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- ItemDicyclohexylbis(naphthalen-1-ylmethyl)phosphonium chloride chloroform disolvate(Chester : International Union of Crystallography, 2012) Gowrisankar, S.; Neumann, H.; Spannenberg, A.; Beller, M.In the title solvated phosphonium salt, C34H40P+·Cl -·2CHCl3, the two cyclohexyl and two 1-naphthylmethyl groups at the P atom are in a distorted tetrahedral arrangement [105.26 (6)-113.35 (6)°]. Both cyclohexyl rings adopt a chair conformation. The dihedral angle between the naphthyl ring systems is 74.08 (3)°.
- Item(η6-Benzene)(carbonato-κ2O,O') [dicyclohexyl(naphthalen-1-ylmethyl)phosphanejP] ruthenium(II) chloroform trisolvate(Chester : International Union of Crystallography, 2014) Gowrisankar, S.; Neumann, H.; Spannenberg, A.; Beller, M.The title compound, [Ru(CO3)(η6-C 6H6){(C6H11)2P(CH 2-C10H7)}]-3CHCl3, was synthesized by carbonation of [RuCl2-(η6-C6H 6){(C6H11)2P(CH2C 10H7)}] with NaHCO3in methanol at room temperature. The RuIIatom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding interactions between adjacent metal complexes and between the complexes and the solvent molecules. The asymmetric unit contains one metal complex and three chloroform solvent molecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloroform solvent molecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON.
- Item(η6-Benzene)dichlorido(chlorodicyclohexylphosphane-κp) ruthenium(II) chloroform monosolvate(Chester : International Union of Crystallography, 2014) Gowrisankar, S.; Neumann, H.; Spannenberg, A.; Beller, M.The title compound, [RuN4(-6-C6H6) (C12H22ClP)]-CHCl3, was prepared by reaction of [RuN 4(-6-C6H6)]2 with chlorodicyclohexyl phosphane in CHCl3 at 323 K under argon. The RuII atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru-P bond length of 2.3247 (4) Å. Both cyclohexyl rings at the P atom adopt a chair conformation. In the crystal, the RuII complex molecule and the chloroform solvent molecule are linked by a bifurcated C-H⋯(Cl,Cl) hydrogen bond. Intramolecular C-H⋯Cl hydrogen bonds are also observed.
- Item2,6-Bis[(S)-4-benzyl-4,5-dihydro-1,3-oxazol-2-yl]pyridine(Chester : International Union of Crystallography, 2011) Möller, K.; Junge, K.; Spannenberg, A.; Beller, M.The commercially available title compound, C25H 23N3O2, has been known since 1993 [Nesper et al. (1993). Helv. Chim. Acta, 76, 2239-2249], but has not been structurally characterized until now. In the free ligand, the N atoms of both oxazoline rings point in opposite directions. The phenyl rings make dihedral angles of 30.56 (5) and 84.57 (3)° with the pyridine ring and 72.85 (3)° with each other.