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Now showing 1 - 4 of 4
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    Local melting to design strong and plastically deformable bulk metallic glass composites
    (London : Nature Publishing Group, 2017) Qin, Yue-Sheng; Han, Xiao-Liang; Song, Kai-Kai; Tian, Yu-Hao; Peng, Chuan-Xiao; Wang, Li; Sun, Bao-An; Wang, Gang; Kaban, Ivan; Eckert, Jürgen
    Recently, CuZr-based bulk metallic glass (BMG) composites reinforced by the TRIP (transformation-induced plasticity) effect have been explored in attempt to accomplish an optimal of trade-off between strength and ductility. However, the design of such BMG composites with advanced mechanical properties still remains a big challenge for materials engineering. In this work, we proposed a technique of instantaneously and locally arc-melting BMG plate to artificially induce the precipitation of B2 crystals in the glassy matrix and then to tune mechanical properties. Through adjusting local melting process parameters (i.e. input powers, local melting positions, and distances between the electrode and amorphous plate), the size, volume fraction, and distribution of B2 crystals were well tailored and the corresponding formation mechanism was clearly clarified. The resultant BMG composites exhibit large compressive plasticity and high strength together with obvious work-hardening ability. This compelling approach could be of great significance for the steady development of metastable CuZr-based alloys with excellent mechanical properties.
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    Mechanical and structural investigation of porous bulk metallic glasses
    (Basel : MDPI, 2015) Wu, Dianyu; Song, Kaikai; Cao, Chongde; Li, Ran; Wang, Gang; Wu, Yuan; Wan, Feng; Ding, Fuli; Shi, Yue; Bai, Xiaojun; Kaban, Ivan; Eckert, Jürgen
    The intrinsic properties of advanced alloy systems can be altered by changing their microstructural features. Here, we present a highly efficient method to produce and characterize structures with systematically-designed pores embedded inside. The fabrication stage involves a combination of photolithography and deep reactive ion etching of a Si template replicated using the concept of thermoplastic forming. Pt- and Zr-based bulk metallic glasses (BMGs) were evaluated through uniaxial tensile test, followed by scanning electron microscope (SEM) fractographic and shear band analysis. Compositional investigation of the fracture surface performed via energy dispersive X-ray spectroscopy (EDX), as well as Auger spectroscopy (AES) shows a moderate amount of interdiffusion (5 at.% maximum) of the constituent elements between the deformed and undeformed regions. Furthermore, length-scale effects on the mechanical behavior of porous BMGs were explored through molecular dynamics (MD) simulations, where shear band formation is observed for a material width of 18 nm.
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    Deformation-induced martensitic transformation in Cu-Zr-Zn bulk metallic glass composites
    (Basel : MDPI, 2015) Wu, Dianyu; Song, Kaikai; Cao, Chongde; Li, Ran; Wang, Gang; Wu, Yuan; Wan, Feng; Ding, Fuli; Shi, Yue; Bai, Xiaojun; Kaban, Ivan; Eckert, Jürgen
    The microstructures and mechanical properties of (Cu0.5Zr0.5)100−xZnx (x = 0, 1.5, 2.5, 4.5, 7, 10, and 14 at. %) bulk metallic glass (BMG) composites were studied. CuZr martensitic crystals together with minor B2 CuZr and amorphous phases dominate the microstructures of the as-quenched samples with low Zn additions (x = 0, 1.5, and 2.5 at. %), while B2 CuZr and amorphous phases being accompanied with minor martensitic crystals form at a higher Zn content (x = 4.5, 7, 10, and 14 at. %). The fabricated Cu-Zr-Zn BMG composites exhibit macroscopically appreciable compressive plastic strain and obvious work-hardening due to the formation of multiple shear bands and the deformation-induced martensitic transformation (MT) within B2 crystals. The present BMG composites could be a good candidate as high-performance structural materials.
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    Local microstructure evolution at shear bands in metallic glasses with nanoscale phase separation
    (London : Nature Publishing Group, 2016) He, Jie; Kaban, Ivan; Mattern, Norbert; Song, Kaikai; Sun, Baoan; Kim, Do Hyang; Eckert, Jürgen; Greer, A.Lindsay
    At room temperature, plastic flow of metallic glasses (MGs) is sharply localized in shear bands, which are a key feature of the plastic deformation in MGs. Despite their clear importance and decades of study, the conditions for formation of shear bands, their structural evolution and multiplication mechanism are still under debate. In this work, we investigate the local conditions at shear bands in new phase-separated bulk MGs containing glassy nanospheres and exhibiting exceptional plasticity under compression. It is found that the glassy nanospheres within the shear band dissolve through mechanical mixing driven by the sharp strain localization there, while those nearby in the matrix coarsen by Ostwald ripening due to the increased atomic mobility. The experimental evidence demonstrates that there exists an affected zone around the shear band. This zone may arise from low-strain plastic deformation in the matrix between the bands. These results suggest that measured property changes originate not only from the shear bands themselves, but also from the affected zones in the adjacent matrix. This work sheds light on direct visualization of deformation-related effects, in particular increased atomic mobility, in the region around shear bands.