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    Ammonia and greenhouse gas emissions from slurry storage : A review
    (Amsterdam [u.a.] : Elsevier, 2020) Kupper, Thomas; Häni, Christoph; Neftel, Albrecht; Kincaid, Chris; Bühler, Marcel; Amon, Barbara; VanderZaag, Andrew
    Storage of slurry is an important emission source for ammonia (NH3), nitrous oxide (N2O), methane (CH4), carbon dioxide (CO2) and hydrogen sulfide (H2S) from livestock production. Therefore, this study collected published emission data from stored cattle and pig slurry to determine baseline emission values and emission changes due to slurry treatment and coverage of stores. Emission data were collected from 120 papers yielding 711 records of measurements conducted at farm-, pilot- and laboratory-scale. The emission data reported in a multitude of units were standardized and compiled in a database. Descriptive statistics of the data from untreated slurry stored uncovered revealed a large variability in emissions for all gases. To determine baseline emissions, average values based on a weighting of the emission data according to the season and the duration of the emission measurements were constructed using the data from farm-scale and pilot-scale studies. Baseline emissions for cattle and pig slurry stored uncovered were calculated. When possible, it was further distinguished between storage in tanks without slurry treatment and storage in lagoons which implies solid-liquid separation and biological treatment. The baseline emissions on an area or volume basis are: for NH3: 0.12 g m−2 h-1 and 0.15 g m−2 h-1 for cattle and pig slurry stored in lagoons, and 0.08 g m−2 h-1 and 0.24 g m−2 h-1 for cattle and pig slurry stored in tanks; for N2O: 0.0003 g m−2 h-1 for cattle slurry stored in lagoons, and 0.002 g m−2 h-1 for both slurry types stored in tanks; for CH4: 0.95 g m-3 h-1 and 3.5 g m-3 h-1 for cattle and pig slurry stored in lagoons, and 0.58 g m-3 h-1 and 0.68 g m-3 h-1 for cattle and pig slurry stored in tanks; for CO2: 6.6 g m−2 h-1 and 0.3 g m−2 h-1 for cattle and pig slurry stored in lagoons, and 8.0 g m−2 h-1 for both slurry types stored in tanks; for H2S: 0.04 g m−2 h-1 and 0.01 g m−2 h-1 for cattle and pig slurry stored in lagoons. Related to total ammoniacal nitrogen (TAN), baseline emissions for tanks are 16% and 15% of TAN for cattle and pig slurry, respectively. Emissions of N2O and CH4 relative to nitrogen (N) and volatile solids (VS) are 0.13% of N and 0.10% of N and 2.9% of VS and 4.7% of VS for cattle and pig slurry, respectively. Total greenhouse gas emissions from slurry stores are dominated by CH4. The records on slurry treatment using acidification show a reduction of NH3 and CH4 emissions during storage while an increase occurs for N2O and a minor change for CO2 as compared to untreated slurry. Solid-liquid separation causes higher losses for NH3 and a reduction in CH4, N2O and CO2 emissions. Anaerobically digested slurry shows higher emissions during storage for NH3 while losses tend to be lower for CH4 and little changes occur for N2O and CO2 compared to untreated slurry. All cover types are found to be efficient for emission mitigation of NH3 from stores. The N2O emissions increase in many cases due to coverage. Lower CH4 emissions occur for impermeable covers as compared to uncovered slurry storage while for permeable covers the effect is unclear or emissions tend to increase. Limited and inconsistent data regarding emission changes with covering stores are available for CO2 and H2S. The compiled data provide a basis for improving emission inventories and highlight the need for further research to reduce uncertainty and fill data gaps regarding emissions from slurry storage.
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    Factors That Influence Nitrous Oxide Emissions from Agricultural Soils as Well as Their Representation in Simulation Models: A Review
    (Basel : MDPI, 2021-4-14) Wang, Cong; Amon, Barbara; Schulz, Karsten; Mehdi, Bano
    Nitrous oxide (N2O) is a long-lived greenhouse gas that contributes to global warming. Emissions of N2O mainly stem from agricultural soils. This review highlights the principal factors from peer-reviewed literature affecting N2O emissions from agricultural soils, by grouping the factors into three categories: environmental, management and measurement. Within these categories, each impact factor is explained in detail and its influence on N2O emissions from the soil is summarized. It is also shown how each impact factor influences other impact factors. Process-based simulation models used for estimating N2O emissions are reviewed regarding their ability to consider the impact factors in simulating N2O. The model strengths and weaknesses in simulating N2O emissions from managed soils are summarized. Finally, three selected process-based simulation models (Daily Century (DAYCENT), DeNitrification-DeComposition (DNDC), and Soil and Water Assessment Tool (SWAT)) are discussed that are widely used to simulate N2O emissions from cropping systems. Their ability to simulate N2O emissions is evaluated by describing the model components that are relevant to N2O processes and their representation in the model.
