2017-1-23, Morales Torres, Galina, Behrens, Stephan, Michalik, Dirk, Selent, Detlef, Spannenberg, Anke, Lühr, Susan, Dyballa, Katrin Marie, Franke, Robert, Börner, Armin

A series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2-diamine unit in the backbone. New compounds were tested alongside related N-acyl phosphoramidites as ligands in the Rh-catalyzed hydroformylation of n-octenes to investigate their influence on the activity and regioselectivity. A subsequent study of their hydrolysis stability revealed that the most stable ligands induced the highest activity in the catalytic reaction.