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    Synthesis of Bulk Zr48Cu36Al8Ag8 Metallic Glass by Hot Pressing of Amorphous Powders
    (Basel : MDPI, 2021) He, Tianbing; Ciftci, Nevaf; Uhlenwinkel, Volker; Scudino, Sergio
    The critical cooling rate necessary for glass formation via melt solidification poses inherent constraints on sample size using conventional casting techniques. This drawback can be overcome by pressure-assisted sintering of metallic glass powders at temperatures above the glass transition, where the material shows viscous-flow behavior. Partial crystallization during sintering usually exacerbates the inherent brittleness of metallic glasses and thus needs to be avoided. In order to achieve high density of the bulk specimens while avoiding (or minimizing) crystallization, the optimal combination between low viscosity and long incubation time for crystallization must be identified. Here, by carefully selecting the time–temperature window for powder consolidation, we synthesized highly dense Zr48Cu36Ag8Al8 bulk metallic glass (BMG) with mechanical properties comparable with its cast counterpart. The larger ZrCu-based BMG specimens fabricated in this work could then be post-processed by flash-annealing, offering the possibility to fabricate monolithic metallic glasses and glass–matrix composites with enhanced room-temperature plastic deformation.
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    Microstructure, mechanical properties and machinability of particulate reinforced Al matrix composites: a comparative study between SiC particles and high-entropy alloy particles
    (Amsterdam : Elsevier, 2020) Lu, Tiwen; He, Tianbing; Li, Zixuan; Chen, Hongyu; Han, Xiaoliang; Fu, Zhiqiang; Chen, Weiping
    In this study, 2024Al matrix composites reinforced by SiC particles (SiC-2024Al) and nanocrystalline high-entropy alloy particles (HEA-2024Al) fabricated by powder metallurgy were systematically compared for the first time. There is a significant difference in microstructure and mechanical properties as well as machinability between two kinds of composites. In term of microstructure, when the volume fraction of reinforcements was 10%, both SiC-2024Al and HEA-2024Al composites showed a homogeneous particle distribution in the matrix. With the increase of reinforcement content, HEA-2024Al composites presented denser microstructure than that of SiC-2024Al composites. The composites with 10, 20 and 30 vol.% HEA reinforcements all showed better plasticity than that of the SiC-2024Al composites with same volume fraction of reinforcements, which was related with better particle distribution and interface bonding. However, the strength showed the opposite tendency in the two kinds of composites. Selecting 10SiC-2024Al and 10HEA-2024Al composites as examples to explore the difference in the yield strength of two kinds of composites, it is ascribed to the dislocation punched zones around interface between the Al matrix and reinforcements, which was analyzed in detail by a combination of calculation, nanoindentation tests and finite element analysis. Additionally, HEA-2024Al composites showed better machinability than those of SiC-2024Al composites. This work provides insight into the application of particulate reinforced Al matrix composites.