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    Identification of representative dairy cattle and fodder crop production typologies at regional scale in Europe
    (Berlin ; Heidelberg : Springer, 2022) Díaz de Otálora, Xabier; Dragoni, Federico; Del Prado, Agustín; Estellés, Fernándo; Wilfart, Aurélie; Krol, Dominika; Balaine, Lorraine; Anestis, Vasileios; Amon, Barbara
    European dairy production faces significant economic, environmental, and social sustainability challenges. Given the great diversity of dairy cattle production systems in Europe, region-specific concepts to improve environmental and socioeconomic sustainability are needed. Regionally integrated dairy cattle-crop systems emerge as a more resilient and sustainable alternative to highly specialized farming systems. Identifying different dairy cattle production typologies and their potential interactions with fodder crop production is presented as a step in transitioning to optimized agricultural systems. Currently existing typologies of integrated systems are often insufficient when characterizing structural, socioeconomic, and environmental components of farms. We fill this gap in the literature by identifying, describing, and comparing representative dairy cattle production system typologies and their interrelation with regional fodder crop production at the European regional scale. This is a necessary step to assess the scope for adapted mitigation and sustainability measures in the future. For this purpose, a multivariate statistical approach is applied. We show how different land-use practices, farm structure characteristics, socio-economic attributes, and emission intensities condition dairy production. Furthermore, the diversity of regional fodder crop production systems is demonstrated by analyzing their distribution in Europe. Together with identified typologies, varying degrees of regional specialization in milk production allow for identifying future strategies associated with the application of integrated systems in key European dairy regions. This study contributes to a better understanding of the existing milk production diversity in Europe and their relationship with regional fodder crop production. In addition, we discuss the benefits of integrated systems as a clear, viable, and resilient alternative to ongoing livestock intensification in the European context. Identifying interactions between components of integrated systems will facilitate decision-making, the design and implementation of measures to mitigate climate change, and the promotion of positive socio-economic and environmental interactions.
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    Urban nitrogen budgets: flows and stock changes of potentially polluting nitrogen compounds in cities and their surroundings–a review
    (London [u.a.] : Taylor & Francis, 2020) Winiwarter, Wilfried; Amon, Barbara; Bai, Zhaohai; Greinert, Andrzej; Kaltenegger, Katrin; Ma, Lin; Myszograj, Sylwia; Schneidergruber, Markus; Suchowski-Kisielewicz, Monika; Wolf, Lisa; Zhang, Lin; Zhou, Feng
    Concepts of material flow and mass consistency of nitrogen compounds have been used to elucidate nitrogen’s fate in an urban environment. While reactive nitrogen commonly is associated to agriculture and hence to large areas, here we have compiled scientific literature on nitrogen budget approaches in cities, following the central role cities have in anthropogenic activities generally. This included studies that specifically dealt with individual sectors as well as budgets covering all inputs and outputs to and from a city across all sectors and media. In the available data set, a clear focus on Asian cities was noted, making full use of limited information and thus enable to quantitatively describe a local pollution situation. Time series comparisons helped to identify trends, but comparison between cities was hampered by a lack of harmonized methodologies. Some standardization, or at least improved reference to relevant standardized data collection along international norms was considered helpful. Analysis of results available pointed to the following aspects that would reveal additional benchmarks for urban nitrogen budgets: analysing the share of nitrogen that is recycled or reused, separating largely independent sets of nitrogen flows specifically between food nitrogen streams and fossil fuel combustion-related flows, and estimating the stock changes for the whole domain or within individual pools.
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    DATAMAN: A global database of nitrous oxide and ammonia emission factors for excreta deposited by livestock and land-applied manure
    (Hoboken, NJ : Wiley, 2021) Beltran, Ignacio; van der Weerden, Tony J.; Alfaro, Marta A.; Amon, Barbara; de Klein, Cecile A. M.; Grace, Peter; Hafner, Sasha; Hassouna, Mélynda; Hutchings, Nicholas; Krol, Dominika J.; Leytem, April B.; Noble, Alasdair; Salazar, Francisco; Thorman, Rachel E.; Velthof, Gerard L.
