2015, Iablonskyi, D., Nagaya, K., Fukuzawa, H., Motomura, K., Kumagai, Y., Mondal, S., Tachibana, T., Takanashi, T., Nishiyama, T., Matsunami, K., Johnsson, P., Piseri, P., Sansone, G., Dubrouil, A., Reduzzi, M., Carpeggiani, P., Vozzi, C., Devetta, M., Negro, M., Faccialà, D., Calegari, F., Trabattoni, A., Castrovilli, M., Ovcharenko, Y., Möller, T., Mudrich, M., Stienkemeier, F., Coreno, M., Alagia, M., Schütte, B., Berrah, N., Callegari, C., Plekan, O., Finetti, P., Spezzani, C., Ferrari, E., Allaria, E., Penco, G., Serpico, C., De Ninno, G., Diviacco, B., Di Mitri, S., Giannessi, L., Prince, K.., Yao, M., Ueda, K.

We present a comprehensive analysis of autoionization processes in Ne clusters (~5000 atoms) after multiple valence excitations by free electron laser radiation. The evolution from 2-body interatomic Coulombic decay (ICD) to 3-body ICD is demonstrated when changing from surface to bulk Frenkel exciton excitation. Super Coster-Kronig type 2-body ICD is observed at Wannier exciton which quenches the main ICD channel.