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    Properties of textile glass fibers based on alkali- and boron oxide-free aluminosilicate glasses
    (Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1998) Kim, Young Keun; Brückner, Rolf; Murach, Jürgen
    The goal of this paper is to examine the possibihty of producing fibers from alkah- and boron oxide-free glasses with properties comparable to those of commercially available glass fibers. Various compositions from the Systems SiO₂ - Al₂O₃ - CaO - RO are investigated with RO = MgO, ZnO, MnO, BaO between 0 and 10 wt%. The fibers are suitable for application as textile fibers and as reinforcement component for composites. The mechanical properties (tensile strength, Young's and shear modulus and Poisson ratio) are comparable to and/or partly better than those of commercially produced glass fibers. The chemical resistivity in 2 mol/1 NaOH is better than that of E-glass fibers. Although the diameter of glass fibers is not the only parameter which determines fiber properties and structure, it is a very important one because it influences both the mechanical and the thermal history of the fibers. For this reason, and in order to approximate commercial fiber drawing conditions, fibers were prepared with roughly the same fiber diameters. Despite this restriction the results provide information for qualitative ratings and for relative comparison of properties and structural interpretations. Of special interest is the opposite dependence of strength and elastic moduli on the fiber diameter. This is explained by means of frozen-in orientation and deformation effects of microcracks and network anisometries due to the mechanical and thermal history of the fibers produced by the fiber drawing process.