    Nitrous oxide (N2 O), ammonia (NH3 ), and methane (CH4 ) emissions from the manure management chain of livestock production systems are important contributors to greenhouse gases (GHGs) and NH3 emitted by human activities. Several studies have evaluated manure-related emissions and associated key variables at regional, national, or continental scales. However, there have been few studies focusing on the drivers of these emissions using a global dataset. An international project was created (DATAMAN) to develop a global database on GHG and NH3 emissions from the manure management chain (housing, storage, and field) to identify key variables influencing emissions and ultimately to refine emission factors (EFs) for future national GHG inventories and NH3 emission reporting. This paper describes the "field" database that focuses on N2 O and NH3 EFs from land-applied manure and excreta deposited by grazing livestock. We collated relevant information (EFs, manure characteristics, soil properties, and climatic conditions) from published peer-reviewed research, conference papers, and existing databases. The database, containing 5,632 observations compiled from 184 studies, was relatively evenly split between N2 O and NH3 (56 and 44% of the EF values, respectively). The N2 O data were derived from studies conducted in 21 countries on five continents, with New Zealand, the United Kingdom, Kenya, and Brazil representing 86% of the data. The NH3 data originated from studies conducted in 17 countries on four continents, with the United Kingdom, Denmark, Canada, and The Netherlands representing 79% of the data. Wet temperate climates represented 90% of the total database. The DATAMAN field database is available at http://www.dataman.co.nz.
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    Ammonia and nitrous oxide emission factors for excreta deposited by livestock and land-applied manure
    (Hoboken, NJ : Wiley, 2021) van der Weerden, Tony J.; Noble, Alasdair; de Klein, Cecile A. M.; Hutchings, Nicholas; Thorman, Rachel E.; Alfaro, Marta A.; Amon, Barbara; Beltran, Ignacio; Grace, Peter; Hassouna, Mélynda; Krol, Dominika J.; Leytem, April B.; Salazar, Francisco; Velthof, Gerard L.
    Manure application to land and deposition of urine and dung by grazing animals are major sources of ammonia (NH3 ) and nitrous oxide (N2 O) emissions. Using data on NH3 and N2 O emissions following land-applied manures and excreta deposited during grazing, emission factors (EFs) disaggregated by climate zone were developed, and the effects of mitigation strategies were evaluated. The NH3 data represent emissions from cattle and swine manures in temperate wet climates, and the N2 O data include cattle, sheep, and swine manure emissions in temperate wet/dry and tropical wet/dry climates. The NH3 EFs for broadcast cattle solid manure and slurry were 0.03 and 0.24 kg NH3 -N kg-1 total N (TN), respectively, whereas the NH3 EF of broadcast swine slurry was 0.29. Emissions from both cattle and swine slurry were reduced between 46 and 62% with low-emissions application methods. Land application of cattle and swine manure in wet climates had EFs of 0.005 and 0.011 kg N2 O-N kg-1 TN, respectively, whereas in dry climates the EF for cattle manure was 0.0031. The N2 O EFs for cattle urine and dung in wet climates were 0.0095 and 0.002 kg N2 O-N kg-1 TN, respectively, which were three times greater than for dry climates. The N2 O EFs for sheep urine and dung in wet climates were 0.0043 and 0.0005, respectively. The use of nitrification inhibitors reduced emissions in swine manure, cattle urine/dung, and sheep urine by 45-63%. These enhanced EFs can improve national inventories; however, more data from poorly represented regions (e.g., Asia, Africa, South America) are needed.
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    Airflow Characteristics Downwind a Naturally Ventilated Pig Building with a Roofed Outdoor Exercise Yard and Implications on Pollutant Distribution
    (Basel : MDPI AG, 2020) Yi, Qianying; Janke, David; Thormann, Lars; Zhang, Guoqiang; Amon, Barbara; Hempel, Sabrina; Nosek, Štěpán; Hartung, Eberhard; Amon, Thomas
    The application of naturally ventilated pig buildings (NVPBs) with outdoor exercise yards is on the rise mainly due to animal welfare considerations, while the issue of emissions from the buildings to the surrounding environment is important. Since air pollutants are mainly transported by airflow, the knowledge on the airflow characteristics downwind the building is required. The objective of this research was to investigate airflow properties downwind of a NVPB with a roofed outdoor exercise yard for roof slopes of 5°, 15°, and 25°. Air velocities downwind a 1:50 scaled NVPB model were measured using a Laser Doppler Anemometer in a large boundary layer wind tunnel. A region with reduced mean air velocities was found along the downwind side of the building with a distance up to 0.5 m (i.e., 3.8 times building height), in which the emission concentration might be high. Additional air pollutant treatment technologies applied in this region might contribute to emission mitigation effectively. Furthermore, a wake zone with air recirculation was observed in this area. A smaller roof slope (i.e., 5° slope) resulted in a higher and shorter wake zone and thus a shorter air pollutant dispersion distance.
