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- ItemDepth profiling analysis of lithium and barium disilicate coatings on silica glass(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1998) Schmitz, Regine; Frischat, Günther HeinzThe electron gas secondary neutral mass spectrometry, operated in the high-frequency mode, is especially suitable for the analysis of electrically insulating materials. This is demonstrated for the sol-gel coating Systems Li₂O · 2 SiO₂ and BaO · 2 SiO₂ on silica glass Substrates as examples. The Li₂O · 2 SiO₂ coating is crystalline and displays fluctuations in composition and/or phases. This heterogeneity is confirmed on atomic force microscope Images. Depending on heat treatment the BaO · 2 SiO₂ coatings are glassy and crystalline, respectively. They do not show any fluctuations; however, the depth profiles display some AI₂O₃ having diffused from the silica Substrates into the films during sol-gel consolidadon. Atomic force microscope Images reveal grooves in the Substrate surfaces in which AI₂O₃ remnants of the grinding process have been captured. The depth of the AI₂O₃ profile from the SNMS measurement corresponds to the depth of Channels found using the atomic force microscope. It is assumed that AI₂O₃ originates from remnants of the grinding material used to produce the silica Substrates.
- ItemImproved homogeneity of various glasses by gas film levitation(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1998) Janke, Achim; Frischat, Günther HeinzHeavy-metal fluoride glasses of the system ZrF₄-BaF₂-LaF₃-AlF₃-NaF and soda-lime-silica glasses both from industrial and laboratory crucible production were processed by the gas film levitation technique. In this process the glass melt is suspended contactlessly on a thin gas film, avoiding any reaction with the crucible material. This prevents chemical contamination, surface defects and heterogeneous nucleation, which is especially advantageous for the preparation of specialty glasses. The overall homogeneity of the glasses was strongly improved, too, which was characterized quantitatively by the Christiansen-Shelyubskii method.
- ItemHomogenization of glass melts by bubbling on a laboratory scale(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1994) Högerl, Klaus; Frischat, Günther HeinzIn a typical melter, the molten glass tends to be inhomogeneous due to the heterogeneity of the raw materials. One means of yielding more homogeneous glass is bubbling air through the glass melt through nozzles at the base of the melter. The induced fluid flow dissolves cords and homogenizes the glass melt. This bubbling process was investigated on a laboratory scale both from an experimental and a theoretical point of view. A standard soda-lime-silica glass was bubbled with argon in a platinum crucible at 1400 C. The samples treated were tested with regard to their optical homogeneity, using an improved version of the Christiansen-Shelyubskii method. The corresponding fluid flow phenomena were simulated by a suitable mathematical model. Due to the axial symmetry of the bubbling equipment and the high viscosity of the glass melt (creeping flow), the problem can be reduced to the solution of a differential equation of the fourth order with the stream function as independent variable. The numerical treatment superposes Gegenbauer functions matching the given boundary values for the velocity and tension, respectively. The homogeneity strongly increased with bubbling time and its local variation showed good correlation with the calculated flow pattern in the crucible.
- ItemApplication of the Christiansen-Shelyubskii method to determine homogeneity and refractive index of industrial glasses(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1995) Tenzler, Thomas; Frischat, Günther HeinzThe Christiansen-Shelyubskii method has been applied to determine the homogeneity of both colorless and colored technical glasses. It could be confirmed that this method is sufficiently sensitive to changes by the melting process of flat, container and special glasses. The homogeneity factor, which essentially is the standard deviation of the refractive index, can be obtained with a precision of about ±5 %. The measurement simultaneously delivers the mean refractive index with high accuracy. This property possibly could be used to substitute density measurements to control the constancy of glass composition. The Christiansen-Shelyubskii method can be standardized and highly automated. About 15 samples can be measured per day. Thus it shows all features of a method to be used for industrial quality control.
- ItemMorphology of silica and borosilicate glass fracture surfaces by atomic force microscopy(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1999) Wünsche, Christine; Rädlein, Edda; Frischat, Günther HeinzFracture surfaces of Herasil (silica) and Duran (borosilicate) glass rods were examined with an atomic force microscope. Generally the roughness in the fracture surface increases with growing distance from the origin of fracture. The morphology displays a variety of features. In the smooth fracture mirror near the origin of fracture the surface consists of small hillocks ≈25 nm in diameter and ≤ 1 nm high. With growing distance these hillocks increase in size and height. In the mist zone bigger outcrops occur with steep flanks. Steps can also be discovered in the fracture surface. Parts of the surface are covered by ripples, which are proposed to result from a local melting of the glass near the crack tip during fracture.
- ItemInfluence of small additions of Li₂O raw materials on glass melting(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1995) Tang, Yan; Frischat, Günther HeinzFor a container glass composition up to 1 mol% of the alkali oxide was substituted by Li₂O in steps of ≈0.2 %. The lithia was added as Li₂CO₃ and as spodumene, respectively. As shown earlier Li₂O reduces the viscosity of the melts considerably, irrespective of the Li₂O source. However, melt formation, carbonate decomposidon, silicate and silicate melt formation processes during raw materials reactions are considerably accelerated by Li₂CO₃ addition only, whereas Li₂O in the spodumene silicate does not enhance these reactions. The fining of the melt and the corrosion behavior of refractories are strongly influenced also by the lower viscosity melts. Thus, the corrosion rate may be diminished by temperature reduction at constant viscosity. For technical purposes the glasses are very stable against crystallization, however, thermal analysis shows that the higher the Li₂O content is, the faster the crystal growth proceeds. The surface tension of the glass melts decreases and the water leach resistance of the solid glasses is enhanced with increasing Li₂O content. The Li⁺ ions are less polarizable and, due to their high Dietzel field strength, the glass structure is dghtened compared with that of Li₂O-free glass. In conclusion, the substitution of small amounts of Li₂O instead of Na₂O and/or K₂O shows several advantages. At low temperatures different raw materials reactions are accelerated and at high temperature the decrease in melt viscosity is decisive.
