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- ItemHydrothermal Carbonization and Pyrolysis of Sewage Sludge: Effects on Lolium perenne Germination and Growth(Basel : MDPI, 2019) Paneque, Marina; Knicker, Heike; Kern, Jürgen; De la Rosa, José MaríaThe pyrolysis and hydrothermal carbonization (HTC) of sewage sludge (SS) resulted in products free of pathogens, with the potential for being used as soil amendment. With this work, we evaluated the impact of dry pyrolysis-treated (600 °C, 1 h) and HTC-treated (200 °C, 260 °C; 0.5 h, 3 h) SS on the germination, survival, and growth of Lolium perenne during an 80 day greenhouse experiment. Therefore, the hydrochars and pyrochars were amended to a Calcic Cambisol at doses of 5 and 25 t ha−1. The addition of sludge pyrochars to the Cambisol did not affect Lolium germination, survival rates or plant yields. However, the use 25 t ha−1 of wood biochar reduced germination and survival rates, which may be related to the low N availability of this sample. In comparison to the control, higher or equal plant biomass was produced in the hydrochar-amended pots, even though some hydrochars decreased plant germination and survival rates. Among all the evaluated char properties, only the organic and inorganic N contents of the chars, along with their organic C values, positively correlated with total and shoot biomass production. Our work demonstrates the N fertilization potential of the hydrochar produced at low temperature, whereas the hydrochar produced at 260 °C and the pyrochars were less efficient with respect to plant yields.
- ItemComparative Studies on Water- and Vapor-Based Hydrothermal Carbonization: Process Analysis(Basel : MDPI, 2020) Ro, Kyoung S.; Libra, Judy A.; Alvarez-Murillo, AndrésHydrothermal carbonization (HTC) reactor systems used to convert wet organic wastes into value-added hydrochar are generally classified in the literature as liquid water-based (HTC) or vapor-based (VTC). However, the distinction between the two is often ambiguous. In this paper, we present a methodological approach to analyze process conditions for hydrothermal systems. First, we theoretically developed models for predicting reactor pressure, volume fraction of liquid water and water distribution between phases as a function of temperature. The reactor pressure model predicted the measured pressure reasonably well. We also demonstrated the importance of predicting the condition at which the reactor system enters the subcooled compression liquid region to avoid the danger of explosion. To help understand water–feedstock interactions, we defined a new solid content parameter %S(T) based on the liquid water in physical contact with feedstock, which changes with temperature due to changes in the water distribution. Using these models, we then compared the process conditions of seven different HTC/VTC cases reported in the literature. This study illustrates that a large range of conditions need to be considered before applying the label VTC or HTC. These tools can help in designing experiments to compare systems and understand results in future HTC research
- ItemHydrothermal Carbonization: Modeling, Final Properties Design and Applications: A Review(Basel : MDPI, 2018-1-16) Román, Silvia; Libra, Judy; Berge, Nicole; Sabio, Eduardo; Ro, Kyoung; Li, Liang; Ledesma, Beatriz; Álvarez, Andrés; Bae, SunyoungActive research on biomass hydrothermal carbonization (HTC) continues to demonstrate its advantages over other thermochemical processes, in particular the interesting benefits that are associated with carbonaceous solid products, called hydrochar (HC). The areas of applications of HC range from biofuel to doped porous material for adsorption, energy storage, and catalysis. At the same time, intensive research has been aimed at better elucidating the process mechanisms and kinetics, and how the experimental variables (temperature, time, biomass load, feedstock composition, as well as their interactions) affect the distribution between phases and their composition. This review provides an analysis of the state of the art on HTC, mainly with regard to the effect of variables on the process, the associated kinetics, and the characteristics of the solid phase (HC), as well as some of the more studied applications so far. The focus is on research made over the last five years on these topics. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.