25 results
Search Results
Now showing 1 - 10 of 25
- ItemImpact of slippage on the morphology and stability of a dewetting rim(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2010) Münch, Andreas; Wagner, BarbaraIn this study lubrication theory is used to describe the stability and morphology of the rim that forms as a thin polymer film dewets from a hydrophobized silicon wafer. Thin film equations are derived from the governing hydrodynamic equations for the polymer to enable the systematic mathematical and numerical analysis of the properties of the solutions for different regimes of slippage and for a range of time scales. Dewetting rates and the cross sectional profiles of the evolving rims are derived for these models and compared to experimental results. Experiments also show that the rim is typically unstable in the spanwise direction and develops thicker and thinner parts that may grow into ``fingers''. Linear stability analysis as well as nonlinear numerical solutions are presented to investigate shape and growth rate of the rim instability. It is demonstrated that the difference in morphology and the rate at which the instability develops can be directly attributed to the magnitude of slippage. Finally, a derivation is given for the dominant wavelength of the bulges along the unstable rim.
- ItemInfluence of slip on the Rayleigh-Plateau rim instability in dewetting viscous films(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2013) Bäumchen, Oliver; Marquant, Ludovic; Blossey, Ralf; Münch, Andreas; Wagner, Barbara; Jacobs, KarinA dewetting viscous film develops a characteristic fluid rim at its receding edge due to mass conservation. In the course of the dewetting process the rim becomes unstable via an instability of Rayleigh-Plateau type. An important difference exists between this classic instability of a liquid column and the rim instability in the thin film as the growth of the rim is continuously fueled by the receding film. We explain how the development and macroscopic morphology of the rim instability are controlled by the slip of the film on the substrate. A single thin-film model captures quantitatively the characteristics of the evolution of the rim observed in our experiments.
- ItemSelf-consistent field theory for a polymer brush. Part II: The effective chemical potential(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2019) Münch, Andreas; Wagner, BarbaraThe most successful mean-field model to describe the collective behaviour of the large class of macromolecular polymers is the self-consistent field theory (SCFT). Still, even for the simple system of a grafted dry polymer brush, the mean-field equations have to be solved numerically. As one of very few alternatives that offer some analytical tractability the strong-stretching theory (SST) has led to explicit expressions for the effective chemical potential and consequently the free energy to promote an understanding of the underlying physics. Yet, a direct derivation of these analytical results from the SCFT model is still outstanding. In this study we present a systematic asymptotic theory based on matched asymtptotic expansions to obtain the effective chemical potential from the SCFT model for a dry polymer brush for large but finite stretching.
- ItemGradient structures for flows of concentrated suspensions(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2018) Peschka, Dirk; Thomas, Marita; Ahnert, Tobias; Münch, Andreas; Wagner, BarbaraIn this work we investigate a two-phase model for concentrated suspensions. We construct a PDE formulation using a gradient flow structure featuring dissipative coupling between fluid and solid phase as well as different driving forces. Our construction is based on the concept of flow maps that also allows it to account for flows in moving domains with free boundaries. The major difference compared to similar existing approaches is the incorporation of a non-smooth twohomogeneous term to the dissipation potential, which creates a normal pressure even for pure shear flows.
- ItemInterface morphologies in liquid/liquid dewetting(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2010) Kostourou, Konstantina; Peschka, Dirk; Münch, Andreas; Wagner, Barbara; Herminghaus, Stephan; Seemann, RalfThe dynamics and morphology of a liquid polystyrene (PS) film on the scale of a hundred nanometer dewetting from a liquid polymethylmethacrylate (PMMA) film is investigated experimentally and theoretically. The polymers considered here are both below their entanglement lengths and have negligible elastic properties. A theoretical model based on viscous Newtonian flow for both polymers is set up from which a system of coupled lubrication equations is derived and solved numerically. A direct comparison of the numerical solution with the experimental findings for the characteristic signatures of the cross-sections of liquid/air and liquid/liquid phase boundaries of the dewetting rims as well as the dewetting rates is performed and discussed for various viscosity ratios of the PS and PMMA layers.
- ItemModels for the two-phase flow of concentrated suspensions(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2014) Ahnert, Tobias; Münch, Andreas; Wagner, BarbaraA new two-phase model for concentrated suspensions is derived that incorporates a constitutive law combining the rheology for non-Brownian suspension and granular flow. The resulting model naturally exhibits a Bingham-type flow property. This property is investigated in detail for the simple geometry of plane Poiseuille flow, where an unyielded or jammed zone of finite width arises in the center of the channel. For the steady state of this problem, the governing equation are reduced to a boundary value problem for a system of ordinary differential equations and the dependence of its solutions are analyzed by using phase-space methods. For the general time-dependent case a new drift-flux model is derived for the first time using matched asymptotic expansions that take account of the boundary layers at the walls and the interface between the yielded and unyielded region. Using the drift-flux model, the behavior of the suspension flow, in particular the appearance and evolution of unyielded or jammed regions is then studied numerically for different choices of the parameters.
