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Cobalt pincer complexes for catalytic reduction of nitriles to primary amines

2019, Schneekönig, Jacob, Tannert, Bianca, Hornke, Helen, Beller, Matthias, Junge, Kathrin

Various cobalt pincer type complexes 1-6 were applied for the catalytic hydrogenation of nitriles to amines. Among these, catalyst 4 is the most efficient, allowing the reduction of aromatic as well as aliphatic nitriles in moderate to excellent yields. © 2019 The Royal Society of Chemistry.