized isobar reflected at the fracture tip 16 times earlier. Nevertheless, two distinct regimes were found in regard to pressure at the fracture tip when bilinear flow ends. For dimensionless fracture conductivities TD < 1, a significant pressure increase is not observed at the fracture tip until bilinear flow is succeeded by radial flow at a fixed dimensionless time. For TD > 10, the pressure at the fracture tip has reached substantial fractions of the associated change in well pressure when the flow field transforms towards intermittent formation linear flow at times that scale inversely with the fourth power of dimensionless fracture conductivity. Our results suggest that semi-log plots of normalized well pressure provide a means for the determination of hydraulic parameters of fracture and matrix after shorter test duration than for conventional analysis.