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Supramolecular assemblies of block copolymers as templates for fabrication of nanomaterials
2011, Nandan, B., Kuila, B.K., Stamm, M.
Self-assembled polymeric systems have played an important role as templates for nanofabrication; they offer nanotemplates with different morphologies and tunable sizes, are easily removed after reactions, and could be further modified with different functional groups to enhance the interactions. Among the various self-assembled polymeric systems, block copolymer supramolecular assemblies have received considerable attention because of the inherent processing advantages. These supramolecular assemblies are formed by the non-covalent interactions of one of the blocks of the block copolymer with a low molar-mass additive. Selective extraction of the additive leads to porous membranes or nano-objects which could then be used as templates for nanofabrication leading to a variety of ordered organic/inorganic nanostructures. In this feature article, we present an over-view of the recent developments in this area with a special focus on some examples from our group.
Heterogeneous freezing on pyroelectric poly(vinylidene fluoride-co-trifluoroethylene) thin films
2020, Apelt, Sabine, Höhne, Susanne, Uhlmann, Petra, Bergmann, Ute
Active deicing of technical surfaces, such as for wind turbines and heat exchangers, currently requires the usage of heat or chemicals. Passive coating strategies that postpone the freezing of covering water would be beneficial in order to save costs and energy. One hypothesis is that pyroelectric active materials can achieve this because of the surface charges generated on these materials when they are subject to a temperature change. High-quality poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) thin films with a high crystallinity, prefererd edge-on orientation, low surface roughness, and comprised of the β-analogous ferroelectric phase were deposited by spin-coating. Freezing experiments with a cooling rate of 1 K min−1 were made on P(VDF-TrFE) coatings in order to separate the effect of different parameters such as the poling direction, film thickness, used solvent, deposition process, underlying substrate, and annealing temperature on the achievable supercooling. The topography and the underlying substrate significantly changed the distribution of freezing temperatures of water droplets in contact with these thin films. In contrast, no significant effect of the thickness, morphology, or pyroelectric effect of the as-prepared domain-state on the freezing temperatures was found.
Process Monitoring of a Vibration Dampening CFRP Drill Tube in BTA deep hole drilling using Fibre-Bragg-Grating Sensors
2022, Summa, Jannik, Michel, Sebastian, Kurkowski, Moritz, Biermann, Dirk, Stommel, Markus, Herrmann, Hans-Georg
The large tool length in BTA deep hole drilling often leads to strong torsional vibrations of the tool system, leading to a reduced bore hole quality failures. When substituting steel drill tubes with tubes from composite material, the laminate structure dampens these vibrations. Secondly, the integration of sensors allow to monitor process vibrations. This contribution introduces a new sensor platform to measure process vibrations, feed force and drilling torque using Fibre-Bragg Grating Sensors. The presented experimental results focus on characteristic frequency spectra with natural torsional and compression frequencies of the CFRP drill tube, which show variations due to changed feed.
Beamline-implemented stretching devices for in situ X-ray scattering experiments
2022, Euchler, E., Sambale, A.K., Schneider, K., Uhlig, K., Boldt, R., Stommel, M., Stribeck, A., Schwartzkopf, M., Rothkirch, A., Roth, S.V.
Two recently developed experimental devices for investigating soft matter deformation are presented. Both devices exploit the capabilities of a modern synchrotron beamline to enable advanced and highly precise materials-science experiments in which X-ray scattering is registered. The devices can be operated both in monotonic as well as cyclic mode and are implemented into a beamline at DESY, Hamburg (Germany). Hence, relevant experimental parameters, such as displacement, force and temperature, are recorded synchronously with the individual X-ray scattering patterns. In addition, spatial variation of materials deformation can be monitored and recorded with optical microscopy. This unique sample environment enables in situ X-ray experiments in transmission, i.e. small- or wide-angle X-ray scattering (SAXS or WAXS), and in grazing-incidence geometry, i.e. grazing-incidence (GI-) SAXS or WAXS. One device with stepper motors is designed for studies of slow, (quasi-) static deformation and the other one with pneumatic actuators can be used for fast, impact deformation. Both devices are available to external beamline users, too.