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- ItemSingle Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy-Oxide Clusterfullerene Dy2O@C82(Chichester : John Wiley and Sons Ltd, 2019) Yang, W.; Velkos, G.; Liu, F.; Sudarkova, S.M.; Wang, Y.; Zhuang, J.; Zhang, H.; Li, X.; Zhang, X.; Büchner, B.; Avdoshenko, S.M.; Popov, A.A.; Chen, N.A new class of single-molecule magnets (SMMs) based on Dy-oxide clusterfullerenes is synthesized. Three isomers of Dy2O@C82 with Cs(6), C3v(8), and C2v(9) cage symmetries are characterized by single-crystal X-ray diffraction, which shows that the endohedral Dy−(µ2-O)−Dy cluster has bent shape with very short Dy−O bonds. Dy2O@C82 isomers show SMM behavior with broad magnetic hysteresis, but the temperature and magnetization relaxation depend strongly on the fullerene cage. The short Dy−O distances and the large negative charge of the oxide ion in Dy2O@C82 result in the very strong magnetic anisotropy of Dy ions. Their magnetic moments are aligned along the Dy−O bonds and are antiferromagnetically (AFM) coupled. At low temperatures, relaxation of magnetization in Dy2O@C82 proceeds via the ferromagnetically (FM)-coupled excited state, giving Arrhenius behavior with the effective barriers equal to the AFM-FM energy difference. The AFM-FM energy differences of 5.4–12.9 cm−1 in Dy2O@C82 are considerably larger than in SMMs with {Dy2O2} bridges, and the Dy∙∙∙Dy exchange coupling in Dy2O@C82 is the strongest among all dinuclear Dy SMMs with diamagnetic bridges. Dy-oxide clusterfullerenes provide a playground for the further tuning of molecular magnetism via variation of the size and shape of the fullerene cage.
- ItemAssessing the influence of the Merzbacher Lake outburst floods on discharge using the hydrological model SWIM in the Aksu headwaters, Kyrgyzstan/NW China(Chichester : John Wiley and Sons Ltd, 2013) Wortmann, M.; Krysanova, V.; Kundzewicz, Z.W.; Su, B.; Li, X.Glacial lake outburst floods (GLOF) often have a significant impact on downstream users. Including their effects in hydrological models, identifying past occurrences and assessing their potential impacts are challenges for hydrologists working in mountainous catchments. The regularly outbursting Merzbacher Lake is located in the headwaters of the Aksu River, the most important source of water discharge to the Tarim River, northwest China. Modelling its water resources and the evaluation of potential climate change impacts on river discharge are indispensable for projecting future water availability for the intensively cultivated river oases downstream of the Merzbacher Lake and along the Tarim River. The semi-distributed hydrological model SWIM was calibrated to the outlet station Xiehela on the Kumarik River, by discharge the largest tributary to the Aksu River. The glacial lake outburst floods add to the difficulties of modelling this high-mountain, heavily glaciated catchment with poor data coverage and quality. The aims of the study are to investigate the glacier lake outburst floods using a modelling tool. Results include a two-step model calibration of the Kumarik catchment, an approach for the identification of the outburst floods using the measured gauge data and the modelling results and estimations of the outburst flood volumes. Results show that a catchment model can inform GLOF investigations by providing 'normal' (i.e. without the outburst floods) catchment discharge. The comparison of the simulated and observed discharge proves the occurrence of GLOFs and highlights the influences of the GLOFs on the downstream water balance.