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    Evaluating Soil-Borne Causes of Biomass Variability in Grassland by Remote and Proximal Sensing
    (Basel : MDPI AG, 2019) Vogel, Sebastian; Gebbers, Robin; Oertel, Marcel; Kramer, Eckart
    On a grassland field with sandy soils in Northeast Germany (Brandenburg), vegetation indices from multi-spectral UAV-based remote sensing were used to predict grassland biomass productivity. These data were combined with soil pH value and apparent electrical conductivity (ECa) from on-the-go proximal sensing serving as indicators for soil-borne causes of grassland biomass variation. The field internal magnitude of spatial variability and hidden correlations between the variables of investigation were analyzed by means of geostatistics and boundary-line analysis to elucidate the influence of soil pH and ECa on the spatial distribution of biomass. Biomass and pH showed high spatial variability, which necessitates high resolution data acquisition of soil and plant properties. Moreover, boundary-line analysis showed grassland biomass maxima at pH values between 5.3 and 7.2 and ECa values between 3.5 and 17.5 mS m−1. After calibrating ECa to soil moisture, the ECa optimum was translated to a range of optimum soil moisture from 7% to 13%. This matches well with to the plant-available water content of the predominantly sandy soil as derived from its water retention curve. These results can be used in site-specific management decisions to improve grassland biomass productivity in low-yield regions of the field due to soil acidity or texture-related water scarcity.
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    Determination of Nutrients in Liquid Manures and Biogas Digestates by Portable Energy-Dispersive X-ray Fluorescence Spectrometry
    (Basel : MDPI AG, 2021) Horf, Michael; Gebbers, Robin; Vogel, Sebastian; Ostermann, Markus; Piepel, Max-Frederik; Olfs, Hans-Werner
    Knowing the exact nutrient composition of organic fertilizers is a prerequisite for their appropriate application to improve yield and to avoid environmental pollution by over-fertilization. Traditional standard chemical analysis is cost and time-consuming and thus it is unsuitable for a rapid analysis before manure application. As a possible alternative, a handheld X-ray fluorescence (XRF) spectrometer was tested to enable a fast, simultaneous, and on-site analysis of several elements. A set of 62 liquid pig and cattle manures as well as biogas digestates were collected, intensively homogenized and analysed for the macro plant nutrients phosphorus, potassium, magnesium, calcium, and sulphur as well as the micro nutrients manganese, iron, copper, and zinc using the standard lab procedure. The effect of four different sample preparation steps (original, dried, filtered, and dried filter residues) on XRF measurement accuracy was examined. Therefore, XRF results were correlated with values of the reference analysis. The best R2s for each element ranged from 0.64 to 0.92. Comparing the four preparation steps, XRF results for dried samples showed good correlations (0.64 and 0.86) for all elements. XRF measurements using dried filter residues showed also good correlations with R2s between 0.65 and 0.91 except for P, Mg, and Ca. In contrast, correlation analysis for liquid samples (original and filtered) resulted in lower R2s from 0.02 to 0.68, except for K (0.83 and 0.87, respectively). Based on these results, it can be concluded that handheld XRF is a promising measuring system for element analysis in manures and digestates.