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- ItemElectron beam-induced immobilization of laccase on porous supports for waste water treatment applications(Basel : MDPI AG, 2014) Jahangiri, E.; Reichelt, S.; Thomas, I.; Hausmann, K.; Schlosser, D.; Schulze, A.The versatile oxidase enzyme laccase was immobilized on porous supports such as polymer membranes and cryogels with a view of using such biocatalysts in bioreactors aiming at the degradation of environmental pollutants in wastewater. Besides a large surface area for supporting the biocatalyst, the aforementioned porous systems also offer the possibility for simultaneous filtration applications in wastewater treatment. Herein a "green" water-based, initiator-free, and straightforward route to highly reactive membrane and cryogel-based bioreactors is presented, where laccase was immobilized onto the porous polymer supports using a water-based electron beam-initiated grafting reaction. In a second approach, the laccase redox mediators 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) and syringaldehyde were cross-linked instead of the enzyme via electron irradiation in a frozen aqueous poly(acrylate) mixture in a one pot set-up, yielding a mechanical stable macroporous cryogel with interconnected pores ranging from 10 to 50 μm in size. The membranes as well as the cryogels were characterized regarding their morphology, chemical composition, and catalytic activity. The reactivity towards waste-water pollutants was demonstrated by the degradation of the model compound bisphenol A (BPA). Both membrane- and cryogel-immobilized laccase remained highly active after electron beam irradiation. Apparent specific BPA removal rates were higher for cryogel-than for membrane-immobilized and free laccase, whereas membrane-immobilized laccase was more stable with respect to maintenance of enzymatic activity and prevention of enzyme leakage from the carrier than cryogel-immobilized laccase. Cryogel-immobilized redox mediators remained functional in accelerating the laccase-catalyzed BPA degradation, and especially ABTS was found to act more efficiently in immobilized than in freely dissolved state.
- ItemModeling climate and management change impacts on water quality and in-stream processes in the Elbe river basin(Basel : MDPI AG, 2016) Hesse, C.; Krysanova, V.
- ItemClimate-driven or human-induced: Indicating severe water scarcity in the Moulouya river basin (Morocco)(Basel : MDPI AG, 2012) Tekken, V.; Kropp, J.P.Many agriculture-based economies are increasingly under stress from climate change and socio-economic pressures. The excessive exploitation of natural resources still represents the standard procedure to achieve socio-economic development. In the area of the Moulouya river basin, Morocco, natural water availability represents a key resource for all economic activities. Agriculture represents the most important sector, and frequently occurring water deficits are aggravated by climate change. On the basis of historical trends taken from CRU TS 2.1, this paper analyses the impact of climate change on the per capita water availability under inclusion of population trends. The Climatic Water Balance (CWB) shows a significant decrease for the winter period, causing adverse effects for the main agricultural season. Further, moisture losses due to increasing evapotranspiration rates indicate problems for the annual water budget and groundwater recharge. The per capita blue water availability falls below a minimum threshold of 500 m3 per year, denoting a high regional vulnerability to increasing water scarcity assuming a no-response scenario. Regional development focusing on the water-intense sectors of agriculture and tourism appears to be at risk. Institutional capacities and policies need to address the problem, and the prompt implementation of innovative water production and efficiency measures is recommended.
- ItemWater implications of foreign direct investment in Ethiopia's agricultural sector(Basel : MDPI AG, 2012) Bossio, D.; Erkossa, T.; Dile, Y.; McCartney, M.; Killiches, F.; Hoff, H.Ethiopia is often highlighted as a country in which a lot of foreign land acquisition is occurring. The extent to which these investments also constitute significant acquisitions of water is the subject of this paper. It is apparent that water availability is a strong driver of the recent surge of investments in agricultural land globally, and in general the investments occur in countries with significant 'untapped' water resources. Ethiopia is no exception. We propose that the perception of unused and abundant water resources, as captured in dominant narratives, that drives and justifies both foreign and domestic investments, fails to reflect the more complex reality on the ground. Based on new collections of lease information and crop modelling, we estimate the potential additional water use associated with foreign investments at various scales. As a consequence of data limitations our analyses provide only crude estimates of consumptive water use and indicate a wide range of possible water consumption depending on exactly how foreign direct investment (FDI) development scenarios unfold. However, they do suggest that if all planned FDI schemes are implemented and expanded in the near future, additional water consumption is likely to be comparable with existing water use in non-FDI irrigation schemes, and a non-trivial proportion of the country's water resources will be effectively utilised by foreign entities. Hence, additional water use as well as local water scarcity ought to be strong considerations in regulating or pricing land leases. If new investments are to increase local food and water security without compromising local and downstream water availability they should be designed to improve often very low agricultural water productivity, and to safeguard access of local populations to water.
- ItemComparison of water flows in four European lagoon catchments under a set of future climate scenarios(Basel : MDPI AG, 2015) Hesse, C.; Stefanova, A.; Krysanova, V.