- ItemAnisotropic surface energy formulations and their effect on stability of a growing thin film(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2012) Korzec, Maciek D.; Münch, Andreas; Wagner, BarbaraIn this paper we revisit models for the description of the evolution of crystalline films with anisotropic surface energies. We prove equivalences of symmetry properties of anisotropic surface energy models commonly used in the literature. Then we systematically develop a framework for the derivation of surface diffusion models for the self-assembly of quantum dots during Stranski-Krastanov growth that include surface energies also with large anisotropy as well as the effect of wetting energy, elastic energy and a randomly perturbed atomic deposition flux. A linear stability analysis for the resulting sixth-order semilinear evolution equation for the thin film surface shows that that the new model allows for large anisotropy and gives rise to the formation of anisotropic quantum dots. The nonlinear three-dimensional evolution is investigated via numerical solutions. These suggest that increasing anisotropy stabilizes the faceted surfaces and may lead to a dramatic slow-down of the coarsening of the dots.
- ItemSignatures of slip in dewetting polymer films(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2018) Peschka, Dirk; Haefner, Sabrina; Jacobs, Karin; Münch, Andreas; Wagner, BarbaraThin liquid polymer films on hydrophobic substrates are susceptable to rupture and formation of holes, which in turn initiate a complex dewetting process that eventually evolves into characteristic stationary droplet patterns. Experimental and theoretical studies suggest that the specific type of droplet pattern largely depends on the nature of the polymer-substrate boundary condition. To follow the morphological evolution numerically over long time scales and for the multiple length scales involved has so far been a major challenge. In this study a highly adaptive finite-element based numerical scheme is presented that allows for large-scale simulations to follow the evolution of the dewetting process deep into the nonlinear regime of the model equations, capturing the complex dynamics including shedding of droplets. In addition, the numerical results predict the previouly unknown shedding of satellite droplets during the destabilisation of liquid ridges, that form during the late stages of the dewetting process. While the formation of satellite droplets is well-known in the context of elongating fluid filaments and jets, we show here that for dewetting liquid ridges this property can be dramatically altered by the interfacial condition between polymer and substrate, namely slip.
- ItemSharp-interface formation during lithium intercalation into silicon(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2016) Meca, Esteban; Münch, Andreas; Wagner, BarbaraIn this study we present a phase-field model that describes the process of intercalation of Li ions into a layer of an amorphous solid such as a-Si. The governing equations couple a viscous Cahn-Hilliard-Reaction model with elasticity in the framework of the Cahn-Larché system. We discuss the parameter settings and flux conditions at the free boundary that lead to the formation of phase boundaries having a sharp gradient in ion concentration between the initial state of the solid layer and the intercalated region. We carry out a matched asymptotic analysis to derive the corresponding sharp-interface model that also takes into account the dynamics of triple points where the sharp interface in the bulk of the layer intersects the free boundary. We numerically compare the interface motion predicted by the sharp-interface model with the long-time dynamics of the phase-field model.
- ItemApparent slip for an upper convected Maxwell fluid(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2016) Münch, Andreas; Wagner, Barbara; Cook, L. Pamela; Braun, Richard R.In this study the flow field of a nonlocal, diffusive upper convected Maxwell (UCM) fluid with a polymer in a solvent undergoing shearing motion is investigated for pressure driven planar channel flow and the free boundary problem of a liquid layer on a solid substrate. For large ratios of the zero shear polymer viscosity to the solvent viscosity, it is shown that channel flows exhibit boundary layers at the channel walls. In addition, for increasing stress diffusion the flow field away from the boundary layers undergoes a transition from a parabolic to a plug flow. Using experimental data for the wormlike micelle solutions CTAB/NaSal and CPyCl/NaSal, it is shown that the analytic solution of the governing equations predicts these signatures of the velocity profiles. Corresponding flow structures and transitions are found for the free boundary problem of a thin layer sheared along a solid substrate. Matched asymptotic expansions are used to first derive sharp-interface models describing the bulk flow with expressions for an apparent slip for the boundary conditions, obtained by matching to the flow in the boundary layers. For a thin film geometry several asymptotic regimes are identified in terms of the order of magnitude of the stress diffusion, and corresponding new thin film models with a slip boundary condition are derived.
- «
- 1 (current)
- 2
- 3
- »