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    Opening Size E ects on Airflow Pattern and Airflow Rate of a Naturally Ventilated Dairy Building : A CFD Study
    (Basel : MDPI, 2020) Saha, Chayan Kumer; Yi, Qianying; Janke, David; Hempel, Sabrina; Amon, Barbara; Amon, Thomas
    Airflow inside naturally ventilated dairy (NVD) buildings is highly variable and difficult to understand due to the lack of precious measuring techniques with the existing methods. Computational fluid dynamics (CFD) was applied to investigate the effect of different seasonal opening combinations of an NVD building on airflow patterns and airflow rate inside the NVD building as an alternative to full scale and scale model experiments. ANSYS 2019R2 was used for creating model geometry, meshing, and simulation. Eight ventilation opening combinations and 10 different reference air velocities were used for the series of simulation. The data measured in a large boundary layer wind tunnel using a 1:100 scale model of the NVD building was used for CFD model validation. The results show that CFD using standard k-ε turbulence model was capable of simulating airflow in and outside of the NVD building. Airflow patterns were different for different opening scenarios at the same external wind speed, which may affect cow comfort and gaseous emissions. Guiding inlet air by controlling openings may ensure animal comfort and minimize emissions. Non-isothermal and transient simulations of NVD buildings should be carried out for better understanding of airflow patterns.
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    Inventory reporting of livestock emissions: the impact of the IPCC 1996 and 2006 Guidelines
    (Bristol : IOP Publ., 2021-6-22) Amon, Barbara; Çinar, Gültaç; Anderl, Michael; Dragoni, Federico; Kleinberger-Pierer, Magdalena; Hörtenhuber, Stefan
    The livestock sector is a major contributor to agricultural greenhouse gas (GHG) and nitrogen (N) emissions and efforts are being made to reduce these emissions. National emission inventories are the main tool for reporting emissions. They have to be consistent, comparable, complete, accurate and transparent. The quality of emission inventories is affected by the reporting methodology, emission factors and knowledge of individual sources. In this paper, we investigate the effects of moving from the 1996 IPCC Guidelines for National Greenhouse Gas Inventories to the 2006 IPCC Guidelines on the emission estimates from the livestock sector. With Austria as a case study, we estimated the emissions according to the two guidelines, revealing marked changes in emission estimates from different source categories resulting from changes in the applied methodology. Overall estimated GHG emissions from the livestock sector decreased when applying the IPCC 2006 methodology, except for emissions from enteric fermentation. Our study revealed shifts in the relative importance of main emission sources. While the share of CH4 emissions from enteric fermentation and manure management increased, the share of N2O emissions from manure management and soils decreased. The most marked decrease was observed for the share of indirect N2O emissions. Our study reveals a strong relationship between the emission inventory methodology and mitigation options as mitigation measures will only be effective for meeting emission reduction targets if their effectiveness can be demonstrated in the national emission inventories. We include an outlook on the 2019 IPCC Refinement and its potential effects on livestock emissions estimates. Emission inventory reports are a potent tool to show the effect of mitigation measures and the methodology prescribed in inventory guidelines will have a distinct effect on the selection of mitigation measures.
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    Assessing the contribution of soil NOx emissions to European atmospheric pollution
    (Bristol : IOP Publ., 2021) Skiba, Ute; Medinets, Sergiy; Cardenas, Laura M.; Carnell, Edward John; Hutchings, Nick; Amon, Barbara
    Atmospheric NOx concentrations are declining steadily due to successful abatement strategies predominantly targeting combustion sources. On the European continent, total NOx emissions fell by 55% between 1990 and 2017, but only modest reductions were achieved from the agricultural sector; with 7.8% from 20 Eastern European countries and 19.1% from 22 Western European countries. Consequently, the share of agricultural NOx emissions for these 42 European countries have increased from 3.6% to 7.2%. These values are highly uncertain due to serious lack of studies from agricultural soils and manure management. The emission factor (EFNO 1.33%), currently used for calculating soil NOx emissions from European agricultural categories ‘N applied to soils’ and ‘manure management’ was evaluated here by including recently published data from temperate climate zones. The newly calculated EFNO (average 0.60%, 0.0625th%/0.5475th%, n = 65 studies) is not notably different from the current value, given the large uncertainties associated with the small pool of studies, and therefore continued use of EFNO (1.33%) is recommended until more data become available. An assessment of the contribution of agricultural and non-agricultural NOx sources found that of the 42 European countries, the 8 most populated countries achieved considerable reductions (1990–2017) from categories ‘non-agricultural sources’ (55%), ‘N applied to soils’ (43%) and ‘manure management’ (1.2%), compared to small reductions from the remaining 34 countries. Forests are also large sources of soil NOx. On average, emissions from Eastern European forests were 4 times larger than from ‘N applied agricultural soil’, whereas Western European NOx emissions from ‘N applied agricultural soil’ were two times larger than from forest soils. Given that non-agricultural sources of NOx continue to decline, soil related emissions from agriculture, forests and manure management become more important, and require rigorous investigation in order to improve atmospheric pollution forecasts.