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Author: Deckert, Volker × DDC: 530 × Type: Text × WGL Institute: IPHT ×

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    Direct molecular-level near-field plasmon and temperature assessment in a single plasmonic hotspot
    (London : Nature Publishing Group, 2020) Richard-Lacroix, Marie; Deckert, Volker
    Tip-enhanced Raman spectroscopy (TERS) is currently widely recognized as an essential but still emergent technique for exploring the nanoscale. However, our lack of comprehension of crucial parameters still limits its potential as a user-friendly analytical tool. The tip’s surface plasmon resonance, heating due to near-field temperature rise, and spatial resolution are undoubtedly three challenging experimental parameters to unravel. However, they are also the most fundamentally relevant parameters to explore, because they ultimately influence the state of the investigated molecule and consequently the probed signal. Here we propose a straightforward and purely experimental method to access quantitative information of the plasmon resonance and near-field temperature experienced exclusively by the molecules directly contributing to the TERS signal. The detailed near-field optical response, both at the molecular level and as a function of time, is evaluated using standard TERS experimental equipment by simultaneously probing the Stokes and anti-Stokes spectral intensities. Self-assembled 16-mercaptohexadodecanoic acid monolayers covalently bond to an ultra-flat gold surface were used as a demonstrator. Observation of blinking lines in the spectra also provides crucial information on the lateral resolution and indication of atomic-scale thermally induced morphological changes of the tip during the experiment. This study provides access to unprecedented molecular-level information on physical parameters that crucially affect experiments under TERS conditions. The study thereby improves the usability of TERS in day-to-day operation. The obtained information is of central importance for any experimental plasmonic investigation and for the application of TERS in the field of nanoscale thermometry. © 2020, The Author(s).
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    A fiber optic-nanophotonic approach to the detection of antibodies and viral particles of COVID-19
    (Berlin : de Gruyter, 2020) Rajil, Navid; Sokolov, Alexei; Yi, Zhenhuan; Adams, Garry; Agarwal, Girish; Belousov, Vsevolod; Brick, Robert; Chapin, Kimberly; Cirillo, Jeffrey; Deckert, Volker; Delfan, Sahar; Esmaeili, Shahriar; Fernández-González, Alma; Fry, Edward; Han, Zehua; Hemmer, Philip; Kattawar, George; Kim, Moochan; Lee, Ming-Che; Lu, Chao-Yang; Mogford, Jon; Neuman, Benjamin; Pan, Jian-Wei; Peng, Tao; Poor, Vincent; Scully, Steven; Shih, Yanhua; Suckewer, Szymon; Svidzinsky, Anatoly; Verhoef, Aart; Wang, Dawei; Wang, Kai; Yan, Lan; Zheltikov, Aleksei; Zhu, Shiyao; Zubairy, Suhail; Scully, Marlan
    Dr. Deborah Birx, the White House Coronavirus Task Force coordinator, told NBC News on "Meet the Press"that "[T]he U.S. needs a 'breakthrough' in coronavirus testing to help screen Americans and get a more accurate picture of the virus' spread."We have been involved with biopathogen detection since the 2001 anthrax attacks and were the first to detect anthrax in real-time. A variation on the laser spectroscopic techniques we developed for the rapid detection of anthrax can be applied to detect the Severe Acute Respiratory Syndrome-Corona Virus-2 (SARS-CoV-2 virus). In addition to detecting a single virus, this technique allows us to read its surface protein structure. In particular, we have been conducting research based on a variety of quantum optical approaches aimed at improving our ability to detect Corona Virus Disease-2019 (COVID-19) viral infection. Indeed, the detection of a small concentration of antibodies, after an infection has passed, is a challenging problem. Likewise, the early detection of disease, even before a detectible antibody population has been established, is very important. Our team is researching both aspects of this problem. The paper is written to stimulate the interest of both physical and biological scientists in this important problem. It is thus written as a combination of tutorial (review) and future work (preview). We join Prof. Federico Capasso and Editor Dennis Couwenberg in expressing our appreciation to all those working so heroically on all aspects of the COVID-19 problem. And we thank Drs. Capasso and Couwenberg for their invitation to write this paper. © 2020 Navid Rajil et al., published by De Gruyter, Berlin/Boston 2020.