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    Daytime sky polarization calibration limitations
    (Bellingham : SPIE, 2017) Harrington, David M.; Kuhn, Jeffrey R.; Ariste, Arturo López
    The daytime sky has recently been demonstrated as a useful calibration tool for deriving polarization cross-talk properties of large astronomical telescopes. The Daniel K. Inouye Solar Telescope and other large telescopes under construction can benefit from precise polarimetric calibration of large mirrors. Several atmospheric phenomena and instrumental errors potentially limit the technique’s accuracy. At the 3.67-m AEOS telescope on Haleakala, we performed a large observing campaign with the HiVIS spectropolarimeter to identify limitations and develop algorithms for extracting consistent calibrations. Effective sampling of the telescope optical configurations and filtering of data for several derived parameters provide robustness to the derived Mueller matrix calibrations. Second-order scattering models of the sky show that this method is relatively insensitive to multiple-scattering in the sky, provided calibration observations are done in regions of high polarization degree. The technique is also insensitive to assumptions about telescope-induced polarization, provided the mirror coatings are highly reflective. Zemax-derived polarization models show agreement between the functional dependence of polarization predictions and the corresponding on-sky calibrations.
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    Remote sensing of life: Polarimetric signatures of photosynthetic pigments as sensitive biomarkers
    (Cambridge : Cambridge University Press, 2015) Berdyugina, Svetlana V.; Kuhn, Jeff R.; Harrington, David M.; Šantl-Temkiv, Tina; Messersmith, E. John
    We develop a polarimetry-based remote-sensing method for detecting and identifying life forms in distant worlds and distinguishing them from non-biological species. To achieve this we have designed and built a bio-polarimetric laboratory experiment BioPol for measuring optical polarized spectra of various biological and non-biological samples. Here we focus on biological pigments, which are common in plants and bacteria that employ them either for photosynthesis or for protection against reactive oxygen species. Photosynthesis, which provides organisms with the ability to use light as a source of energy, emerged early in the evolution of life on Earth. The ability to harvest such a significant energy resource could likely also develop on habited exoplanets. Thus, we investigate the detectability of biomolecules that can capture photons of particular wavelengths and contribute to storing their energy in chemical bonds. We have carried out laboratory spectropolarimetric measurements of a representative sample of plants containing various amounts of pigments such as chlorophyll, carotenoids and others. We have also measured a variety of non-biological samples (sands, rocks). Using our lab measurements, we have modelled intensity and polarized spectra of Earth-like planets having different surface coverage by photosynthetic organisms, deserted land and ocean, as well as clouds. Our results demonstrate that linearly polarized spectra provide very sensitive and rather unambiguous detection of photosynthetic pigments of various kinds. Our work paves the path towards analogous measurements of microorganisms and remote sensing of microbial ecology on the Earth and of extraterrestrial life on other planets and moons.