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    Electrocatalytic Reduction of CO2 to Acetic Acid by a Molecular Manganese Corrole Complex
    (Weinheim : Wiley-VCH, 2020) De, Ratnadip; Gonglach, Sabrina; Paul, Shounik; Haas, Michael; Sreejith, S.S.; Gerschel, Philipp; Apfel, Ulf-Peter; Vuong, Thanh Huyen; Rabeah, Jabor; Roy, Soumyajit; Schöfberger, Wolfgang
    The controlled electrochemical reduction of carbon dioxide to value added chemicals is an important strategy in terms of renewable energy technologies. Therefore, the development of efficient and stable catalysts in an aqueous environment is of great importance. In this context, we focused on synthesizing and studying a molecular MnIII-corrole complex, which is modified on the three meso-positions with polyethylene glycol moieties for direct and selective production of acetic acid from CO2. Electrochemical reduction of MnIII leads to an electroactive MnII species, which binds CO2 and stabilizes the reduced intermediates. This catalyst allows to electrochemically reduce CO2 to acetic acid in a moderate acidic aqueous medium (pH 6) with a selectivity of 63 % and a turn over frequency (TOF) of 8.25 h−1, when immobilized on a carbon paper (CP) electrode. In terms of high selectivity towards acetate, we propose the formation and reduction of an oxalate type intermediate, stabilized at the MnIII-corrole center. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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    New perspectives on interdisciplinary earth science at the Dead Sea: The DESERVE project
    (Amsterdam [u.a.] : Elsevier Science, 2016) Kottmeier, Christoph; Agnon, Amotz; Al-Halbouni, Djamil; Alpert, Pinhas; Corsmeier, Ulrich; Dahm, Torsten; Eshel, Adam; Geyer, Stefan; Haas, Michael; Holohan, Eoghan; Kalthoff, Norbert; Kishcha, Pavel; Krawczyk, Charlotte; Lati, Joseph; Laronne, Jonathan B.; Lott, Friederike; Mallast, Ulf; Merz, Ralf; Metzger, Jutta; Mohsen, Ayman; Morin, Efrat; Nied, Manuela; Rödiger, Tino; Salameh, Elias; Sawarieh, Ali; Shannak, Benbella; Siebert, Christian; Weber, Michael
    The Dead Sea region has faced substantial environmental challenges in recent decades, including water resource scarcity, ~ 1 m annual decreases in the water level, sinkhole development, ascending-brine freshwater pollution, and seismic disturbance risks. Natural processes are significantly affected by human interference as well as by climate change and tectonic developments over the long term. To get a deep understanding of processes and their interactions, innovative scientific approaches that integrate disciplinary research and education are required. The research project DESERVE (Helmholtz Virtual Institute Dead Sea Research Venue) addresses these challenges in an interdisciplinary approach that includes geophysics, hydrology, and meteorology. The project is implemented by a consortium of scientific institutions in neighboring countries of the Dead Sea (Israel, Jordan, Palestine Territories) and participating German Helmholtz Centres (KIT, GFZ, UFZ). A new monitoring network of meteorological, hydrological, and seismic/geodynamic stations has been established, and extensive field research and numerical simulations have been undertaken. For the first time, innovative measurement and modeling techniques have been applied to the extreme conditions of the Dead Sea and its surroundings. The preliminary results show the potential of these methods. First time ever performed eddy covariance measurements give insight into the governing factors of Dead Sea evaporation. High-resolution bathymetric investigations reveal a strong correlation between submarine springs and neo-tectonic patterns. Based on detailed studies of stratigraphy and borehole information, the extension of the subsurface drainage basin of the Dead Sea is now reliably estimated. Originality has been achieved in monitoring flash floods in an arid basin at its outlet and simultaneously in tributaries, supplemented by spatio-temporal rainfall data. Low-altitude, high resolution photogrammetry, allied to satellite image analysis and to geophysical surveys (e.g. shear-wave reflections) has enabled a more detailed characterization of sinkhole morphology and temporal development and the possible subsurface controls thereon. All the above listed efforts and scientific results take place with the interdisciplinary education of young scientists. They are invited to attend joint thematic workshops and winter schools as well as to participate in field experiments.