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- ItemInfluence of water on tribolayer growth when lubricating steel with a fluorinated phosphonium dicyanamide ionic liquid(Basel : MDPI, 2019) Urtis, L.A.; Arcifa, A.; Zhang, P.; Du, J.; Fantauzzi, M.; Rauber, D.; Hempelmann, R.; Kraus, T.; Rossi, A.; Spencer, N.D.This work aims to elucidate the role of environmental humidity on the tribological behavior of steel surfaces lubricated with an ionic liquid comprised of a fluorinated phosphonium cation-tributyl-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl-phosphonium-and a dicyanamide anion (i.e. N(CN) 2 - ). Ball-on-disk tribotests were carried out at room temperature and at various levels of relative humidity (RH). Water was found to be required to promote the formation of a tribofilm over the contact area. The reaction layer exhibited a patchy morphology, which resembles that observed formed with conventional antiwear additives such as ZnDTP. A surface-chemical analysis of the tribofilm indicated that the tribofilm is composed of fluorides, oxides, and phosphates, pointing to a stress-induced degradation of the ions and corrosion of the sliding counterparts, which is enabled by the presence of water at the sliding interface. © 2019 by the authors.