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Electrodeposition of Fe70Pd30 nanowires from a complexed ammonium-sulfosalicylic electrolyte with high stability

2010, Haehnel, V., Fähler, S., Schultz, L., Schlörb, H.

A highly stable plating bath for the electrodeposition of Fe-Pd nanowires into nanoporous alumina templates has been developed. Complexing of both metal ions and exchanging Fe2+ by Fe3+ avoid chemical reduction of Pd ions and, therefore, undesirable deposition. By using a pulse potential mode and appropriate adjustment of deposition potentials homogeneously filled templates without surface deposits and nanowires close to the desired composition of Fe70Pd30 have been achieved. These alloy nanowires represent a key step towards nanoactuators based on magnetic shape memory alloys. © 2010 Elsevier B.V. All rights reserved.

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Combining magnetic forces for contactless manipulation of fluids in microelectrode-microfluidic systems

2019, Haehnel, V., Khan, F.Z., Mutschke, G., Cierpka, C., Uhlemann, M., Fritsch, I.

A novel method to drive and manipulate fluid in a contactless way in a microelectrode-microfluidic system is demonstrated by combining the Lorentz and magnetic field gradient forces. The method is based on the redox-reaction [Fe(CN) 6 ] 3− /[Fe(CN) 6 ] 4− performed in a magnetic field oriented perpendicular to the ionic current that crosses the gap between two arrays of oppositely polarized microelectrodes, generating a magnetohydrodynamic flow. Additionally, a movable magnetized CoFe micro-strip is placed at different positions beneath the gap. In this region, the magnetic flux density is changed locally and a strong magnetic field gradient is formed. The redox-reaction changes the magnetic susceptibility of the electrolyte near the electrodes, and the resulting magnetic field gradient exerts a force on the fluid, which leads to a deflection of the Lorentz force-driven main flow. Particle Image Velocity measurements and numerical simulations demonstrate that by combining the two magnetic forces, the flow is not only redirected, but also a local change of concentration of paramagnetic species is realized.