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(Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide

2011, Peulecke, N., Peitz, S., Müller, B.H., Spannenberg, A., Rosenthal, U.

The title compound, C 16H 21NP +· I -, was obtained by the reaction of PH 2PN( iPr)P(Ph)N( iPr)H with MeI involving cleavage of one of the P - N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor-acceptor N - H⋯I inter-action is observed.

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N,P,P-Triisopropyl-phosphinic amide

2011, Peulecke, N., Aluri, B.R., Müller, B.H., Spannenberg, A., Rosenthal, U.

The title compound, C9H22NOP, was obtained by slow diffusion of oxygen into a toluene solution of iPr2PNHiPr. In the crystal, an inter-molecular N - H⋯O hydrogen bond occurs.