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Author: Fery, Andreas × Author: König, Tobias A.F. × DDC: 540 × Type: Text × Publisher: Weinheim : Wiley-VCH ×

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    Nanoimprint Lithography Facilitated Plasmonic-Photonic Coupling for Enhanced Photoconductivity and Photocatalysis
    (Weinheim : Wiley-VCH, 2021) Gupta, Vaibhav; Sarkar, Swagato; Aftenieva, Olha; Tsuda, Takuya; Kumar, Labeesh; Schletz, Daniel; Schultz, Johannes; Kiriy, Anton; Fery, Andreas; Vogel, Nicolas; König, Tobias A.F.
    Imprint lithography has emerged as a reliable, reproducible, and rapid method for patterning colloidal nanostructures. As a promising alternative to top-down lithographic approaches, the fabrication of nanodevices has thus become effective and straightforward. In this study, a fusion of interference lithography (IL) and nanosphere imprint lithography on various target substrates ranging from carbon film on transmission electron microscope grid to inorganic and dopable polymer semiconductor is reported. 1D plasmonic photonic crystals are printed with 75% yield on the centimeter scale using colloidal ink and an IL-produced polydimethylsiloxane stamp. Atomically smooth facet, single-crystalline, and monodisperse colloidal building blocks of gold (Au) nanoparticles are used to print 1D plasmonic grating on top of a titanium dioxide (TiO2) slab waveguide, producing waveguide-plasmon polariton modes with superior 10 nm spectral line-width. Plasmon-induced hot electrons are confirmed via two-terminal current measurements with increased photoresponsivity under guiding conditions. The fabricated hybrid structure with Au/TiO2 heterojunction enhances photocatalytic processes like degradation of methyl orange (MO) dye molecules using the generated hot electrons. This simple colloidal printing technique demonstrated on silicon, glass, Au film, and naphthalenediimide polymer thus marks an important milestone for large-scale implementation in optoelectronic devices. © 2021 The Authors. Advanced Functional Materials published by Wiley-VCH GmbH
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    Mechanotunable Plasmonic Properties of Colloidal Assemblies
    (Weinheim : Wiley-VCH, 2020) Brasse, Yannic; Gupta, Vaibhav; Schollbach, H.C. Tomohiro; Karg, Matthias; König, Tobias A.F.; Fery, Andreas
    Noble metal nanoparticles can absorb incident light very efficiently due to their ability to support localized surface plasmon resonances (LSPRs), collective oscillations of the free electron cloud. LSPRs lead to strong, nanoscale confinement of electromagnetic energy which facilitates applications in many fields including sensing, photonics, or catalysis. In these applications, damping of the LSPR caused by inter- and intraband transitions is a limiting factor due to the associated energy losses and line broadening. The losses and broad linewidth can be mitigated by arranging the particles into periodic lattices. Recent advances in particle synthesis, (self-)assembly, and fabrication techniques allow for the realization of collective coupling effects building on various particle sizes, geometries, and compositions. Beyond assemblies on static substrates, by assembling or printing on mechanically deformable surfaces a modulation of the lattice periodicity is possible. This enables significant alteration and tuning of the optical properties. This progress report focuses on this novel approach for tunable spectroscopic properties with a particular focus on low-cost and large-area fabrication techniques for functional plasmonic lattices. The report concludes with a discussion of the perspectives for expanding the mechanotunable colloidal concept to responsive structures and flexible devices. © 2019 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim