Search Results
Non-remote reference noise cancellation - using reference data in the presence of surface-NMR signals
Surface-NMR measurements commonly suffer from low signal-to-noise ratios. In recent years, with the introduction of multi-channel surface-NMR instruments, the technique of remote-reference noise cancellation (RNC) was developed and significantly improved the applicability of surface-NMR. The current formulation of RNC requires a reference loop to be placed a remote distance from the transmitter loop such that no NMR signal is recorded. Reference loops placed at non-remote distances have been envisaged to provide both improved noise cancellation performance and field efficiency; however, the concept has not been previously applied because the theoretical framework was missing. In this paper, the theoretical framework is presented. It is demonstrated that reference loops placed at non-remote distances provide superior noise cancellation performance. Considerations for placing the reference loop relative to the transmitter loop are provided, and the theoretical framework is evaluated based on a semi-synthetic example using real field noise and synthetic surface-NMR data. © 2020
A State-Of-The-Art Perspective on the Characterization of Subterranean Estuaries at the Regional Scale
Subterranean estuaries the, subsurface mixing zones of terrestrial groundwater and seawater, substantially influence solute fluxes to the oceans. Solutes brought by groundwater from land and solutes brought from the sea can undergo biogeochemical reactions. These are often mediated by microbes and controlled by reactions with coastal sediments, and determine the composition of fluids discharging from STEs (i.e., submarine groundwater discharge), which may have consequences showing in coastal ecosystems. While at the local scale (meters), processes have been intensively studied, the impact of subterranean estuary processes on solute fluxes to the coastal ocean remains poorly constrained at the regional scale (kilometers). In the present communication, we review the processes that occur in STEs, focusing mainly on fluid flow and biogeochemical transformations of nitrogen, phosphorus, carbon, sulfur and trace metals. We highlight the spatio-temporal dynamics and measurable manifestations of those processes. The objective of this contribution is to provide a perspective on how tracer studies, geophysical methods, remote sensing and hydrogeological modeling could exploit such manifestations to estimate the regional-scale impact of processes in STEs on solute fluxes to the coastal ocean.
Structurally coupled cooperative inversion of magnetic resonance with resistivity soundings
Hydrologic parameters, such as porosity, salinity, and hydraulic conductivity are keys for understanding the subsurface. Hydrogeophysical investigations can lead to ambiguous results, particularly in the presence of clay and saltwater. A combination of magnetic resonance sounding and vertical electrical sounding is known to provide insight into these properties. Structural coupling increases the model resolution and reduces the ambiguity for both methods. Inversion schemes using block models exist, but they have trouble resolving smooth or complex parameter distributions. We have developed a structurally coupled cooperative inversion (SCCI) that works with smooth parameter distributions and is able to introduce blocky features through the exchange of structural information. The coupling adapts the smoothness constraint locally in connection to the model roughness to allow for sharper model boundaries. We investigate the performance of the SCCI using blocky and smooth synthetic models that depend on two controlling coupling parameters. A well-known field case is used to verify the results with drilling core and well logs. Varying the coupling parameters results in equivalent models covering the bandwidth from smooth to blocky, while providing a similar data fit. The SCCI results are more consistent with the synthetic models. Structural coupling improves the resolution of the single methods and can be used to describe hydrogeophysical targets in more detail and less ambiguously.
Application of adiabatic pulses for magnetic Resonance Sounding – Pulse shapes and resolution
Magnetic Resonance Sounding (MRS) can image the spatial distribution of hydrologically relevant parameters in in the subsurface. However, the application of MRS is often limited by its low signal-to-noise ratio. The use of adiabatic excitation pulses show promising features to overcome this limitation. In this work, we study practical considerations when applying adiabatic pulses for MRS, i.e. calculation of the sensitivity kernel for varying pulse shapes and vertical resolution. The pulse shape is crucial for the performance of adiabatic pulses. We investigate the shapes of adiabatic pulses recorded during a MRS and observe small systematic deviations from the theoretical predicted pulse shape and variations between different pulse strengths. We show that the overall impact on the obtained sounding curve and inversion result was small. This enables to limit the time consuming modelling of the spin dynamic to one representative pulse shape, which significantly speeds up the calculation of the sensitivity kernel, necessary for the interpretation of MRS. Additionally, we show that on-resonance excitation generally outperforms adiabatic excitation concerning vertical resolution and depth of investigation (both up to a factor of two). This is true for a wide range of noise conditions. For a very shallow depth interval compared to the loop size, however, adiabatic excitation features improved imaging capabilities. © 2020 The Authors
Utilizing pre-polarization to enhance SNMR signals - Effect of imperfect switch-off
Surface nuclear magnetic resonance (SNMR) is a well-established technique for the hydrogeological characterization of the subsurface up to depths of about 150 m. Recently, SNMR has been adapted to investigate also the shallow unsaturated zone with small surface loop setups. Due to the decreased volume, a pre-polarization (PP) field prior to the classical spin excitation is applied to enhance the measured response signal. Depending on the strength and orientation of the applied PP-field, the enhancement can often reach several orders of magnitude in the vicinity of the PP-loop. The theoretically achievable enhancement depends on the assumption of an adiabatic, that is perfect, switch-off of the corresponding PP-field. To study the effect of imperfect switch-off, we incorporate full spin dynamics simulations into the SNMR forward modelling. The affected subsurface volume strongly depends on the chosen PP switch-off ramp and the geometry of the loop setup. Due to the imperfect switch-off, the resulting SNMR sounding curves can have significantly decreased signal amplitudes. For comparison, the signal amplitudes of either a 1 ms exponential or linear switch-off ramp are reduced by 17 and 65 per cent, respectively. Disregarding this effect would therefore yield an underestimation of the corresponding subsurface water content of similar magnitude. © 2020 The Author(s) 2020. Published by Oxford University Press on behalf of The Royal Astronomical Society.
