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- ItemBuilding Hierarchical Martensite(Weinheim : Wiley-VCH, 2020) Schwabe, Stefan; Niemann, Robert; Backen, Anja; Wolf, Daniel; Damm, Christine; Walter, Tina; Seiner, Hanuš; Heczko, Oleg; Nielsch, Kornelius; Fähler, SebastianMartensitic materials show a complex, hierarchical microstructure containing structural domains separated by various types of twin boundaries. Several concepts exist to describe this microstructure on each length scale, however, there is no comprehensive approach bridging the whole range from the nano- up to the macroscopic scale. Here, it is described for a Ni-Mn-based Heusler alloy how this hierarchical microstructure is built from scratch with just one key parameter: the tetragonal distortion of the basic building block at the atomic level. Based on this initial block, five successive levels of nested building blocks are introduced. At each level, a larger building block is formed by twinning the preceding one to minimize the relevant energy contributions locally. This naturally explains the coexistence of different types of twin boundaries. The scale-bridging approach of nested building blocks is compared with experiments in real and reciprocal space. The approach of nested building blocks is versatile as it can be applied to the broad class of functional materials exhibiting diffusionless transformations. © 2020 The Authors. Advanced Functional Materials published by Wiley-VCH GmbH
- ItemPhase Selection in Mn–Si Alloys by Fast Solid-State Reaction with Enhanced Skyrmion Stability(Weinheim : Wiley-VCH, 2021) Li, Zichao; Xie, Yufang; Yuan, Ye; Ji, Yanda; Begeza, Viktor; Cao, Lei; Hübner, René; Rebohle, Lars; Helm, Manfred; Nielsch, Kornelius; Prucnal, Slawomir; Zhou, ShengqiangB20-type transition-metal silicides or germanides are noncentrosymmetric materials hosting magnetic skyrmions, which are promising information carriers in spintronic devices. The prerequisite is to prepare thin films on technology-relevant substrates with magnetic skyrmions stabilized at a broad temperature and magnetic-field working window. A canonical example is the B20-MnSi film grown on Si substrates. However, the as-yet unavoidable contamination with MnSi1.7 occurs due to the lower nucleation temperature of this phase. In this work, a simple and efficient method to overcome this problem and prepare single-phase MnSi films on Si substrates is reported. It is based on the millisecond reaction between metallic Mn and Si using flash-lamp annealing (FLA). By controlling the FLA energy density, single-phase MnSi or MnSi1.7 or their mixture can be grown at will. Compared with bulk MnSi, the prepared MnSi films show an increased Curie temperature of up to 41 K. In particular, the magnetic skyrmions are stable over a much wider temperature and magnetic-field range than reported previously. The results constitute a novel phase selection approach for alloys and can help to enhance specific functional properties, such as the stability of magnetic skyrmions. © 2021 The Authors. Advanced Functional Materials published by Wiley-VCH GmbH
- ItemComparative Study of Onion-like Carbons Prepared from Different Synthesis Routes towards Li-Ion Capacitor Application(Basel : MDPI, 2022) Permana, Antonius Dimas Chandra; Ding, Ling; Gonzalez-Martinez, Ignacio Guillermo; Hantusch, Martin; Nielsch, Kornelius; Mikhailova, Daria; Omar, AhmadLi-ion capacitors (LIC) have emerged as a promising hybrid energy storage system in response to increasing energy demands. However, to achieve excellent LIC performance at high rates, along with cycling stability, an alternative anode to graphite is needed. Porous high-surface-area carbons, such as onion-like carbons (OLCs), have been recently found to hold high potential as high-rate-capable LIC anodes. However, a systematic understanding of their synthesis route and morphology is lacking. In this study, OLCs prepared from self-made metal organic frameworks (MOFs) Fe-BTC and Fe-MIL100 by a simple pyrolysis method were compared to OLCs obtained via high-temperature annealing of nanodiamonds. The LICs with OLCs produced from Fe-BTC achieved a maximum energy density of 243 Wh kg−1 and a power density of 20,149 W kg−1. Furthermore, excellent capacitance retention of 78% after 10,000 cycles was demonstrated. LICs with MOF-derived OLCs surpassed the energy and power density of LICs with nanodiamond-derived OLCs. We determined the impact of the MOF precursor structure and morphology on the resulting OLC properties, as well as on the electrochemical performance. Thus, MOF-derived OLCs offer significant potential toward high-performance anode material for LICs, enabling control over structure and morphology, as well as easy scalability for industrial implementation.