Search Results
Hydrothermal Carbonization: Modeling, Final Properties Design and Applications: A Review
2018-1-16, Román, Silvia, Libra, Judy, Berge, Nicole, Sabio, Eduardo, Ro, Kyoung, Li, Liang, Ledesma, Beatriz, Álvarez, Andrés, Bae, Sunyoung
Active research on biomass hydrothermal carbonization (HTC) continues to demonstrate its advantages over other thermochemical processes, in particular the interesting benefits that are associated with carbonaceous solid products, called hydrochar (HC). The areas of applications of HC range from biofuel to doped porous material for adsorption, energy storage, and catalysis. At the same time, intensive research has been aimed at better elucidating the process mechanisms and kinetics, and how the experimental variables (temperature, time, biomass load, feedstock composition, as well as their interactions) affect the distribution between phases and their composition. This review provides an analysis of the state of the art on HTC, mainly with regard to the effect of variables on the process, the associated kinetics, and the characteristics of the solid phase (HC), as well as some of the more studied applications so far. The focus is on research made over the last five years on these topics. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.
Atomic Sn–enabled high-utilization, large-capacity, and long-life Na anode
2022, Xu, Fei, Qu, Changzhen, Lu, Qiongqiong, Meng, Jiashen, Zhang, Xiuhai, Xu, Xiaosa, Qiu, Yuqian, Ding, Baichuan, Yang, Jiaying, Cao, Fengren, Yang, Penghui, Jiang, Guangshen, Kaskel, Stefan, Ma, Jingyuan, Li, Liang, Zhang, Xingcai, Wang, Hongqiang
Constructing robust nucleation sites with an ultrafine size in a confined environment is essential toward simultaneously achieving superior utilization, high capacity, and long-term durability in Na metal-based energy storage, yet remains largely unexplored. Here, we report a previously unexplored design of spatially confined atomic Sn in hollow carbon spheres for homogeneous nucleation and dendrite-free growth. The designed architecture maximizes Sn utilization, prevents agglomeration, mitigates volume variation, and allows complete alloying-dealloying with high-affinity Sn as persistent nucleation sites, contrary to conventional spatially exposed large-size ones without dealloying. Thus, conformal deposition is achieved, rendering an exceptional capacity of 16 mAh cm−2 in half-cells and long cycling over 7000 hours in symmetric cells. Moreover, the well-known paradox is surmounted, delivering record-high Na utilization (e.g., 85%) and large capacity (e.g., 8 mAh cm−2) while maintaining extraordinary durability over 5000 hours, representing an important breakthrough for stabilizing Na anode.