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- ItemOptimized Deep Learning Model as a Basis for Fast UAV Mapping of Weed Species in Winter Wheat Crops(Basel : MDPI AG, 2021) de Camargo, Tibor; Schirrmann, Michael; Landwehr, Niels; Dammer, Karl-Heinz; Pflanz, MichaelWeed maps should be available quickly, reliably, and with high detail to be useful for site-specific management in crop protection and to promote more sustainable agriculture by reducing pesticide use. Here, the optimization of a deep residual convolutional neural network (ResNet-18) for the classification of weed and crop plants in UAV imagery is proposed. The target was to reach sufficient performance on an embedded system by maintaining the same features of the ResNet-18 model as a basis for fast UAV mapping. This would enable online recognition and subsequent mapping of weeds during UAV flying operation. Optimization was achieved mainly by avoiding redundant computations that arise when a classification model is applied on overlapping tiles in a larger input image. The model was trained and tested with imagery obtained from a UAV flight campaign at low altitude over a winter wheat field, and classification was performed on species level with the weed species Matricaria chamomilla L., Papaver rhoeas L., Veronica hederifolia L., and Viola arvensis ssp. arvensis observed in that field. The ResNet-18 model with the optimized image-level prediction pipeline reached a performance of 2.2 frames per second with an NVIDIA Jetson AGX Xavier on the full resolution UAV image, which would amount to about 1.78 ha h−1 area output for continuous field mapping. The overall accuracy for determining crop, soil, and weed species was 94%. There were some limitations in the detection of species unknown to the model. When shifting from 16-bit to 32-bit model precision, no improvement in classification accuracy was observed, but a strong decline in speed performance, especially when a higher number of filters was used in the ResNet-18 model. Future work should be directed towards the integration of the mapping process on UAV platforms, guiding UAVs autonomously for mapping purpose, and ensuring the transferability of the models to other crop fields.
- ItemTopographical anisotropy and wetting of ground stainless steel surfaces(Basel : MDPI AG, 2012) Calvimontes, A.; Mauermann, M.; Bellmann, C.Microscopic and physico-chemical methods were used for a comprehensive surface characterization of different mechanically modified stainless steel surfaces. The surfaces were analyzed using high-resolution confocal microscopy, resulting in detailed information about the topographic properties. In addition, static water contact angle measurements were carried out to characterize the surface heterogeneity of the samples. The effect of morphological anisotropy on water contact angle anisotropy was investigated. The correlation between topography and wetting was studied by means of a model of wetting proposed in the present work, that allows quantifying the air volume of the interface water drop-stainless steel surface.
- ItemHigh temperature behavior of rual thin films on piezoelectric CTGS and LGS substrates(Basel : MDPI AG, 2020) Seifert, M.This paper reports on a significant further improvement of the high temperature stability of RuAl thin films (110 nm) on the piezoelectric Ca3TaGa3Si2O14 (CTGS) and La3Ga5SiO14 (LGS) substrates. RuAl thin films with AlN or SiO2 cover layers and barriers to the substrate (each 20 nm), as well as a combination of both were prepared on thermally oxidized Si substrates, which serve as a reference for fundamental studies, and the piezoelectric CTGS, as well as LGS substrates. In somefilms, additional Al layers were added. To study their high temperature stability, the samples were annealed in air and in high vacuum up to 900 °C, and subsequently their cross-sections, phase formation, film chemistry, and electrical resistivity were analyzed. It was shown that on thermally oxidized Si substrates, all films were stable after annealing in air up to 800 °C and in high vacuum up to 900 °C. The high temperature stability of RuAl thin films on CTGS substrates was improved up to 900 °C in high vacuum by the application of a combined AlN/SiO2 barrier layer and up to 800 °C in air using a SiO2 barrier. On LGS, the films were only stable up to 600 °C in air; however, a single SiO2 barrier layer was sufficient to prevent oxidation during annealing at 900 °C in high vacuum.