Schlussbericht zum Verbundvorhabens Entwicklung, Bau und Erprobung einer 1H-NMR-Bohrlochsonde zur Grundwassererkundung, -erschließung und -gewinnung, Teilprojekt 1: HYDRO-NMR-Bohrlochsonde: Geophysikalische Grundlagen
[no abstract available]
Evaluation of single-sided nuclear magnetic resonance technology for usage in geosciences
Because of its mobility and ability to investigate exposed surfaces, single-sided (SiS) nuclear magnetic resonance (NMR) technology enables new application fields in geosciences. To test and assess its corresponding potential, we compare longitudinal (T 1) and transverse (T 2) data measured by SiS NMR with those of conventional geoscientific laboratory NMR. We use reference sandstone samples covering a broad range of pore sizes. Our study demonstrates that the lower signal-to-noise ratio of SiS NMR data generally tends to slightly overestimated widths of relaxation time distributions and consequently pore size distributions. While SiS and conventional NMR produce very similar T 1 relaxation data, unbiased SiS NMR results for T 2 measurements can only be expected for fine material, i.e. clayey or silty sediments and soils with main relaxation times below 0.05s . This limit is given by the diffusion relaxation rate due to the gradient in the primary magnetic field associated with the SiS NMR. Above that limit, i.e. for coarse material, the relaxation data is strongly attenuated. If considering the diffusion relaxation time of 0.2 s in the numerical data inversion process, the information content >0.2s is blurred over a range larger than that of conventional NMR. However, our results show that principle range and magnitudes of the relaxation time distributions are reconstructed to some extent. Regarding these findings, SiS NMR can be helpful to solve geoscientific issues, e.g. to assess the hydro-mechanical properties of the walls of underground facilities or to provide local soil moisture data sets for calibrating indirect remote techniques on the regional scale. The greatest opportunity provided by the SiS NMR technology is the acquisition of profile relaxation data for rocks with significant bedding structures at the μm scale. With this unique feature, SiS NMR can support the understanding and modeling of hydraulic and diffusional anisotropy behavior of sedimentary rocks.
Hydraulic characterisation of iron-oxide-coated sand and gravel based on nuclear magnetic resonance relaxation mode analyses
The capability of nuclear magnetic resonance (NMR) relaxometry to characterise hydraulic properties of iron-oxide-coated sand and gravel was evaluated in a laboratory study. Past studies have shown that the presence of paramagnetic iron oxides and large pores in coarse sand and gravel disturbs the otherwise linear relationship between relaxation time and pore size. Consequently, the commonly applied empirical approaches fail when deriving hydraulic quantities from NMR parameters. Recent research demonstrates that higher relaxation modes must be taken into account to relate the size of a large pore to its NMR relaxation behaviour in the presence of significant paramagnetic impurities at its pore wall. We performed NMR relaxation experiments with water-saturated natural and reworked sands and gravels, coated with natural and synthetic ferric oxides (goethite, ferrihydrite), and show that the impact of the higher relaxation modes increases significantly with increasing iron content. Since the investigated materials exhibit narrow pore size distributions, and can thus be described by a virtual bundle of capillaries with identical apparent pore radius, recently presented inversion approaches allow for estimation of a unique solution yielding the apparent capillary radius from the NMR data. We found the NMR-based apparent radii to correspond well to the effective hydraulic radii estimated from the grain size distributions of the samples for the entire range of observed iron contents. Consequently, they can be used to estimate the hydraulic conductivity using the well-known Kozeny–Carman equation without any calibration that is otherwise necessary when predicting hydraulic conductivities from NMR data. Our future research will focus on the development of relaxation time models that consider pore size distributions. Furthermore, we plan to establish a measurement system based on borehole NMR for localising iron clogging and controlling its remediation in the gravel pack of groundwater wells.