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P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl- thio-phosphinic amide

2009, Peulecke, N., Aluri, B.R., Wöhl, A., Spannenberg, A., Al-Hazmi, M.H.

The title compound, C24H30N2P2S2, was obtained by the reaction of Ph2PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N - H⋯S hydrogen bonding influences the mol-ecular conformation; a P - N - P - N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°.