- ItemAnalysing Interlinked Frequency Dynamics of the Urban Acoustic Environment(Basel : MDPI AG, 2022) Haselhoff, Timo; Braun, Tobias; Hornberg, Jonas; Lawrence, Bryce T.; Ahmed, Salman; Gruehn, Dietwald; Moebus, SusanneAs sustainable metropolitan regions require more densely built-up areas, a comprehensive understanding of the urban acoustic environment (AE) is needed. However, comprehensive datasets of the urban AE and well-established research methods for the AE are scarce. Datasets of audio recordings tend to be large and require a lot of storage space as well as computationally expensive analyses. Thus, knowledge about the long-term urban AE is limited. In recent years, however, these limitations have been steadily overcome, allowing a more comprehensive analysis of the urban AE. In this respect, the objective of this work is to contribute to a better understanding of the time-frequency domain of the urban AE, analysing automatic audio recordings from nine urban settings over ten months. We compute median power spectra as well as normalised spectrograms for all settings. Additionally, we demonstrate the use of frequency correlation matrices (FCMs) as a novel approach to access large audio datasets. Our results show site-dependent patterns in frequency dynamics. Normalised spectrograms reveal that frequency bins with low power hold relevant information and that the AE changes considerably over a year. We demonstrate that this information can be captured by using FCMs, which also unravel communities of interlinked frequency dynamics for all settings.
- ItemAmorphous Li-Al-based compounds: A novel approach for designing high performance electrode materials for Li-ion batteries(Basel : MDPI AG, 2013) Thoss, F.; Giebeler, L.; Thomas, J.; Oswald, S.; Potzger, K.; Reuther, H.; Ehrenberg, H.; Eckert, J.A new amorphous compound with the initial atomic composition Al43Li43Y6Ni8 applied as electrode material for Li-ion batteries is investigated. Unlike other amorphous compounds so-far investigated as anode materials, it already contains Li as a base element in the uncycled state. The amorphous compound powder is prepared by high energy ball milling of a master alloy. It shows a strongly enhanced specific capacity in contrast to amorphous alloys without Li in the initial state. Therewith, by enabling a reversible (de)lithiation of metallic electrodes without the phase transition caused volume changes it offers the possibility of much increased specific capacities than conventional graphite anodes. According to the charge rate (C-rate), the specific capacity is reversible over 20 cycles at minimum in contrast to conventional crystalline intermetallic phases failing by volume changes. The delithiation process occurs quasi-continuously over a voltage range of nearly 4 V, while the lithiation is mainly observed between 0.1 V and 1.5 V. That way, the electrode is applicable for different potential needs. The electrode stays amorphous during cycling, thus avoiding volume changes. The cycling performance is further enhanced by a significant amount of Fe introduced as wear debris from the milling tools, which acts as a promoting element.
- ItemClimate-driven or human-induced: Indicating severe water scarcity in the Moulouya river basin (Morocco)(Basel : MDPI AG, 2012) Tekken, V.; Kropp, J.P.Many agriculture-based economies are increasingly under stress from climate change and socio-economic pressures. The excessive exploitation of natural resources still represents the standard procedure to achieve socio-economic development. In the area of the Moulouya river basin, Morocco, natural water availability represents a key resource for all economic activities. Agriculture represents the most important sector, and frequently occurring water deficits are aggravated by climate change. On the basis of historical trends taken from CRU TS 2.1, this paper analyses the impact of climate change on the per capita water availability under inclusion of population trends. The Climatic Water Balance (CWB) shows a significant decrease for the winter period, causing adverse effects for the main agricultural season. Further, moisture losses due to increasing evapotranspiration rates indicate problems for the annual water budget and groundwater recharge. The per capita blue water availability falls below a minimum threshold of 500 m3 per year, denoting a high regional vulnerability to increasing water scarcity assuming a no-response scenario. Regional development focusing on the water-intense sectors of agriculture and tourism appears to be at risk. Institutional capacities and policies need to address the problem, and the prompt implementation of innovative water production and efficiency measures is recommended.