- ItemSol-gel preparation of scratch-resistant AI₂O₃ coatings on float glass(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1999) Hauk, Rainer; Frischat, Günther Heinz; Ruppert, KarlGlass surfaces including those of automotive glazing show insufficient Scratch resistance. In order to improve this, a sol-gel process has been developed by means of which scratch-resistant and transparent corundum coatings (α-Αl₂O₃) may be deposited on glass surfaces. Coatings which were produced by using commercial boehmite(AlOOH) dispersions could also be completely transformed into α-Αl₂O₃, but they were not dense enough at about 500 nm thickness. Coatings produced by an alkoxide-gel process from aluminium butoxide were dense at a thickness of maximal 100 nm and adhered very well to the glass surface which had been slightly roughened by HF etching. Α Scratch test with a quartz grain showed that the damage of the glass surfaces coated in this way was less than 2 % compared to that of uncoated surfaces. Transmission of these coated glasses was about 90 % in the visible wavelength ränge.
- ItemDrawing of oxynitride glass fibers(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1997) Kaplan-Dietrich, Hannelore; Frischat, Günther HeinzGlass fibers were drawn from three MgO-Al₂O₃-Y₂O₃-SiO₂-based oxynitride glass melts. Α single-hole bushing process was used to spin the melts containing nitrogen contents between about 13 and 16at.%. The drawing process is described in detail, and it is shown that besides melt viscosity the high surface tension of the oxynitride glass melts strongly controls the fiberization. Thi s is analyzed in terms of Reynolds and Weber numbers. Glass fibers up to a length of about 30 cm can be drawn for Reynolds numbers between about O.Ol and 0.2 and Weber numbers between about 2.6 and 3.1, however, even there the fiber diameter oscillates to some extent. For smaller Reynolds and Weber numbers it is impossible to draw fibers at all. In this instability regime only droplets leave the nozzle outlet. The oxynitride fibers obtained have excellent mechanical properties and a high chemical resistance to alkaline attack.
- ItemLaboratory trials to incorporate sulphur in the vitrification of filter ashes from incineration plants and hydrolytic investigation of the melt products(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1997) Schumacher, Leo; Frischat, Günther HeinzIncineration of refuse in incineration plants produces toxic dusts in the waste gas filters which have to be disposed of Vitrification is one possibility of immobilization of such dusts which are contaminated by heavy metals, sulphates and Chlorides. Under oxidizing melting conditions, alkaline sulphates a n d Chlorides would volatilize and would have to be precipitated again. Therefore, in this work reducing melts were used. Thus, it was possible to reduce the sulphate to sulphide and to incorporate the latter in the glass matrix to an efficiency of up to 100%. This is experimentally proved by melting batch compositions of a filter ash from a refuse incineration plant with glass forming additives as well as model glasses. The reduction of CaSO₄ and formation of sulphides is induced by means of suitable additions of the Clements carbon, iron, zinc, titanium, manganese, Silicon, and aluminium, separately and in combination. The sulphides CaS, FeS, ZnS, MnS and AI₂S₃ are present in the melt product mainly in giassy form and only for a small part in a crystalline phase. The melts with additions of manganese and Silicon show the best properties with respect tc vitrification, incorporation of the sulphur and hydrolytic resistance of the product. By means of leaching tests using the Soxhlet equipment, products of great hydrolitic resistance are proved falling under the hydrolytic class III at least.
- ItemMechanism of defect creation on sheet glass by particle impact and its influence on stray light(Offenbach : Verlag der Deutschen Glastechnischen Gesellschaft, 1998) Holtmann, Klaus Heinrich; Frischat, Günther Heinz; Ruppert, KarlStray light on the windshields of automotive vehicles, caused by the impact of small particles, imposes severe safety hazards during night driving. Due to reduced contrast by stray light, nonilluminated objects are perceived much later than through pristine windshields. The objective of this paper therefore is to show the dependence of stray light on impact velocity, impact angle, particle shape and the mechanical properties of the impacting particle and the target material. Single and multiple impacts of SiC (≈1 mg/particle) and quartz sand (≈ 0.7 mg/particle) on ordinary and strengthened float glass under angles of 30°, 45° and 90° and velocities between 50 and 200 km/h were investigated. Profilometer and various methods of stray light measurement, such as total integrated scattering, were used. Based on the correlation between surface roughness and stray light, it can be proved that the amount of stray light is proportional to the ratio of impact volume to the area of the undamaged surface. Caiculating the contact pressure during impact on the target for Sharp and rounded particles in dependence on velocity and impact angle and applying the fracture mechanical criteria for the formation of lateral cracks allows the modeling of the impact volume for the various combinations of particle and target contacts and thus an estimation of the stray light to be expected. Comparison of the model calculation with experimental data exhibits good agreement. Both sets of data show an increase in the amount of damage with increasing velocity and steeper impact angle. The damage caused by SiC is always more severe than the damage by quartz sand. Increasing the fracture toughness of the target material reduces the extent of the damage by about 10%. Α more pronounced reducdon of stray light and mechanical deterioration of up to 60% in comparison to normal float glass can be achieved by a newly developed composite material, consisting of a 0.2 mm thick glass, a 0.36 mm thick layer of PVB, and a float glass Substrate of 3 mm thickness.