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- ItemMultivariate Analysis of Coupled Operando EPR/XANES/EXAFS/UV–Vis/ATR-IR Spectroscopy: A New Dimension for Mechanistic Studies of Catalytic Gas-Liquid Phase Reactions(Weinheim : Wiley-VCH, 2020) Rabeah, Jabor; Briois, Valérie; Adomeit, Sven; La Fontaine, Camille; Bentrup, Ursula; Breckner, AngelikaOperando EPR, XANES/EXAFS, UV-Vis and ATR-IR spectroscopic methods have been coupled for the first time in the same experimental setup for investigation of unclear mechanistic aspects of selective aerobic oxidation of benzyl alcohol by a Cu/TEMPO catalytic system (TEMPO=2,2,6,6-tetramethylpiperidinyloxyl). By multivariate curve resolution with alternating least-squares fitting (MCR-ALS) of simultaneously recorded XAS and UV-Vis data sets, it was found that an initially formed (bpy)(NMI)CuI- complex (bpy=2,2′-bipyridine, NMI=N-methylimidazole) is converted to two different CuII species, a mononuclear (bpy)(NMI)(CH3CN)CuII-OOH species detectable by EPR and ESI-MS, and an EPR-silent dinuclear (CH3CN)(bpy)(NMI)CuII(μ-OH)2⋅CuII (bpy)(NMI) complex. The latter is cleaved in the further course of reaction into (bpy)(NMI)(HOO)CuII-TEMPO monomers that are also EPR-silent due to dipolar interaction with bound TEMPO. Both Cu monomers and the Cu dimer are catalytically active in the initial phase of the reaction, yet the dimer is definitely not a major active species nor a resting state since it is irreversibly cleaved in the course of the reaction while catalytic activity is maintained. Gradual formation of non-reducible CuII leads to slight deactivation at extended reaction times. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
- ItemNanostructured Silicon Matrix for Materials Engineering(Weinheim : Wiley-VCH, 2023) Liu, Poting; Schleusener, Alexander; Zieger, Gabriel; Bochmann, Arne; van Spronsen, Matthijs A.; Sivakov, VladimirTin-containing layers with different degrees of oxidation are uniformly distributed along the length of silicon nanowires formed by a top-down method by applying metalorganic chemical vapor deposition. The electronic and atomic structure of the obtained layers is investigated by applying nondestructive surface-sensitive X-ray absorption near edge spectroscopy using synchrotron radiation. The results demonstrated, for the first time, a distribution effect of the tin-containing phases in the nanostructured silicon matrix compared to the results obtained for planar structures at the same deposition temperatures. The amount and distribution of tin-containing phases can be effectively varied and controlled by adjusting the geometric parameters (pore diameter and length) of the initial matrix of nanostructured silicon. Due to the occurrence of intense interactions between precursor molecules and decomposition by-products in the nanocapillary, as a consequence of random thermal motion of molecules in the nanocapillary, which leads to additional kinetic energy and formation of reducing agents, resulting in effective reduction of tin-based compounds to a metallic tin state for molecules with the highest penetration depth in the nanostructured silicon matrix. This effect will enable clear control of the phase distributions of functional materials in 3D matrices for a wide range of applications.