- ItemSynthesis and characterization of nanocrystallineMg-7.4%Al powders produced by mechanical alloying(Basel : MDPI AG, 2013) Chaubey, A.K.; Scudino, S.; Khoshkhoo, M.S.; Prashanth, K.G.; Mukhopadhyay, N.K.; Mishra, B.K.; Eckert, J.Nanocrystalline Mg-7.4%Al powder was prepared by mechanical alloying using a high-energy mill. The evolution of the various phases and their microstructure, including size and morphology of the powder particles in the course of milling and during subsequent annealing, were investigated in detail. Room temperature milling leads to a rather heterogeneous microstructure consisting of two distinct regions: Al-free Mg cores and Mg-Al intermixed areas. As a result, the material is mechanically heterogeneous with the Mg cores displaying low hardness (40–50 HV) and the Mg-Al intermixed regions showing high hardness of about 170 HV. The Mg cores disappear and the microstructure becomes (also mechanically) homogeneous after subsequent cryo-milling. Rietveld structure refinement reveals that the crystallite size of the milled powders decreases with increasing the milling time reaching a minimum value of about 30 nm. This is corroborated by transmission electron microscopy confirming an average grain size of ~25 nm.
- ItemImpact of process parameters and bulk properties on quality of dried hops(Basel : MDPI AG, 2020) Raut, Sharvari; Gersdorff, Gardis J.E. von; Münsterer, Jakob; Kammhuber, Klaus; Hensel, Oliver; Sturm, BarbaraHops are critical to the brewing industry. In commercial hop drying, a large bulk of hops is dried in multistage kilns for several hours. This affects the drying behavior and alters the amount and chemical composition of the hop oils. To understand these changes, hops of the var. Hallertauer Tradition were dried in bulks of 15, 25 and 35 kg/m2 at 60◦C and 0.35 m/s. Additionally, bulks of 25 kg/m2 were also dried at 65◦C and 0.45 m/s to assess the effect of change in temperature and velocity, respectively. The results obtained show that bulk weights significantly influence the drying behavior. Classification based on the cone size reveals 45.4% medium cones, 41.2% small cones and 8.6% large cones. The highest ∆E value of 6.3 and specific energy consumption (113,476 kJ/kgH2O) were observed for the 15 kg/m2 bulk. Increasing the temperature from 60◦C to 65◦C increased the oil yield losses by about 7% and myrcene losses by 22%. The results obtained show that it is important to define and consider optimum bulk and process parameters, to optimize the hop drying process to improve the process efficiency as well the product quality. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
- ItemFabrication of metastable crystalline nanocomposites by flash annealing of Cu47.5Zr47.5Al5 metallic glass using joule heating(Basel : MDPI AG, 2020) Okulov, I.; Soldatov, I.; Kaban, I.; Sarac, B.; Spieckermann, F.; Eckert, J.Flash Joule-heating was applied to the Cu47.5Zr47.5Al5 metallic glass for designing fully crystalline metastable nanocomposites consisting of the metastable B2 CuZr and low-temperature equilibrium Cu10Zr7 phases. The onset of crystallization was in situ controlled by monitoring resistivity changes in the samples. The effect of heating rate and annealing time on the volume fraction of the crystalline phases and mechanical properties of the nanocomposites was studied in detail. Particularly, an increase of the heating rate and a decrease of the annealing time lead to a lower number of equilibrium Cu10Zr7 precipitates and an increase of tensile ductility. Tailoring of these non-equilibrium microstructures and mechanical properties may not be possible unless one starts with a fully glassy material that opens new perspectives for designing metastable nanomaterials with unique physical properties.
- ItemImpacts of climate change on the hydrological regime of the danube river and its tributaries using an ensemble of climate scenarios(Basel : MDPI AG, 2015) Stagl, J.C.; Hattermann, F.F.