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Martin, Andreas
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Ait Ali, Mustapha
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Eckelt, Reinhard
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El Firdoussi, Larbi
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Oubaassine, Saadia
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catalysts
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natural terpene
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β-bromoalcohols
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New York, NY [u.a.] : Hindawi
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Journal of chemistry 2019 (2019)
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Author: Martin, Andreas
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Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides
(
New York, NY [u.a.] : Hindawi,
2018
)
Oubaassine, Saadia
;
Köckritz, Angela
;
Eckelt, Reinhard
;
Martin, Andreas
;
Ait Ali, Mustapha
;
El Firdoussi, Larbi
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In a one-step procedure, various ß-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H 2 O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The synthesized ß-bromoalcohols were subsequently converted in situ to the corresponding epoxides in good yields. © 2019 Saadia Oubaassine et al.
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