2020, Reitsma, G., Hummert, J., Dura, J., Loriot, V., Vrakking, M.J.J., Lépine, F., Kornilov, O.

The efficiency of energy transfer in ultrafast electronic relaxation of molecules depends strongly on the complex interplay between electronic and nuclear motion. In this study we use wavelength-selected XUV pulses to induce relaxation dynamics of highly excited cationic states of naphthalene. Surprisingly, the observed relaxation lifetimes increase with the cationic excitation energy. We propose that this is a manifestation of a quantum mechanical population trapping that leads to delayed relaxation of molecules in the regions with a high density of excited states. © 2019 Published under licence by IOP Publishing Ltd.

2017, Arbó, D.G., López, S. D., Kubin, M., Hummert, J., Vrakking, M.J.J., Kornilov, O.

Synopsis We present a theoretical and experimental study of the subcycle interference in laser assisted XUV ionization of Ar atoms. Averaging over the focal volume happens to blur the intracycle interference, which thus cannot be measured directly. We show that even at these conditions, the intracycle interference can be obtained through the subtraction of two different angle and energy-resolved distributions at slightly different laser intensities.