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Spinodal dewetting of thin films with large interfacial slip : implications from the dispersion relation

2008, Rauscher, Markus, Blossey, Ralf, Münch, Andreas, Wagner, Barbara

We compare the dispersion relations for spinodally dewetting thin liquid films for increasing magnitude of interfacial slip length in the lubrication limit. While the shape of the dispersion relation, in particular the position of the maximum, are equal for no-slip up to moderate slip lengths, the position of the maximum shifts to much larger wavelengths for large slip lengths. Here, we discuss the implications of this fact for recently developed methods to assess the disjoining pressure in spinodally unstable thin films by measuring the shape of the roughness power spectrum. For PS films on OTS covered Si wafers (with slip length $bapprox 1,mu$m) we predict a 20% shift of the position of the maximum of the power spectrum which should be detectable in experiments.

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Linear stability analysis of ta sharp-interface model for dewetting thin films

2007, King, John R., Münch, Andreas, Wagner, Barbara

The topic of this study concerns the stability of the three-phase contact-line of a dewetting thin liquid film on a hydrophobised substrate driven by van der Waals forces. The role of slippage in the emerging instability at the three-phase contact-line is studied by deriving a sharp-interface model for the dewetting thin film via matched asymptotic expansions. This allows for a derivation of travelling waves and their linear stability via eigenmode analysis. In contrast to the dispersion relations typically encountered for the finger-instabilty, where the dependence of the growth rate on the wave number is quadratic, here it is linear. Using the separation of time scales of the slowly growing rim of the dewetting film and time scale on which the contact line destabilises, the sharp-interface results are compared to earlier results for the full lubrication model and good agreement for the most unstable modes is obtained.

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On the Landau-Levich problem for non-Newtonian liquids

2007, Afanasiev, Konstantin, Münch, Andreas, Wagner, Barbara

In this paper the drag-out problem for shear-thinning liquids at variable inclination angle is considered. For this free boundary problem dimension-reduced lubrication equations are derived for the most commonly used viscosity models, namely, the power-law, Ellis and Carreau model. For the resulting lubrication models a system of ordinary differential equation governing the steady state solutions is obtained. Phase plane analysis is used to characterize the type of possible steady state solutions and their dependence on the rheological parameters.

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Slip vs. viscoelasticity in dewetting thin films

2006, Blossey, Ralf, Münch, Andreas, Rauscher, Markus, Wagner, Barbara

Ultrathin polymer films on non-wettable substrates display dynamic features which have been attributed to either viscoelastic or slip effects. Here we show that in the weak and strong slip regime effects of viscoelastic relaxation are either absent or essentially indistinguishable from slip effects. Strong-slip modifies the fastest unstable mode in a rupturing thin film, which questions the standard approach to reconstruct the effective interface potential from dewetting experiments.