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Author: Lu, Xueyi × Type: Article ×

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Now showing 1 - 4 of 4
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    High-performance Li-O2 batteries with trilayered Pd/MnOx/Pd nanomembranes
    (Hoboken, NJ : Wiley, 2015) Lu, Xueyi; Deng, Junwen; Si, Wenping; Sun, Xiaolei; Liu, Xianghong; Liu, Bo; Liu, Lifeng; Oswald, Steffen; Baunack, Stefan; Grafe, Hans Joachim; Yan, Chenglin; Schmidt, Oliver G.
    Trilayered Pd/MnOx/Pd nanomembranes are fabricated as the cathode catalysts for Li‐O2 batteries. The combination of Pd and MnOx facilitates the transport of electrons, lithium ions, and oxygen‐containing intermediates, thus effectively decomposing the discharge product Li2O2 and significantly lowering the charge overpotential and enhancing the power efficiency. This is promising for future environmentally friendly applications.
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    A compact tube-in-tube microsized lithium-ion battery as an independent microelectric power supply unit
    ([New York, NY] : Elsevier, 2021) Weng, Qunhong; Wang, Sitao; Liu, Lixiang; Lu, Xueyi; Zhu, Minshen; Li, Yang; Gabler, Felix; Schmidt, Oliver G.
    Independent and well-packaged miniaturized energy storage devices (MESDs) are indispensable as power sources or backup units for integrated circuits and many dispersive electronics applications. Challenges associated with MESD development relate to their low packaged areal energy density and poor battery performance. Here, we propose a compact tube-in-tube battery configuration to overcome the areal energy density and packaging problems in microbatteries. Compact microtubular microelectrodes rolled up from patterned nanomembranes are sealed in an inert glass capillary with a thin tube wall. The resultant tube-in-tube microsized lithium-ion batteries (micro-LIBs), based on various active materials, exhibit very high and scalable packaged areal energy densities up to 605 microampere hours per square centimeter (μAh cm−2) or 313 μWh cm−2 with footprints as small as 0.39–0.79 mm2. This approach is a practical alternative for microbattery microelectrode, packaging, and configuration innovations.
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    High-defect hydrophilic carbon cuboids anchored with Co/CoO nanoparticles as highly efficient and ultra-stable lithium-ion battery anodes
    (Cambridge : Royal Society of Chemistry, 2016) Sun, Xiaolei; Hao, Guang-Ping; Lu, Xueyi; Xi, Lixia; Liu, Bo; Si, Wenping; Ma, Chuansheng; Liu, Qiming; Zhang, Qiang; Kaskel, Stefan; Schmidt, Oliver G.
    We propose an effective strategy to engineer a unique kind of porous carbon cuboid with tightly anchored cobalt/cobalt oxide nanoparticles (PCC–CoOx) that exhibit outstanding electrochemical performance for many key aspects of lithium-ion battery electrodes. The host carbon cuboid features an ultra-polar surface reflected by its high hydrophilicity and rich surface defects due to high heteroatom doping (N-/O-doping both higher than 10 atom%) as well as hierarchical pore systems. We loaded the porous carbon cuboid with cobalt/cobalt oxide nanoparticles through an impregnation process followed by calcination treatment. The resulting PCC–CoOx anode exhibits superior rate capability (195 mA h g−1 at 20 A g−1) and excellent cycling stability (580 mA h g−1 after 2000 cycles at 1 A g−1 with only 0.0067% capacity loss per cycle). Impressively, even after an ultra-long cycle life exceeding 10 000 cycles at 5 A g−1, the battery can recover to 1050 mA h g−1 at 0.1 A g−1, perhaps the best performance demonstrated so far for lithium storage in cobalt oxide-based electrodes. This study provides a new perspective to engineer long-life, high-power metal oxide-based electrodes for lithium-ion batteries through controlling the surface chemistry of carbon host materials.
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    Nitrogen and boron doped carbon layer coated multiwall carbon nanotubes as high performance anode materials for lithium ion batteries
    ([London] : Nature Publishing Group, 2021) Liu, Bo; Sun, Xiaolei; Liao, Zhongquan; Lu, Xueyi; Zhang, Lin; Hao, Guang-Ping
    Lithium ion batteries (LIBs) are at present widely used as energy storage and conversion device in our daily life. However, due to the limited power density, the application of LIBs is still restricted in some areas such as commercial vehicles or heavy-duty trucks. An effective strategy to solve this problem is to increase energy density through the development of battery materials. At the same time, a stable long cycling battery is a great demand of environmental protection and industry. Herein we present our new materials, nitrogen and boron doped carbon layer coated multiwall carbon nanotubes (NBC@MWCNTs), which can be used as anodes for LIBs. The electrochemical results demonstrate that the designed NBC@MWCNTs electrode possesses high stable capacity over an ultra-long cycling lifespan (5000 cycles) and superior rate capability even at very high current density (67.5 A g−1). Such impressive lithium storage properties could be ascribed to the synergistic coupling effect of the distinctive structural features, the reduced diffusion length of lithium ions, more active sites generated by doped atoms for lithium storage, as well as the enhancement of the electrode structural integrity. Taken together, these results indicate that the N, B-doped carbon@MWCNTs materials may have great potential for applications in next-generation high performance rechargeable batteries.