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    Biochar as a tool to reduce the agricultural greenhouse-gas burden–knowns, unknowns and future research needs
    (Vilnius : Technika, 2017) Kammann, Claudia; Ippolito, Jim; Hagemann, Nikolas; Borchard, Nils; Cayuela, Maria Luz; Estavillo, José M.; Fuertes-Mendizabal, Teresa; Jeffery, Simon; Kern, Jürgen; Novak, Jeff; Rasse, Daniel; Saarnio, Sanna; Schmidt, Hans-Peter; Spokas, Kurt; Wrage-Mönnig, Nicole
    Agriculture and land use change has significantly increased atmospheric emissions of the non-CO2 green-house gases (GHG) nitrous oxide (N2O) and methane (CH4). Since human nutritional and bioenergy needs continue to increase, at a shrinking global land area for production, novel land management strategies are required that reduce the GHG footprint per unit of yield. Here we review the potential of biochar to reduce N2O and CH4 emissions from agricultural practices including potential mechanisms behind observed effects. Furthermore, we investigate alternative uses of biochar in agricultural land management that may significantly reduce the GHG-emissions-per-unit-of-product footprint, such as (i) pyrolysis of manures as hygienic alternative to direct soil application, (ii) using biochar as fertilizer carrier matrix for underfoot fertilization, biochar use (iii) as composting additive or (iv) as feed additive in animal husbandry or for manure treatment. We conclude that the largest future research needs lay in conducting life-cycle GHG assessments when using biochar as an on-farm management tool for nutrient-rich biomass waste streams. © 2017 The Author(s) Published by VGTU Press and Informa UK Limited, [trading as Taylor & Francis Group].
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    Pyrogenic carbon capture and storage
    (Oxford : Wiley-Blackwell, 2019) Schmidt, Hans-Peter; Anca-Couce, Andrés; Hagemann, Nikolas; Werner, Constanze; Gerten, Dieter; Lucht, Wolfgang; Kammann, Claudia
    The growth of biomass is considered the most efficient method currently available to extract carbon dioxide from the atmosphere. However, biomass carbon is easily degraded by microorganisms releasing it in the form of greenhouse gases back to the atmosphere. If biomass is pyrolyzed, the organic carbon is converted into solid (biochar), liquid (bio-oil), and gaseous (permanent pyrogas) carbonaceous products. During the last decade, biochar has been discussed as a promising option to improve soil fertility and sequester carbon, although the carbon efficiency of the thermal conversion of biomass into biochar is in the range of 30%–50% only. So far, the liquid and gaseous pyrolysis products were mainly considered for combustion, though they can equally be processed into recalcitrant forms suitable for carbon sequestration. In this review, we show that pyrolytic carbon capture and storage (PyCCS) can aspire for carbon sequestration efficiencies of >70%, which is shown to be an important threshold to allow PyCCS to become a relevant negative emission technology. Prolonged residence times of pyrogenic carbon can be generated (a) within the terrestrial biosphere including the agricultural use of biochar; (b) within advanced bio-based materials as long as they are not oxidized (biochar, bio-oil); and (c) within suitable geological deposits (bio-oil and CO 2 from permanent pyrogas oxidation). While pathway (c) would need major carbon taxes or similar governmental incentives to become a realistic option, pathways (a) and (b) create added economic value and could at least partly be implemented without other financial incentives. Pyrolysis technology is already well established, biochar sequestration and bio-oil sequestration in soils, respectively biomaterials, do not present ecological hazards, and global scale-up appears feasible within a time frame of 10–30 years. Thus, PyCCS could evolve into a decisive tool for global carbon governance, serving climate change mitigation and the sustainable development goals simultaneously. © 2018 John Wiley & Sons Ltd