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    Axial GaAs/Ga(As, Bi) nanowire heterostructures
    (Bristol : IOP Publ., 2019) Oliva, Miriam; Gao, Guanhui; Luna, Esperanza; Geelhaar, Lutz; Lewis, Ryan B
    Bi-containing III-V semiconductors constitute an exciting class of metastable compounds with wide-ranging potential optoelectronic and electronic applications. However, the growth of III-V-Bi alloys requires group-III-rich growth conditions, which pose severe challenges for planar growth. In this work, we exploit the naturally-Ga-rich environment present inside the metallic droplet of a self-catalyzed GaAs nanowire (NW) to synthesize metastable GaAs/GaAs1-xBi x axial NW heterostructures with high Bi contents. The axial GaAs1-xBi x segments are realized with molecular beam epitaxy by first enriching only the vapor-liquid-solid (VLS) Ga droplets with Bi, followed by exposing the resulting Ga-Bi droplets to As2 at temperatures ranging from 270 °C to 380 °C to precipitate GaAs1-xBi x only under the NW droplets. Microstructural and elemental characterization reveals the presence of single crystal zincblende GaAs1-xBi x axial NW segments with Bi contents up to (10 ± 2)%. This work illustrates how the unique local growth environment present during the VLS NW growth can be exploited to synthesize heterostructures with metastable compounds. © 2019 IOP Publishing Ltd.
  • Item
    Self-cross-linked arrays enabled flexible mechanical sensors for monitoring the body tremor
    (London : Springer Nature, 2020) Wang, Xuewen; Fu, Wei; Gao, Guanhui; Mehay, Mandeep Singh; Wang, Hong; Zhao, Wu; Loh, Kian Ping; Zhang, Ting; Huang, Wei; Liu, Zheng
    Thin-film electronics played an important role in flexible healthcare sensor applications. The common status of their constituent blocks are solid film and network structures. However, the solid film could only sustain bend in a narrow range due to cracks, and the network structure decreased the sensitivity of flexion sensors due to the strong interactions between nanowires. New materials and technologies are urgently required for flexible sensing electronics, to produce the reliable data for assessment of the human body. Here, we report on a novel three-dimensional (3D) carbon nanorods array (CNA) that is characterized as vertically aligned nanorods and self-cross-linked junctions. We also demonstrate the CNA-based flexible healthcare sensors in monitoring the Parkinsonian tremors. Comparing with two-dimensional (2D) carbon nanotube networks and solid thin films, such self-cross-linked geometries are highly resistant to crack and fragmentation under strain. In the meantime, it shows high sensitivity and good stability (~10,000 times) to detect the flexions. These CNA-based flexible devices are capable of recording low-frequency vibrations (<6 Hz) and make it excellent to monitor the rest tremor of the human body, which is an initial symptom of Parkinson’s disease. The 3D self-cross-linked CNA film shows great potential in the fabrication of cost-effective and durable flexible sensors for early diagnosis of disease by monitoring the health-related rest tremors. © 2020, The Author(s).