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Author: Peitz, S. × End date: 2019 × Start date: 2010 × Subject: Chemistry × WGL Institute: LIKAT ×

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[2,2-Bis(diphenylphosphanyl)propane κ2P,P0] tetracarbonylchromium(0)dichloromethane monosolvate

2010, Peulecke, N., Peitz, S., Müller, B.H., Spannenberg, A., Rosenthal, U.

The title compound, [Cr(C27H26P2)(CO) 4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC 4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 70.27 (2)°.

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[Bis(diphenylphosphanyl)dimethylsilane κ2P,P′] tetracarbonylchromium(0)

2010, Peulecke, N., Peitz, S., Müller, B.H., Spannenberg, A., Rosenthal, U.

The title compound, [Cr(C26H26P2Si)(CO) 4], was obtained by the reaction of Ph2PSiMe 2PPh2 with Cr(CO)6 in refluxing toluene by ligand exchange. The CrC4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 80.27 (1)°.

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